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Hot Corrosion and Oxidation Behavior of Network Structured TiBw/TA15 Composite at 1073 K

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Abstract

The hot corrosion and high temperature oxidation performance of the TiBw/TA15 composite were tested at 1073 K for up to 100 h. The final mass gain caused by the high temperature oxidation was only 16.9% of that caused by the hot corrosion, showing that the effect of hot corrosion is much larger than that of oxidation. After 100 h of high temperature oxidation testing, an approximately 50 μm-thick oxide scale formed on the substrate surface, consisting of mixed TiO2 and Al2O3 oxide. An approximately about 300 μm-thick hot corrosion scale, mainly composed of TiO2 and Al2O3 with holes and cracks, was generated after 100 h of hot corrosion testing. The change of acidity/basicity in the molten salt caused by the self-circulating sulfurization/chlorination–oxidation cycle and basic dissolution was the mean reasons for hot corrosion.

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The raw/processed data required to reproduce these findings cannot be shared at this time as the data also forms part of an ongoing study.

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Acknowledgements

This project is supported by National Natural Science Foundation of China (No. 51875122).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Harbin Institute of Technology, Harbin, 150001, China

    Qingxin Kang, Guofeng Wang, Zhenlun Li & Shuyi Luo

  2. National Key Laboratory for Precision Hot Processing of Metals, Harbin Institute of Technology, Harbin, 150001, China

    Qingxin Kang, Guofeng Wang, Zhenlun Li & Shuyi Luo

  3. School of Mechanical Science and Engineering, Northeast Petroleum University, 199 Fazhan Road, Daqing, 163318, People’s Republic of China

    Xiaoting Xu

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  1. Qingxin Kang
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Correspondence to Guofeng Wang.

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Kang, Q., Xu, X., Wang, G. et al. Hot Corrosion and Oxidation Behavior of Network Structured TiBw/TA15 Composite at 1073 K. J. of Materi Eng and Perform 33, 1156–1168 (2024). https://doi.org/10.1007/s11665-023-08045-7

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