Abstract
The mechanical properties and corrosion resistance of extruded Mg-8Li-3Al alloys with varying Gd contents are investigated by x-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and electrochemical tests. The results show that the size of α-Mg grains in extruded Mg-8Li-3Al alloys is obviously refined during the dynamic recrystallization process due to the addition of Gd. The ultimate tensile strength of extruded Mg-8Li-3Al-1.2Gd alloy attains to 278 MPa, which is approximately 35% higher than that of the matrix alloy (206 MPa). The improved mechanical properties of the Mg-8Li-3Al alloys containing Gd are mainly attributed to the formation of the Al2Gd phase, which can refine the α-Mg grain as a heterogeneous nucleation substrate and hinder the movement of the dislocations and grain boundaries and the rotation of the grains. The comprehensive electrochemical results show that the corrosion resistance of extruded Mg-8Li-3Al-xGd (x = 0.6, 1.2 and 1.8 wt.%) alloys is improved by the addition of Gd. In addition, the corrosion mechanism of extruded Mg-8Li-3Al alloys contained Gd is discussed.
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X.C. Luo, L.M. Kang, H.L. Liu, Z.J. Li, Y.F. Liu, D.T. Zhang, and D.L. Chen, Enhancing Mechanical Properties of AZ61 Magnesium Alloy Via Friction Stir Processing: Effect of Processing Parameters, Mater. Sci. Eng., A, 2020, 797, 139945.
W.J. Joost and P.E. Krajewski, Towards Magnesium Alloys for High-Volume Automotive Applications, Scripta Mater., 2017, 128, p 107-112.
X. Li, Z. Hu, H. Yan, X. Wu, H. Xie, and Z. Dong, Effect of Sm-Rich Phase on Corrosion Behavior of Hot-Extruded AZ31-1.5Sm Magnesium Alloy, J. Mater. Eng. Perform., 2018, 27, p 3072-3082.
J. Le, L. Liu, F. Liu, Y. Deng, C. Zhong, and W. Hu, Interdiffusion Kinetics of the Intermetallic Coatings on AZ91D Magnesium Alloy formed in Molten Salts at Lower Temperatures, J. Alloy. Compd., 2014, 610, p 173-179.
C. Muga, H. Guo, Y. Zou, S. Xu, and Z. Zhang, Effects of Holmium and Hot-Rolling on Microstructure and Mechanical Properties of Mg-Li based Alloys, J. Rare Earths, 2016, 34, p 1269-1276.
Y. Yan, Y. Qiu, O. Gharbi, N. Birbilis, and P.N.H. Nakashima, Characterisation of Li in the Surface Film of a Corrosion Resistant Mg-Li(-Al-Y-Zr) alloy, Appl. Surf. Sci., 2019, 494, p 1066-1071.
Z. Zhu, J. Zhu, Y. Nie, X. Li, J. Cheng, and X. Zhang, Effects of Annealing on Mechanical and Corrosion Properties of as-Extruded NQZ310K Alloy, J. Mater. Eng. Perform., 2020, 29, p 925-932.
J. Zhao, B. Jiang, Z. Dai, and Lu. Liwei, Microstructure, Texture, and Tensile Properties of Mg-3Li Alloy Extruded at Different Temperatures, J Mater. Eng. Perform., 2022, 31(7), p 5782-5789. https://doi.org/10.1007/s11665-022-06625-7
X. Lu, Y. Li, P. Ju, Y. Chen, J. Yang, K. Qian, T. Zhang, and F. Wang, Unveiling the Inhibition Mechanism of an Effective Inhibitor for AZ91 Mg Alloy, Corros. Sci., 2019, 148, p 264-271.
A. Medjahed, A. Henniche, M. Derradji, T. Yu, Y. Wang, R. Wu, L. Hou, J. Zhang, X. Li, and M. Zhang, Effects of Cu/Mg Ratio on the Microstructure, Mechanical and Corrosion Properties of Al-Li-Cu-Mg-X Alloys, Mater. Sci. Eng., A, 2018, 718, p 241-249.
Y. Yang, X. Xiong, J. Chen, X. Peng, D. Chen, and F. Pan, Research Advances in Magnesium and Magnesium Alloys Worldwide in 2020, J. Magnesium Alloys, 2021, 9, p 705-747.
B.J. Wang, D.K. Xu, X. Cai, Y.X. Qiao, and L.Y. Sheng, Effect of Rolling Ratios on the Microstructural Evolution and Corrosion Performance of an as-rolled Mg-8 wt.%Li alloy, J. Magnesium Alloys, 2021, 9, p 560-568.
T. Zhao, Y. Hu, C. Zhang, and B. He, T. Zheng, A. Tang, F. Pan, Influence of Extrusion Conditions on Microstructure and Mechanical Properties of Mg-2Gd-0.3Zr Magnesium Alloy, J. Magnes. Alloys, 2020.
X. Zhang, S.K. Kairy, J. Dai, and N. Birbilis, A Closer Look at the Role of Nanometer Scale Solute-Rich Stacking Faults in the Localized Corrosion of a Magnesium Alloy GZ31K, J. Electrochem. Soc., 2018, 165, p C310-C316.
X. Zhang, J. Dai, Q. Dong, Z. Ba, and Y. Wu, Corrosion Behavior and Mechanical Degradation of as-Extruded Mg-Gd-Zn-Zr Alloys for Orthopedic Application, J. Biomed. Mater. Res. B Appl. Biomater., 2020, 108, p 698-708.
X. Zhang, J. Dai, R. Zhang, Z. Ba, and N. Birbilis, Corrosion behavior of Mg-3Gd-1Zn-0.4Zr Alloy with and without Stacking Faults, J. Magnesium Alloys, 2019, 7(2), p 240-248. https://doi.org/10.1016/j.jma.2019.02.009
X. Peng, X. Shihao, D. Ding, G. Liao, W. Guohua, W. Liu, and W. Ding, Microstructural Evolution, Mechanical Properties and Corrosion Behavior of as-cast Mg-5Li-3Al-2Zn Alloy with Different Sn and Y Addition[J], J. Mater. Sci. Technol., 2021, 72, p 16-22.
L.Y. Sheng, B.N. Du, Z.Y. Hu, Y.X. Qiao, Z.P. Xiao, B.J. Wang, D.K. Xu, Y.F. Zheng, and T.F. Xi, Effects of Annealing Treatment on Microstructure and Tensile Behavior of the Mg-Zn-Y-Nd alloy, Journal of Magnesium and Alloys, 2020, 8, p 601-613.
Z. Yin, R. He, Y. Chen, Z. Yin, K. Yan, K. Wang, H. Yan, H. Song, C. Yin, H. Guan, C. Luo, Z. Hu, and C. Luc, Effects of Surface Micro-Galvanic Corrosion and Corrosive Film on the Corrosion Resistance of AZ91-xNd Alloys, Appl. Surf. Sci., 2021, 536, 147761.
B. Du, Z. Hu, J. Wang, L. Sheng, H. Zhao, Y. Zheng, and T. Xi, Effect of Extrusion Process on the Mechanical and in Vitro Degradation Performance of a Biomedical Mg-Zn-Y-Nd alloy, Bioact Mater, 2020, 5, p 219-227.
H. Bo, L.B. Liu, J.L. Hu, X.D. Zhang, and Z.P. Jin, Thermodynamic re-Assessment of the Al-Gd and Gd-Zr Systems, Thermochim. Acta, 2014, 591, p 51-56.
Z. Zheng, Q. Xing, Z. Sun, J. Xu, Z. Zhao, S. Chen, P.K. Liaw, and Y. Wang, Effects of Annealing on the Microstructure, Corrosion Resistance, and Mechanical Properties of RE65Co25Al10 (RE=Ce, La, Pr, Sm, and Gd) Bulk Metallic Glasses, Mater. Sci. Eng., A, 2015, 626, p 467-473.
L. Sheng, X. Zhang, H. Zhao, and B. Du, Y. Zheng, T. Xi, Influence of Multi-Pass Hot Extrusion on Microstructure and Mechanical Properties of the Mg-4Zn-1.2Y-0.8Nd Alloy[J], Crystals, 2021, 11: 425.
P. Dinesh, S. Manivannan, S.P. Kumaresh Babu, and S. Natarajan, Effect of Nd on the Microstructure and Corrosion Behaviour of Mg-9Li-3Al Magnesium Alloy in 3.5 wt.% NaCl Solution, Mater. Today, 2019, 15, p 126-131.
X. Zhang, Z. Ba, Z. Wang, Y. Wu, and Y. Xue, Effect of LPSO Structure on Mechanical Properties and Corrosion Behavior of as-Extruded GZ51K Magnesium Alloy, Mater. Lett., 2016, 163, p 250-253.
T. Zhu, C. Cui, T. Zhang, R. Wu, S. Betsofen, Z. Leng, J. Zhang, and M. Zhang, Influence of the Combined Addition of Y and Nd on the Microstructure and Mechanical Properties of Mg-Li alloy, Mater. Des., 2014, 57, p 245-249.
F. Zhong, H. Wu, Y. Jiao, R. Wu, J. Zhang, L. Hou, and M. Zhang, Effect of Y and Ce on the Microstructure, Mechanical Properties and Anisotropy of as-rolled Mg-8Li-1Al alloy, J. Mater. Sci. Technol., 2020, 39, p 124-134.
B. Zhang, X.D. Peng, Y. Ma, Y.M. Li, Y.Q. Yu, and G.B. Wei, Microstructure and Mechanical Properties of Mg-9Li-3Al-xGd Alloys, Mater. Sci. Technol-lond., 2015, 31, p 1035-1041.
J.-W. Dai, X.-Bo. Zhang, Y. Fei, Z.-Z. Wang, and H.-M. Sui, Effect of Solution Treatment on Microstructure and Corrosion Properties of Mg-4Gd-1Y-1Zn-0.5Ca-1Zr Alloy, Acta Metallurgica Sinica Engl. Lett., 2018, 31(8), p 865-872. https://doi.org/10.1007/s40195-018-0709-5
N. Jiang, L. Chen, L. Meng, C. Fang, H. Hao, and X. Zhang, Effect of Neodymium, Gadolinium Addition on Microstructure and Mechanical Properties of AZ80 Magnesium Alloy, J. Rare Earths, 2016, 34, p 632-637.
R. Arrabal, B. Mingo, A. Pardo, E. Matykina, M. Mohedano, M.C. Merino, A. Rivas, and A. Maroto, Role of Alloyed Nd in the Microstructure and Atmospheric Corrosion of as-cast Magnesium Alloy AZ91, Corros. Sci., 2015, 97, p 38-48.
R. Arrabal, A. Pardo, M.C. Merino, K. Paucar, M. Mohedano, P. Casajús, and G. Garcés, Influence of Gd on the Corrosion Behavior of AM50 and AZ91D Magnesium Alloys, Corrosion, 2012, 68, p 398-410.
Z. Hu, Z. Yin, Z. Yin, K. Wang, Q. Liu, P. Sun, H. Yan, H. Song, C. Luo, H. Guan, and C. Luc, Corrosion Behavior Characterization of as Extruded Mg-8Li-3Al Alloy with Minor Alloying Elements (Gd, Sn and Cu) by Scanning Kelvin Probe Force Microscopy, Corros. Sci., 2020, 176, 108923.
B.L. Bramfitt, The Effect of Carbide and Nitride Additions on the Heterogeneous Nucleation Behavior of Liquid Iron, Metall. Trans., 1970, 1, p 1987-1995.
B.N. Du, Z.Y. Hu, L.Y. Sheng, D.K. Xu, Y.X. Qiao, B.J. Wang, J. Wang, Y.F. Zheng, and T.F. Xi, Microstructural Characteristics and Mechanical Properties of the Hot Extruded Mg-Zn-Y-Nd Alloys, J. Mater. Sci. Technol., 2021, 60, p 44-55.
B.N. Du, Z.P. Xiao, Y.X. Qiao, L. Zheng, B.Y. Yu, D.K. Xu, and L.Y. Sheng, Optimization of Microstructure and Mechanical Property of a Mg-Zn-Y-Nd alloy by Extrusion Process, J. Alloy. Compd., 2019, 775, p 990-1001.
Y. Song, E.H. Han, D. Shan, C.D. Yim, and B.S. You, The Effect of Zn Concentration on the Corrosion Behavior of Mg-xZn Alloys, Corros. Sci., 2012, 65, p 322-330.
Z. Yin, Y. Chen, H. Yan, G.H. Zhou, X.Q. Wu, and Z. Hu, Effects of the Second Phases on Corrosion Resistance of AZ91-xGd Alloys Treated with Ultrasonic Vibration, J. Alloy. Compd., 2019, 783, p 877-885.
A. Nandini Dinodi and Nityananda Shetty, Electrochemical Investigations on the Corrosion Behaviour of Magnesium Alloy ZE41 in a Combined Medium of Chloride And Sulphate, J. Magnesium Alloys, 2013, 1(3), p 201-209. https://doi.org/10.1016/j.jma.2013.08.003
Y. Luo, Y. Deng, L. Guan, L. Ye, and X. Guo, The Microstructure and Corrosion Resistance of as-Extruded Mg-6Gd-2Y- (0-1.5) Nd-0.2Zr Alloys, Materials and Design, 2020, 186, p 108289.
G. Song, A. Atrens, D.S. John, X. Wu, and J. Nairn, The Anodic Dissolution of Magnesium in Chloride and Sulphate Solutions, Corros. Sci., 1997, 39, p 1981-2004.
W.L. Cheng, S.C. Ma, Y. Bai, Z.Q. Cui, and H.X. Wang, Corrosion Behavior of Mg-6Bi-2Sn Alloy in the Simulated Body Fluid Solution: The Influence of Microstructural Characteristics, J. Alloy. Compd., 2018, 731, p 945-954.
M. Cheng, J. Chen, H. Yan, B. Su, Z. Yu, W. Xia, and X. Gong, Effects of Minor Sr Addition on Microstructure, Mechanical and bio-Corrosion Properties of the Mg-5Zn Based alloy System, J. Alloy. Compd., 2017, 691, p 95-102.
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The authors would like to acknowledge the financial support by the National Natural Science Foundation of China (51961026, 52065066) and Interdisciplinary Innovation Fund of Nanchang University (Project No.2019-9166-27060003)
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Xu, M., Deng, S., Yin, Z. et al. The Effect of Gd Concentration on the Mechanical Properties and Corrosion Behavior of Extruded Mg-8Li-3Al-xGd (x = 0, 0.6, 1.2, and 1.8 wt.%) Alloys. J. of Materi Eng and Perform 32, 6642–6653 (2023). https://doi.org/10.1007/s11665-022-07607-5
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DOI: https://doi.org/10.1007/s11665-022-07607-5