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Dilatometric and Microstructural Investigations on Austenite Decomposition under Continuous Cooling Conditions in a Cu-Bearing High-Strength Low-Alloy Steel

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Abstract

High-strength low-alloy (HSLA) steels are an important class of steels that meet combinations of varied properties demanded by critical engineering applications. Microstructures of this class of steels are engineered to meet the targeted mechanical properties. Thorough understanding of phases that evolve during decomposition of austenite in these steels after hot working or after austenitizing treatments is essential to optimize their key processing parameters. This is achieved through establishment of continuous cooling transformation diagrams. These diagrams shed light on details of cooling transformations like the phases formed during transformation, sequence of transformation when multiple phase transformations are involved and the temperatures at which the transformations start and end, all as a function of cooling rate. These diagrams are constructed from dilatometry experiments together with corroborating microstructural investigations and mechanical property assessments. However, analyses of dilatograms, identification and quantification of microstructural constituents and correlating the same with mechanical properties (usually hardness) are not trivial, especially, in low-carbon HSLA steels where the microstructure is often composed of martensite and bainite that have rather similar morphological features and practically difficult to distinguish from each other. Advanced data processing of electron backscattered diffraction (EBSD) data has been used in recent times with considerable success to differentiate bainite and martensite. This work highlights the salient aspects involved in decomposition of austenite in an indigenously developed Cu-bearing HSLA steel. Details of methodology employing grain average misorientation obtained through EBSD experiments to identify and quantify martensite and bainite are discussed in detail.

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References

  1. S.W. Thompson, D.J. Colvin, and G. Krauss, Austenite Decomposition During Continuous Cooling of an HSLA-80 Plate Steel, Metall. and Mater. Trans. A., 1996, 27, p 1557–1571.

    Article  Google Scholar 

  2. J.R. Davis, High-Strength Low-Alloy Steels, Alloying: Understanding the Basics, 1st ed., ASM International, 2001, p 193-209

  3. S.Vervynckt, K. Verbeken., B. Lopez, and J.J. Jonas, Modern HSLA steels and role of non-recrystallisation temperature, International Materials Reviews, 2012, 57(4), p 187-207

  4. The greatest depth of immersion of submarines of the Russian Navy, US Navy and Japan, https://weaponews.com/weapons/65355810-the-greatest-depth-of-immersion-of-submarines-of-the-russian-navy-us-n.html, Accessed on 24 June 2021

  5. A. Danijel, Skobir, Visokotrdna Malolegirana (HSLA) Konstrukcijskajekla (High-Strength Low-Alloy (Hsla) Steels), Materiali in Tehnologije, 2011, 45(4), p 295–301.

    Google Scholar 

  6. N.J. Kim, The Physical Metallurgy of HSLA Linepipe Steels- A Review, J. Metals, 1983, 35(4), p 21–27.

    Google Scholar 

  7. Ernest J. Czyryca, Richard E. Link, Richard J. Wong, Denise A. Aylor, Thomas W. Montemarano, and John P. Gudas, Development and Certification of HSLA -100 Steel for Naval Ship Construction, Naval Engineers Journal, 1990, 63, 102(3)

  8. G. Malkondaiah, M. Srinivas, and R. Balamuralikrishnan, High performance steels for Indian defence, IIM Metal News, 2012, 15(2), p 28–31.

    Google Scholar 

  9. Nirmalya Rarhi, Parmanand Bairwa, R. Veerababu, K. Ankalu, S. Nagarjuna, R. Balamuralikrishnan, K Muraleedharan, and M. Srinivas, Development of 780 MPa Steels for Naval Applications: Part-I: Initial Trials on Composition and Heat Treatment Optimization, DRDO-DMRL-SSG-33, DMRL Technical Report, DMRL, India, 2012

  10. Nirmalya Rarhi, Paramanand Bairwa, K. Ankalu, R. Balamuralikrishnan, S. Nagarjuna, K. Muraleedharan, and M. Srinivas, Development of 780 MPa Steels for Naval Applications: Part-II: Composition Refinement and Establishment of Reproducibility, DRDO-DMRL-SSG-068, DMRL Technical Report, DMRL, India, 2014

  11. G.K. Prior, The role of dilatometry in the characterisation of steels, Mater. Forum, 1994, 18, p 265–276.

    Google Scholar 

  12. A.A. Zisman, S.N. Petrov, and A.V. Ptashnik, Quantitative Verification of High-Strength Alloyed Steel Bainite-Martensite Structures by Scanning Electron Microscopy Methods, Metallurgist, 2015, 58(11–12), p 1019–1024. (in Russian)

    Article  Google Scholar 

  13. A. A. Zisman, N. Yu. Zolotorevsky, S. N. Petrov, E. I. Khlusova, and E. A. Yashina, Panoramic Crystallographic Analysis of Structure Evolution in Low-Carbon Martensitic Steel under Tempering Metal Science and Heat Treatment, 2018, 60 (3-4), p 142-149, in Russian

  14. S.K. Dhua, D. Mukerjee, and D.S. Sarma, Effect of cooling rate on the as-quenched microstructure and mechanical properties of HSLA-100 steel plates, Metall. and Mater. Trans. A., 2003, 34, p 2493–2504.

    Article  Google Scholar 

  15. S.W. Thompson, D.J. Colvin and G. Krauss, Continuous cooling transformations and microstructures in a low-carbon, high-strength low-alloy plate steel, Metall. Trans. A, 1990, 21, p 1493–1507.

    Article  Google Scholar 

  16. Y-J Yang, J-X Fu, R-J Zhao, and Y-X Wu, Dilatometric Analysis of Phase Fractions During Austenite Decomposition in Pipeline Steel, 3rd International Conference on Material, Mechanical and Manufacturing Engineering (IC3ME2015), Prasad Yarlagadda, June 27-28, 2015, Guangzhou, China, p 2186–2190

  17. S.W. Thompson, D.J. Colvin, and G. Krauss, On the bainitic structure formed in a modified A710 steel, Scripta Metall., 1988, 22(7), p 1069–1074.

    Article  Google Scholar 

  18. A.D. Wilson, E.G. Hamburg, D.J. Colvin, S.W. Thompson, and G Krauss, Proc. Int. Conf. on Microalloyed HSLA Steel, Microalloying’88, ASM International, Metals Park, OH, 1988, p 259-275

  19. Harry Bhadeshia, and Robert Honeycombe, Formation of Martensite, Steels: Microstructure and Properties, 3rd ed., Butterworth-Heinemann, 2006, p 95

  20. D.E. Laughlin, N.J. Jones, A.J. Schwartz, and T.B. Massalski, Thermally Activated Martensite: Its Relationship to Non-Thermally Activated (Athermal) Martensite, G. B. Olson, D. S. Lieberman, and A. Saxena, (Ed.) International Conference on Martensitic Transformations (ICOMAT), New Mexico, 2010, p 141–144

  21. C. Capedevila, F.G. Caballero, and C. Garcia de Andres, Determination of Ms Temperature in Steels: A Bayesian Neural Network Model, ISIJ Int., 2002, 42, p 894–902.

    Article  Google Scholar 

  22. R. Abbaschian, L. Abbaschian, and R.E. ReedHill, The transformation of austenite to Pearlite, Physical Metallurgy Principles, 4rth ed., Cengage Learning, 2009, p 568

  23. S.-W. Seo, H.K.D.H. Bhadeshia, and D.W. Suh, Pearlite growth rate in Fe-C and Fe-Mn-C Steels, Mater. Sci. Technol., 2015, 31, p 487–493.

    Article  Google Scholar 

  24. G. Krauss and S.W. Thompson, Ferritic Microstructures in Continuously Cooled Low- and Ultralow-carbon Steels, ISIJ Int., 1995, 35(8), p 937–945.

    Article  Google Scholar 

  25. S. Morito, X. Huang, T. Furuhara, T. Maki, and N. Hansen, The Morphology and Crystallography of Lath Martensite in Alloy Steels, Acta Mater., 2006, 54(19), p 5323–5331.

    Article  Google Scholar 

  26. B.L. Bramfitt and J.G. Speer, A Perspective on the Morphology of Bainite, Metall. Trans. A, 1990, 21(3), p 817–829.

    Article  Google Scholar 

  27. S. Zajac, V. Schwinn, and K.H. Tacke, Characterisation and Quantification of Complex Bainitic Microstructures in High and Ultra-High Strength Linepipe Steels, Mater. Sci. Forum, 2005, 500–501, p 387–394.

    Article  Google Scholar 

  28. H.K.D.H. Bhadeshia, The Discovery of Bainite, Bainite in Steels: Theory and Practice, 3rd ed. CRC Press, Boca raton, 2015, p 2

    Google Scholar 

  29. H. Kitahara, R. Ueji, N. Tsuji, and Y. Minamino, Crystallographic Features of Lath Martensite in Low-Carbon Steel, Acta Mater., 2006, 54, p 1279–1288.

    Article  Google Scholar 

  30. S.-H. Na, J.-B. Seol, M. Jafari, and C.-G. Park, A Correlative Approach for Identifying Complex Phases by Electron Backscatter Diffraction and Transmission Electron Microscopy, Appl. Microsc., 2017, 47(1), p 43–49.

    Article  Google Scholar 

  31. K.-S. Min-SeokBaek, T.-W. Park, J. Ham, and K.-A. Lee, Quantitative Phase Analysis of Martensite-Bainite Steel Using EBSD and its Microstructure, Tensile and High-Cycle Fatigue Behaviors, Mater. Sci. Eng., A, 2020, 785(139375), p 1–13.

    Google Scholar 

  32. C. Herrera, D. Ponge, and D. Raabe, Design of a Novel Mn-Based 1 GPa Duplex Stainless TRIP Steel with 60% Ductility by a Reduction of Austenite Stability, Acta Mater., 2011, 59, p 4653–4664.

    Article  Google Scholar 

  33. R. Petrov, L. Kestens, A. Wasilkowska, and Y. Houbaert, Microstructure and Texture of a Lightly Deformed TRIP-Assisted Steel Characterized by Means of the EBSD Technique, Mater. Sci. Eng. A, 2007, 447(1–2), p 285–297.

    Article  Google Scholar 

  34. S. Zaefferer, J. Ohlert, and W. Bleck, A Study of Microstructure, Transformation Mechanisms and Correlation Between Microstructure and Mechanical Properties of a Low Alloyed TRIP Steel, Acta Mater., 2004, 52, p 2765–2778.

    Article  Google Scholar 

  35. O. Man, L. Pantělejev, and Z. Pešina, EBSD Analysis of Phase Compositions of Trip Steel on Various Strain Levels, Mater. Eng., 2009, 16, p 15–21.

    Google Scholar 

  36. A.A. Gazder, F. Al-Harbi, H. ThSpanke, and D.R.G. Mitchell, A Correlative Approach to Segmenting Phases and Ferrite Morphologies in Transformation-Induced Plasticity Steel Using Electron Back-Scattering Diffraction and Energy Dispersive X-ray Spectroscopy, Ultramicroscopy, 2014, 147, p 114–132.

    Article  Google Scholar 

  37. M. Takahashi and H.K.D.H. Bhadeshia, Model for Transition from Upper to Lower Bainite, Mater. Sci. Technol., 1990, 6(7), p 592–603.

    Article  Google Scholar 

  38. J.F. Nye, Some Geometrical Relations in Dislocated Crystals, Acta Metall., 1953, 1(2), p 153–162.

    Article  Google Scholar 

  39. F. Sozio and A. Yavari, On Nye’s Lattice Curvature Tensor, Mech. Res. Commun., 2021, 113, p 103696.

    Article  Google Scholar 

  40. A.A. Zisman, Choice of Scalar Measure for Crystal Curvature to Image Dislocation Substructure in Terms of Discrete Orientation Data, J. Mech. Bhr. Mater., 2016, 25(1–2), p 15–22.

    Article  Google Scholar 

  41. W. Pantleon, Resolving the Geometrically Necessary Dislocation Content by Conventional Electron Backscattering Diffraction, Scripta Mater., 2008, 58, p 994–997.

    Article  Google Scholar 

  42. O. Muránsky, L. Balogh, M. Tran, C.J. Hamelin, J.-S. Park, and M.R. Daymond, On the Measurement of Dislocations and Dislocation Substructures Using EBSD and HRSD Techniques, Acta Mater., 2019, 175, p 297–313.

    Article  Google Scholar 

  43. J.-Y. Kang, Do Hyun Kim, Sung-Il Baik, Tae-Hong Ahn, Young-Woon Kim, Heung Nam Han, Kyu Hwan Oh, Hu-Chul Lee, Seong Ho Han, Phase Analysis of Steels by Grain-averaged EBSD Functions, ISIJ Int., 2011, 51(1), p 130–136.

    Article  Google Scholar 

  44. Y. Wang and L. Li, Microstructure Evolution of Fine Grained Heat Affected Zone in Type IV Failure of P91 Welds, Weld. Res., 2016, 95, p 27–36.

    Google Scholar 

  45. S. Zaefferer, P. Romano, and F. Friedel, EBSD as a Tool to Identify and Quantify bainite and Ferrite in Low-Alloyed Al-TRIP Steels, J. Microsc., 2008, 230(3), p 499–508.

    Article  Google Scholar 

  46. J.-Y. Kang, B. Bacroix, H. Regle, K.H. Oh, and H.-C. Lee, Effect of Deformation Mode and Grain Orientation on Misorientation Development in a Body-Centered Cubic Steel, Acta Mater., 2007, 55, p 4935–4946.

    Article  Google Scholar 

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Acknowledgment

The authors would like to thank Director, DMRL, for providing continuous support and encouragement for carrying out this work.

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Correspondence to Atul Kumar.

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Kumar, A., Sahoo, L., Kumar, D. et al. Dilatometric and Microstructural Investigations on Austenite Decomposition under Continuous Cooling Conditions in a Cu-Bearing High-Strength Low-Alloy Steel. J. of Materi Eng and Perform 31, 9060–9072 (2022). https://doi.org/10.1007/s11665-022-06974-3

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