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Oxidation Behavior and High Temperature Friction and Wear Resistance of TiN-VC Reinforced VN Alloy/Co-Based Composite Coatings by Laser Cladding

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Abstract

TiN-VC reinforced VN alloy/Co-based composite coatings were fabricated on mild steel by laser cladding. High temperature oxidation and tribological properties of the composite coatings were researched. Results illustrated that TiN and VC phases were in-situ synthesized in the composite coatings and appeared the aggregation phenomenon. Compared with VN alloy/Co-based composite coatings and substrate, the mass gain of the TiN-VC reinforced VN alloy/Co-based composite coatings after oxidation at 1000 °C was decreased by 16.98 and 89.74%, respectively. The oxidation kinetics curve complied with the parabolic law. The oxidation mechanism was that preferentially formed TiO2 oxidation film with pore structure promoted a few inward diffusional O atoms and outward diffusional Cr and Co atoms to form a thin continuous and dense Cr2O3 and CoO oxidation film, which reduced the oxidation rate of the composite coatings. The mass loss of the TiN-VC reinforced VN alloy/Co-based composite coatings at 600 °C was, respectively, decreased by 23.95 and 97.61%, and the friction coefficient was also obviously decreased. The worn mechanism was the comprehensive action of the abrasive wear, adhesive wear and oxidation wear.

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Data Availability

The data used to support the findings of this study are available from the corresponding author upon request.

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Acknowledgments

This author wish to express thanks for financial support of Excellent Young Talents Fund Program of Higher Education Institutions of Anhui Province of China (no. gxyq2019073) and High Level Talents Fund Program of West Anhui University (no. 12).

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Authors and Affiliations

  1. School of Mechanical and Automotive Engineering, West Anhui University, Lu’an, 237012, Anhui, China

    Lin Ding & Hongxin Wang

  2. School of Materials Science and Engineering, Tianjin University, Tianjin, 300072, People’s Republic of China

    Lin Ding, ShengSun Hu & Junqi Shen

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Ding, L., Hu, S., Wang, H. et al. Oxidation Behavior and High Temperature Friction and Wear Resistance of TiN-VC Reinforced VN Alloy/Co-Based Composite Coatings by Laser Cladding. J. of Materi Eng and Perform 31, 3481–3492 (2022). https://doi.org/10.1007/s11665-021-06497-3

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  • DOI: https://doi.org/10.1007/s11665-021-06497-3

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