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AMT/APS Multilayered Films as Adherence Promoters for Epoxy Coatings on Carbon Steel—Part I: Influence of Curing Conditions on Anticorrosive Properties of AMT/APS Films in Saline Medium

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Abstract

The first part of this work evaluates the influence of the cure conditions on the preparation of 3-aminopropyl trimethoxysilane (APS) and the corrosion inhibitor 5-amino-1,3,4-thiadiazole-2-thiol (AMT) multilayered films onto AISI 1020 carbon steel. The steel samples were pretreated in a 10−2 mol L−1 AMT solution for 3 h, immersed twice in a 5% v/v APS solution, and heat-treated at different temperatures and curing times. Regardless of the curing conditions used, electrochemical impedance spectroscopy (EIS) in 0.5 mol L−1 NaCl showed that the inhibitor pretreatment favored the formation of a more protective film when compared to the alkaline-treated steel, covered or not by AMT or APS thin films. The AMT/APS multilayered film cured at 100 °C and 80 min exhibited the best improvement in the anticorrosive properties among all of the films studied in this work, which was confirmed by potentiodynamic polarization (PP) experiments performed in the same electrolyte. XPS analysis of the selected AMT/APS film system revealed the formation of a Fe-O-S-R chemical bond, confirming the interaction of the AMT inhibitor with the NaOH-treated steel surface. The present findings indicate that the APS-AMT interaction may have occurred from the N-S bond, identified in the N 1s spectrum.

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Acknowledgments

The authors would like to thank the Rio de Janeiro Research Foundation (FAPERJ), the Brazilian National Research Council (CNPq), the Postgraduation Support Program (PROAP), and the Rio de Janeiro State University (UERJ) for the financial support. This study was financed in part by the “Coordenação de Aperfeiçoamento de Pessoal de Nível Superior—Brasil (CAPES)”—Finance Code 001. The authors would also like to thank Erika Batista Silveira from the National Institute of Technology (INT) for the XPS analyses.

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  1. Department of Analytical Chemistry, Laboratory of Electrochemistry and Corrosion, Rio de Janeiro State University, Rua São Francisco Xavier, 524, PHLC, 427, Maracanã, Rio de Janeiro, RJ, 20559-013, Brazil

    João Carlos Santos Silva Júnior, Dalva Cristina Baptista do Lago & Lilian Ferreira de Senna

  2. Laboratory of Computer Instrumentation and Simulation, Federal Institute of Education, Science, and Technology of Rio de Janeiro Campus Paracambi, Rua Sebastião de Lacerda, S/N—Fábrica, Paracambi, RJ, 26600-000, Brazil

    André Rocha Pimenta & Renato Pereira de Freitas

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Silva Júnior, J.C.S., Pimenta, A.R., de Freitas, R.P. et al. AMT/APS Multilayered Films as Adherence Promoters for Epoxy Coatings on Carbon Steel—Part I: Influence of Curing Conditions on Anticorrosive Properties of AMT/APS Films in Saline Medium. J. of Materi Eng and Perform 30, 2482–2503 (2021). https://doi.org/10.1007/s11665-021-05555-0

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