Abstract
Binding and particle phases are the two important parameters influencing materials properties. In this study, a series of novel W-4.9Ni-2.1Fe-xY2O3 (in weight%) alloys with different Y2O3 contents are prepared by secondary ball milling and spark plasma sintering (SPS) techniques to obtain uniformly distributed γ-(Ni, Fe) binding phases and finer grains. The microstructure, mechanical, wear resistance, and corrosion behavior of the sintered bodies with different Y2O3 were obtained by x-ray diffraction, scanning electron microscopy, Rockwell hardness tester, friction wear tester, and three-dimensional profile instruments. The results showed that a certain addition of Y2O3 led to refined grains and uniformed microstructures; but, if excessive, a weak grain refinement would be appeared. Moreover, the grain size tends to be stable with enhancing of the Y2O3 content. Considering properties such as density, hardness, compression yield strength, grain size, and uniform distribution of tungsten hard phase and γ-(Ni, Fe) binding phase, the comprehensive optimal amount of 0.7 wt.% of Y2O3 was attained for the alloy. Meanwhile, the SPS sintered body also exhibited the best friction, wear behavior, and corrosion resistance in 3.5% of NaCl solution.
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12 September 2019
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References
N. Senthilnathan, A.R. Annamalai, and G. Venkatachalam, Sintering of Tungsten and Tungsten Heavy Alloys of W–Ni–Fe and W–Ni–Cu: A Review, Trans. Indian Inst. Met., 2017, 5, p 1161–1176
Z. Wu, Y.Z. Li, C.M. Yang, and Q.J. Liu, Mechanical Properties of Tungsten Heavy Alloy and Damage Behaviors After Hypervelocity Impact, Rare Met., 2014, 4, p 414–418
N. Senthilnathan, A.R. Annamalai, and G. Venkatachalam, Microstructure and Mechanical Properties of Spark Plasma Sintered Tungsten Heavy Alloys, Mater. Sci. Eng. A, 2018, 710, p 66–73
W.R. Lu, C.Y. Gao, and Y.L. Ke, Constitutive Modeling of Two-Phase Metallic Composites with Application to Tungsten-Based Composite 93W–4.9Ni–2.1Fe, Met. Mater. Trans. A, 2014, 592, p 136–142
D.P. Xiang, L. Ding, Y.Y. Li, X.Y. Chen, and T.M. Zhang, Fabrication Fine-Grained Tungsten Heavy Alloy by Spark Plasma Sintering of Low-Energy Ball-Milled W–2Mo–7Ni–3Fe Powders, Metal. Mater. Trans. A, 2013, 578, p 18–23
J.J. Zhang, W.S. Liu, Y.Z. Ma, X.S. Ye, and Y.Y. Wu, Fabrication and Properties of Novel NiWFeB Amorphous Alloys, J. Mater. Eng. Perform., 2017, 26, p 4349–4353
A. Upadhyaya, Processing Strategy for Consolidating Tungsten Heavy Alloys for Ordnance Applications, Mater. Chem. Phys., 2001, 67, p 101–110
J.K. Chaurasia, K. Jitender, A. Muthuchamy, P.N. Patel, and A.R. Annamalai, Densification of SiC Particle Reinforced W–Ni–Fe Heavy Alloy Composites Through Conventional and Spark Plasma Sintering, Trans. Indian Inst. Met., 2017, 8, p 2185–2191
H.Y. Liu, S.H. Cao, J. Zhu, Y. Jin, and B.H. Chen, Densification, Microstructure and Mechanical Properties of 90W–4Ni–6Mn Heavy Alloy, Int. J. Refract. Met. Hard Mater., 2013, 37, p 121–126
J.L. Fan, B.Y. Huang, L.P. Xiao, and B.H. Kear, Sintering Behavior of Nanostructured W Based Composite Powder, Int. J. Powder. Met., 2005, 41, p 49–54
X.Q. Li, K. Hu, S.G. Qu, L. Li, and C. Yang, 93W–5.6Ni–1.4Fe Heavy Alloys with Enhanced Performance Prepared by Cyclic Spark Plasma Sintering, Mater. Sci. Eng. A, 2014, 599, p 233–241
T. Tanabe, M. Wada, T. Ohgo, and V. Philipps, Application of Tungsten for Plasma Limiters in TEXTOR, J. Nucl. Mater., 2000, 283(287), p 1128–1133
G.M. Song, Y.J. Wang, and Y. Zhou, Thermomechanical Properties of TiC Particle-Reinforced Tungsten Composites for High Temperature Applications, Int. J. Refract. Met. Hard Mater., 2003, 21, p 1–12
Y.F. Xie, L.L. Zhou, X.Y. Zhang, X.X. Li, Z.L. Zhou, and X.H. Zhang, Microstructure and Properties of W–4.9Ni–2.1Fe Heavy Alloy with Dy2O3 Addition, Rare Met., 2019, 8, p 746–753
X.H. Zhang and S.H. Hong, Fabrication and Properties of Mechanically Alloyed Oxide-Dispersed Tungsten Heavy Alloys, Mater. Sci. Eng. A, 2003, 363, p 179–184
A. Grairia, N.E. Beliardouh, M. Zahzouh, C. Nouveau, and A. Besnard, Dry Sliding Wear Investigation on Tungsten Carbide Particles Reinforced Iron Matrix Composites, Mater. Res. Exp., 2018, 5, p 116528
Y. Kim, S. Lee, E.P. Kim, and J.W. Noh, Effects of ThO2 on the Solid-State Sintering Behavior of W–Ni–Fe Alloy, Int. J. Ref. Met. Hard. Mater., 2011, 1, p 112–116
A.J. Mueller, R. Bianco, and R.W. Buckman, Evaluation of Oxide Dispersion Strengthened (ODS) Molybdenum and Molybdenum–Rhenium Alloys, Int. J. Refract. Met. Hard. Mater., 2000, 18, p 205–211
M.Y. Zhao, Z.J. Zhou, Q.M. Ding, M. Zhong, and K. Arshad, Effect of Rare Earth Elements on the Consolidation Behavior and Microstructure of Tungsten Alloys, Int. J. Refract. Met. Hard. Mater., 2014, 48, p 19–23
Y.L. Pan, L. Ding, H. Li, and D.P. Xiang, Effect of Y2O3 on the Microstructure and Mechanical Properties of Spark Plasma Sintered Fine-Grained W–Ni–Mn Alloy, J. Rare Earths, 2017, 35, p 1149–1155
X.H. Zhang, X.X. Li, H. Chen, T.B. Li, and W. Su, Investigation on Microstructure and Properties of Cu–Al2O3 Composites Fabricated by a Novel In-Situ Reactive Synthesis, Mater. Des., 2016, 92, p 58–63
C.L. Chen, C.L. Huang, and Y. Zeng, Synthesis of ODS Heavy Tungsten Alloys Through Post-Annealing and Secondary Balling Milling, Int. J. Refract. Met. Hard Mater., 2015, 45, p 359–364
X.H. Zhang, H. Chen, X.X. Li, J.H. Li, and W.J. Liu, Effect of Rare Earth on the Microstructure and Performance of Electrodeposited Ni–W Coatings, Rare Met. Mater. Eng., 2016, 10, p 2605–2608
H.F. Shen, W.G. Chen, and C.Q. Gu, Research on Nano W–Ni–Fe High Specific Gravity Alloy, Rare Met., 2005, 2, p 133–137
T. Liu, J.L. Fan, B.Y. Huang, M.G. Qi, and J.M. Tian, Effect of Mechanical Alloying and Trace Y2O3 Addition on Microstructure of Fine-Grain Tungsten Heavy Alloy Rods, Rare Met. Mater. Eng., 2010, 2, p 314–317
Z.W. Zhang, G.L. Chen, G. Chen, and J.E. Zhou, Thermal Stability of W–Ni–Fe Nano Structured and Amorphous Materials by Mechanical Alloying W–Ni–Fe, Rare Met. Mater. Eng., 2019, 11, p 1698–1702
X.H. Zhang and X.X. Li, Characteristics of Alumina Particles in Dispersion Strengthened Copper Alloys, Int. J. Min. Met. Mater., 2014, 11, p 1115–1119
M.I.A. El Aal and H.S. Kim, Wear Properties of High Pressure Torsion Processed Ultrafine Grained Al–7%Si Alloy, Mater. Des., 2014, 53, p 373–382
R. Yamanoglu, E. Karakulak, A. Zeren, and M. Zeren, Effect of Heat Treatment on the Tribological Properties of Al–Cu–Mg/nano SiC Composites, Mater. Des., 2013, 49, p 820–825
Y.L. Pan, L. Ding, H. Li, and D.P. Xiang, Effects of Y2O3 on the Microstructure and Mechanical Properties of Spark Plasma Sintered Fine-Grained W–Ni–Mn Alloy, J. Rare Earth, 2017, 35, p 1149–1155
Y.C. Wang, Z.T. Yao, X.W. Cheng, F.Y. Wu, and F.C. Wang, Effects of Y2O3 on the Microstructure and Mechanical Properties of Tungsten Alloys, J. Beijing Inst. Technol., 2007, 9, p 824–827
G.C. Wu, J.M. Yang, and D.W. Wang, Effect of La Doping on Impurity Segregation and Fracture Behavior of Tungsten-Based Heavy-Alloy Composites, J. Adv. Mater., 2007, 2, p 47–55
D.P. Xiang and L. Ding, Research Progress of Alloying Elements or Oxides Strengthened W–Ni–Fe Heavy Alloys, Chin. J. Nonferr. Met., 2013, 6, p 1549–1559
Acknowledgment
This study is financially supported by the National Key Research and Development Program of China (Grant No. 2016YFB0301400), the National Natural Science Foundation of China (Grant No.51871114 and 51804138), the Postdoctoral Science Foundation of China (2019M652290), the Postdoctoral Science Foundation of Jiangxi Province (3205700012 and 2018KY05), and the National Natural Science Foundation of Jiangxi Province (20181BBE58001).
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Zhang, X., Zhu, S., Zhang, B. et al. Effect of Y2O3 Addition on the Microstructure, Wear Resistance, and Corrosion Behavior of W-4.9Ni-2.1Fe Heavy Alloy. J. of Materi Eng and Perform 28, 4801–4810 (2019). https://doi.org/10.1007/s11665-019-04251-4
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DOI: https://doi.org/10.1007/s11665-019-04251-4