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Sliding Wear Behavior of an AISI 440B Martensitic Stainless Steel Lubricated with Biodiesel and Diesel–Biodiesel Blends

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Abstract

The aim of this work was to analyze the effect of biodiesel and diesel–biodiesel blends on the sliding wear behavior of AISI 440B martensitic stainless steel. Lubricated tests were performed on AISI 440B martensitic stainless steel samples using Brazilian commercial diesel (containing 7 vol.% biodiesel), pure biodiesel, and diesel–biodiesel blends with biodiesel additions of 20% v/v, 30% v/v, and 50% v/v. Non-lubricated tests were also performed. The stainless steel was analyzed in the as-received condition (annealed) and after heat treatments (quenched and tempered at different temperatures), using a pin-on-disk device with an alumina pin, at a 1.8 m/s sliding speed, 14.7 N load, and 4400 m sliding distance, following the ASTM G99-04 Standard. Wear track widths, wear coefficients, and wear track surfaces were analyzed by optical and scanning electron microscopy. The results showed that AISI 440B presented the worst wear behavior in the dry condition with a microstructure characterized by a ferritic matrix and dispersed carbides (annealed condition). The wear resistance increased with the increase in biodiesel content due to the matrix strengthening by the martensitic transformation (heat-treated condition). When the biodiesel content was superior to 50% v/v, a reverse result was found. The observed wear mechanism was abrasive in all conditions. A − 1.35 power law coefficient characterized the wear coefficient as a function of biodiesel content for the annealed condition and a − 0.95 power law coefficient for the heat-treated conditions.

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References

  1. ANP – Brazilian National Agency for Petroleum, Oil, Gas and Biofuels. Law no 13263, 3.23.2016.

  2. F.A. Almeida, M.M. Maru, L.N. Batista, F.J.A. Oliveira, R.R.F.S. Silva, and C.A. Achete, Wear and Friction Behaviour of Si3N4 Ceramics Under Diesel and Biodiesel Lubrication, J. Mater. Res. Technol., 2013, 2(2), p 110–116

    Article  Google Scholar 

  3. A. Nicolau, C.V. Lutckmeier, D. Samios, M. Gutterres, and C.M.S. Piatnick, The Relation Between Lubricity and Electrical Properties of Low Sulfur Diesel and Diesel/Biodiesel Blends, Fuel, 2014, 117, p 26–32

    Article  CAS  Google Scholar 

  4. A.S.M.A. Haseeb, S.Y. Sia, M.A. Fazal, and H.H. Masjuki, Effect of Temperature on Tribological Properties of Palm Biodiesel, Energy, 2010, 35, p 1460, 1464

    Article  Google Scholar 

  5. M.A. Fazal, A.S.M.A. Haseeb, and H.H. Masjuki, Investigation of Friction and Wear Characteristics of Palm Biodiesel, Energy Convers. Manag., 2013, 67, p 251–256

    Article  CAS  Google Scholar 

  6. M.A. Fazal, A.S.M.A. Haseeb, and H.H. Masjuki, A Critical Review on the Tribological Compatibility of Automotive Materials in Palm Biodiesel, Energy Convers. Manag., 2014, 79, p 180–186

    Article  CAS  Google Scholar 

  7. M.H. Mosarof, M.A. Kalam, H.H. Masjuki, A.M. Ashraful, M.M. Rashed, H.K. Imdadul, and I.M. Monirul, Implementation of a Palm Biodiesel Based on Economic Aspects, Performance, Emission, and Wear Characteristics, Energy Manag., 2015, 105, p 617–629

    CAS  Google Scholar 

  8. F. Sundus, M.A. Fazal, and H.H. Masjuki, Tribology with Biodiesel: A Study on Enhancing Biodiesel Stability and its Fuel Properties, Renew. Sustain. Energy Rev., 2017, 70, p 399–412

    Article  CAS  Google Scholar 

  9. A.K. Agarwal, J.G. Gupta, and A. Dhar, Potential and Challenges for Large-Scale Application of Biodiesel in Automotive Sector, Prog. Energy Combust. Sci., 2017, 61, p 113–149

    Article  Google Scholar 

  10. M. Habibullah, H.H. Masjuki, M.A. Kalam, N.W.M. Zulkifli, B.M. Masum, A. Arslan, and M. Gulzar, Friction and Wear Characteristics of Calophyllum inophyllum Biodiesel, Ind. Crops Prod., 2015, 76, p 188–197

    Article  CAS  Google Scholar 

  11. A. Dhar and A.K. Agarwal, Effect of Karanja Biodiesel Blend on Engine Wear in a Diesel Engine, Fuel, 2014, 134, p 81–89

    Article  CAS  Google Scholar 

  12. M.S. Reddy, N. Sharma, and A.K. Agarwal, Effect of Straight Vegetable Oil and Blends and Biodiesel Blends on Wear of Mechanical Fuel Injection Equipment of a Constant Speed Diesel Engine, Renew. Energy, 2016, 99, p 1008–1018

    Article  Google Scholar 

  13. S.H. Hamdan, W.W.F. Chong, J.-H. Ng, M.J. Ghazali, and R.J.K. Wood, Influence of Fatty Acid Methyl Ester Composition on Tribological Properties of vegetable Oils and Duck Fat Derived Biodiesel, Tribol. Int., 2017, 113, p 76–82

    Article  Google Scholar 

  14. A.S.M. Handbook, Properties and Selection: Irons, Steels, and High-Performance Alloys, Vol 1, ASM International, Russell Township, 1990

    Google Scholar 

  15. Villares Metals, Catalog (2011). (http://www.villaresmetals.com.br). (http://www.villaresmetals.nl/english/files/Cat_SS.pdf).

  16. J.F. Tovell, Ceramics and the Reciprocating Internal Combustion Engine, Mater. Des., 1984, 5, p 215–220

    Article  Google Scholar 

  17. P.J. Blau, Friction and Wear of a Zr-Based Amorphous Metal Alloy Under Dry and Lubricated Conditions, Wear, 2001, 250, p 431–434

    Article  Google Scholar 

  18. J. Qu, J.J. Truhan, and P.J. Blau, Investigation of the Scuffing Characteristics of Candidate Materials for Heavy Duty Diesel Fuel Injectors, Tribol. Int., 2005, 38, p 381–390

    Article  CAS  Google Scholar 

  19. J. Qu, J.J. Truhan, P.J. Blau, and H.M. Meyer, III, Scuffing Transition Diagrams for Heavy Duty Diesel Fuel Injector Materials in Ultra Low-Sulfur Fuel-Lubricated Environment, Wear, 2005, 259, p 1031–1040

    Article  CAS  Google Scholar 

  20. F. Gustavsson, P. Forsberg, and S. Jacobson, Friction and Wear Behavior of Low-Friction Coatings in Conventional and Alternative Fuels, Tribol. Int., 2012, 48, p 22–28

    Article  CAS  Google Scholar 

  21. V.V. Castro, L.A.M. Fontoura, J.D. Benfica, M. Seferin, J.L. Pacheco, and C.A. Santos, Lubricated Sliding Wear of SAE 1045 and SAE 52100 Steel Against Alumina in the Presence of Biodiesel, Diesel and a 50:50 Blend of those Fuels, Wear, 2016, 368–369, p 267–277

    Article  Google Scholar 

  22. ASTM E3–11, Standard Guide for Preparation of Metallographic Specimens, American Society for Testing and Materials, ASM Society, Russell Township p, 2011, p 8

    Google Scholar 

  23. ASTM E 18-03, Standard Test Methods for Rockwell Hardness and Rockwell Superficial Hardness of Metallic Materials, American Society for Testing and Materials, ASM Society, Russell Township, 2004, p 22

    Google Scholar 

  24. ASTM E384-99, Standard Test Method for Microindentation Hardness of Materials, American Society for Testing and Materials, ASM Society, Russell Township, 2000, p 24

    Google Scholar 

  25. ASTM G99-04, Standard Test Method for Wear Testing with a Pin-on-Disk Apparatus, American Society for Testing and Materials, ASM Society, Russell Township, 2004, p 5

    Google Scholar 

  26. M. Hua, X. Wei, and J. Li, Friction and Wear Behavior of SUS 304 Austenitic Stainless Steel Against Al2O3 Ceramic Ball Under Relative High Load, Wear, 2008, 265, p 799–810

    Article  Google Scholar 

  27. J.F. Archard, Contact and Rubbing of Flat Surfaces, J. Appl. Phys., 1953, 24, p 981–988

    Article  Google Scholar 

  28. J.F. Archard and W. Hirst, The Wear of metals Under Unlubricated Conditions, Proceed. R. Soc., 1956, 236–1206, p 397–410

    Article  Google Scholar 

  29. J.K. Lancaster, Material-Specific Wear Mechanism: Relevance to Wear Modelling, Wear, 1990, 141, p 159–183

    Article  CAS  Google Scholar 

  30. EN 14103, Fats and Oil Derivatives—Fatty Acid Methyl Esters (FAME)—Determination of Ester and Linolenic Acid Methyl Esters Contents, European Standard, European Committee for Standardization, Belgium, 2003, p 18

    Google Scholar 

  31. ASTM D 7371-12, Standard Test Method for Determination of Biodiesel (Fatty Acid Methyl Esters) Content in Diesel Fuel Oil Using Mid Infrared Spectroscopy (FTIRATR- PLS Method), American Society for Testing and Materials, ASM Society, Russell Township, 2012, p 10

    Google Scholar 

  32. K.H. Lo, F.T. Cheng, and H.C. Man, Laser Transformation Hardening of AISI, 440C Martensitic Stainless Steel for Higher Cavitation Erosion Resistance, Surf. Coat. Technol., 2003, 173(1), p 96–104

    Article  CAS  Google Scholar 

  33. E. Huttunen-Saarivista, L. Kilpi, T.J. Hakala, L. Carpen, and H. Ronkainen, Tribocorrosion Study of Martensitic and Austenitic Stainless Steels in 0.01 M NaCl Solution, Tribol. Int., 2016, 95, p 358–371

    Article  Google Scholar 

  34. R. Puli and G.D.J. Ram, Microstructures and Properties of Friction Surface Coatings in AISI, 440C Martensitic Stainless Steel, Surf. Coat. Technol., 2012, 207, p 310–318

    Article  CAS  Google Scholar 

  35. H.H. Shen, L. Liu, X.Z. Liu, Q. Guo, T.X. Meng, Z.X. Wang, H.J. Yang, and X.P. Liu, Zr/ZrC Modified Layer Formed on AISI, 440B Stainless Steel by Plasma Zr-Alloying, Appl. Surf. Sci., 2016, 388, p 126–132

    Article  CAS  Google Scholar 

  36. T.X. Meng, Q. Guo, W. Xi, W.Q. Ding, X.Z. Liu, N.M. Lin, S.W. Yu, and X.P. Liu, Effect of Surface Etching on the Oxidation Behavior of Plasma Chromizing-Treated AISI, 440B Stainless Steel, Appl. Surf. Sci., 2018, 433, p 855–861

    Article  CAS  Google Scholar 

  37. V. Goyal, S.K. Sharma, and B.V.M. Kumar, Effect of Lubrication on Tribological Behaviour of Martensitic Stainless Steel, Mater. Today: Proceed., 2015, 2(4-5), p 1082–1091

    Article  Google Scholar 

Download references

Acknowledgments

The authors are grateful to the CNPq (The Brazilian Research Council—Grant Number: 403303/2016-8), FAPERGS (State Foundation for Research of Rio Grande do Sul), CAPES (Coordination for the Improvement of Higher Educational Personnel), and FINEP (Studies and Projects Financing Agency), for their support.

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Correspondence to Carlos Alexandre dos Santos.

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Venske, A.F., de Castro, V.V., da Costa, E.M. et al. Sliding Wear Behavior of an AISI 440B Martensitic Stainless Steel Lubricated with Biodiesel and Diesel–Biodiesel Blends. J. of Materi Eng and Perform 27, 5427–5437 (2018). https://doi.org/10.1007/s11665-018-3626-x

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  • DOI: https://doi.org/10.1007/s11665-018-3626-x

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