Thermophysical Properties of High-Frequency Induction Heat Sintered Graphene Nanoplatelets/Alumina Ceramic Functional Nanocomposites
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This paper concerns the thermophysical properties of high-frequency induction heat (HFIH) sintered alumina ceramic nanocomposites containing various graphene nanoplatelets (GNP) concentrations. The GNP/alumina nanocomposites demonstrated high densities, fine-grained microstructures, highest fracture toughness and hardness values of 5.7 MPa m1/2 and 18.4 GPa, which found 72 and 8%, superior to the benchmarked monolithic alumina, respectively. We determine the role of GNP in tuning the microstructure and inducing toughening mechanisms in the nanocomposites. The sintered monolithic alumina exhibited thermal conductivity value of 24.8 W/mK; however, steady drops of 2, 15 and 19% were recorded after adding respective GNP contents of 0.25, 0.5 and 1.0 wt.% in the nanocomposites. In addition, a dwindling trend in thermal conductions with increasing temperatures was recorded for all sintered samples. Simulation of experimental results with proven theoretical thermal models showed the dominant role of GNP dispersions, microstructural porosity, elastic modulus and grain size in controlling the thermal transport properties of the GNP/alumina nanocomposites. Thermogravimetric analysis showed that the nanocomposite with up to 0.5 mass% of GNP is thermally stable at the temperatures greater than 875 °C. The GNP/alumina nanocomposites owning a distinctive combination of mechanical and thermal properties are promising contenders for the specific components of the aerospace engine and electronic devices having contact with elevated temperatures.
Keywordsceramics interfaces microstructure nanocomposites sintering thermal analysis
The authors would like to extend their sincere appreciation to the Deanship of Scientific Research at King Saud University for funding this Research Group Project No. RG-1437-028.
Conflict of Interest
The authors declare that they have no conflict of interest.
- 28.I. Ahmad, M. Islam, T. Subhani, and Y.Q. Zhu, Toughness Enhancement in Graphene Nanoplatelet/SiC Reinforced Al2O3 Ceramic Hybrid Nanocomposites, Nanotechnology, 2016, 27, p 42Google Scholar
- 31.I. Barin, Thermochemical Data of Pure Substances, VCH, Weinheim, 1993Google Scholar
- 32.N. Takeshi and I. Tadao, Temperature Dependence of Lattice Vibrations and Analysis of the Specific Heat of Graphite, Phys. Rev., 2003, 68, p 399–404Google Scholar
- 41.N.J. Petch, The Cleavage Strength of Polycrystals, J. Iron Steel Inst., 1953, 173, p 25–28Google Scholar
- 46.S.C. Zhang, W.G. Fahrenholtz, G.E. Hilmas, and E.J. Yadlowsky, Pressureless Sintering of Carbon Nanotube-Al2O3 Composites, J. Eur. Ceram. Soc., 2010, 30, p 33–35Google Scholar