Journal of Materials Engineering and Performance

, Volume 27, Issue 4, pp 1635–1641 | Cite as

Electrochemical Behavior of Biomedical Titanium Alloys Coated with Diamond Carbon in Hanks’ Solution

  • S. Gnanavel
  • S. Ponnusamy
  • L. Mohan
  • R. Radhika
  • C. Muthamizhchelvan
  • K. Ramasubramanian


Biomedical implants in the knee and hip are frequent failures because of corrosion and stress on the joints. To solve this important problem, metal implants can be coated with diamond carbon, and this coating plays a critical role in providing an increased resistance to implants toward corrosion. In this study, we have employed diamond carbon coating over Ti-6Al-4V and Ti-13Nb-13Zr alloys using hot filament chemical vapor deposition method which is well-established coating process that significantly improves the resistance toward corrosion, wears and hardness. The diamond carbon-coated Ti-13Nb-13Zr alloy showed an increased microhardness in the range of 850 HV. Electrochemical impedance spectroscopy and polarization studies in SBF solution (simulated body fluid solution) were carried out to understand the in vitro behavior of uncoated as well as coated titanium alloys. The experimental results showed that the corrosion resistance of Ti-13Nb-13Zr alloy is relatively higher when compared with diamond carbon-coated Ti-6Al-4V alloys due to the presence of β phase in the Ti-13Nb-13Zr alloy. Electrochemical impedance results showed that the diamond carbon-coated alloys behave as an ideal capacitor in the body fluid solution. Moreover, the stability in mechanical properties during the corrosion process was maintained for diamond carbon-coated titanium alloys.


corrosion diamond carbon electrochemical impedance HFCVD titanium alloys 


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Copyright information

© ASM International 2018

Authors and Affiliations

  • S. Gnanavel
    • 1
  • S. Ponnusamy
    • 2
  • L. Mohan
    • 4
  • R. Radhika
    • 3
  • C. Muthamizhchelvan
    • 2
  • K. Ramasubramanian
    • 3
  1. 1.Department of Biomedical EngineeringSRM Institute of Science and TechnologyChennaiIndia
  2. 2.Centre for Materials Science and Nano DevicesSRM Institute of Science and TechnologyChennaiIndia
  3. 3.Nano Functional Materials Technology CentreIndian Institute of Technology MadrasChennaiIndia
  4. 4.Surface Engineering DivisionCSIR-National Aerospace LaboratoriesBangaloreIndia

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