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Processing and Characterization of Ag-Cu-Sn Brazing Alloy Prepared by a Mechanical Alloying Method

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Abstract

Mechanical alloying was used to prepare an Ag-Cu-Sn brazing alloy with the low amounts of intermetallic compounds. X-ray diffraction and differential scanning calorimetry were carried out to investigate the phase transformation of the as-milled samples. It seemed that the intermetallic compounds experienced the stage of synthesis-decomposition-resynthesis in the ball milling process. By controlling the ball milling time and tin contents, the solid solution phases of Ag (Cu, Sn) and Ag (Cu) were achieved in the 60Ag30Cu10Sn sample after milling for 40 h. Although the intermetallic compound will be generated during the brazing process, the improvement of their distributed morphology is beneficial for the good bonding interface of the joint with stainless steel substrate.

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References

  1. C.L. Ma, S.B. Xue, and B. Wang, Study on Novel Ag-Cu-Zn-Sn Brazing Filler Metal Bearing Ga, J. Alloys compd., 2016, 688, p p854–862

    Article  Google Scholar 

  2. J. Cao, L.X. Zhang, H.Q. Wang, L.Z. Wu, and J.C. Feng, Effect of Silver Content on Microstructure and Properties of Brass/Steel Induction Brazing Joint Using Ag-Cu-Zn-Sn Filler Metal, J. Mater. Sci. Technol., 2011, 27(4), p 377–381

    Article  Google Scholar 

  3. Y. Liu., J. F. Xu, Q. Y. Zhai, and H. L. Liu, 低蒸汽压中温钎料研究进展 (Research Progress on Medium Temperature Brazing Alloys with Low Vapour Pressure), Foundry Technology. 2011, 32(10), 1435–1438 (in Chinese)

  4. X. Ma, L.F. Li, Z. Zhang, H. Wang, E. Wang, and T. Qiu, Effects of Rare Earth La on Microstructure and Properties of Ag–21Cu–25Sn Alloy Ribbon Prepared by Melt Spinning, Mater. Des., 2015, 83, p 1–5

    Article  Google Scholar 

  5. L.F. Li, T. Qiu, J. Yang, and Y.B. Feng, Effects of Rare Earth La on the Microstructure and Melting Property of (Ag-Cu28)-30Sn Alloys Prepared by Mechanical Alloying, Rare Met., 2011, 30(1), p 49–52

    Article  Google Scholar 

  6. M. Salehisaki, and M. Aryana, Effect of Microstructure on Corrosion Behavior of Ag-30Cu-27Sn Alloy Invitro Media, Appl. Surf. Sci., 2014, 297, p 205–212

    Article  Google Scholar 

  7. C.C. Koch, The Synthesis and Structure of Nanocrystalline Materials Produced by Mechanical Attrition: A Review, Nanostruct. Mater., 1993, 2, p p109–129

    Article  Google Scholar 

  8. S. Sheibani, S. Heshmati-Manesh, and A. Ataie, Structural Investigation on Nano-crystalline Cu-Cr Supersaturated Solid Solution Prepared by Mechanical Alloying, J. Alloys Compd., 2010, 495(1), p 59–62

    Article  Google Scholar 

  9. F. Fang and M. He, Mechanical Alloying of Ag-Cu Immiscible Alloy System, J Shanghai Jiaotong Univ (Sci), 2006, E-11(1), p 84–87

    Google Scholar 

  10. O. Gingu, C. Nicolicescu, and G. Sima, Research of the Milling Time Influence On Ag-Cu Powder Particles Size Processed By Mechanical Alloying Route, Solid State Phenom., 2012, 188, p 382–387

    Article  Google Scholar 

  11. L.F. Li, T. Qiu, J. Yang, and Y.B. Feng, Synthesis of Nanocrystalline Ag-Cu Supersaturated Solid Solution by Mechanical Alloying, Adv. Mater. Res., 2010, 92, p 271–276

    Article  Google Scholar 

  12. L.F. Li, T. Qiu, J. Yang, and Y.B. Feng, Synthesis of Ag-Cu-Sn Nanocrystalline Alloys as Intermediate Temperature Solder by High Energy Ball Milling, Adv. Mater. Res., 2009, 79–82, p 449–452

    Article  Google Scholar 

  13. D.K. Basri, L. Sisamouth, Y. Farazila, Y. Miyazawa, and T. Ariga, Brazeability and Mechanical Properties of Ag-Cu-Sn Brazing Filler Metals on Copper-Brazed Joint, Mater. Res. Innov., 2014, 18(S6), p p429–432

    Google Scholar 

  14. D.M. Jafarlou, E. Zalnezhad, M.A. Ezazi, N.A. Mardi, and M.A. Hassan, The Application of Equal Channel Angular Pressing to Join Dissimilar Metals, Aluminium Alloy and Steel, using an Ag-Cu-Sn Interlayer, Mater. Des., 2015, 87, p p553–566

    Article  Google Scholar 

  15. J.P. Hammond, S.A. David, and J.J. Woodhouse, Process for Forming Unusually Strong Joints Between Metals and Ceramics by Brazing at Temperatures that do no Exceed 750 degree C., US 4621761 A

  16. E. Ma and M. Atzmon, Calorimetric Evidence for Polymorphous Constraints on Metastable Zr-Al Phase Formation by Mechanical Alloying, J. Phys. Rev. Lett., 1991, 67(9), p 1126–1129

    Article  Google Scholar 

  17. M. Oehringand and R. Bormann, NanocrystallineAlloys Prepared by Mechanical Alloying and Ball Milling, Mater. Sci. Eng., 1991, 134, p 1330–1333

    Article  Google Scholar 

  18. R.S. Maurya and T. Laha, Effect of Rare Earth and Transition Metal Elements on the Glass Forming Ability of Mechanical Alloyed Al-TM-RE Based Amorphous Alloys, J. Mater. Sci. Tech., 2015, 31(11), p 1118–1124

    Article  Google Scholar 

  19. Q.Y. Zhang and H.S. Zhuang, Manual of the Ternary alloy phase diagrams, China Machine Press, Beijing, 2011

    Google Scholar 

Download references

Acknowledgments

This work was financially supported by Huaguang Advanced Welding Materials Co., LTD under Grant No. H131064.

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Correspondence to Peng He.

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Liu, W., Zheng, M., Wang, X. et al. Processing and Characterization of Ag-Cu-Sn Brazing Alloy Prepared by a Mechanical Alloying Method. J. of Materi Eng and Perform 27, 1148–1153 (2018). https://doi.org/10.1007/s11665-017-2930-1

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  • DOI: https://doi.org/10.1007/s11665-017-2930-1

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