Abstract
In this work, effects of isothermal aging on phase transformation, microstructure evolution, hardness and wear resistance of the wrought Co-Cr-Mo alloy with low carbon content were investigated. Initially, temperature range of FCC to HCP phase transformation of the alloy was determined by a dilatometer test. Then, aging at the temperature of 850 °C for different holding times with subsequent water quenching was carried out. Metallography examination, x-ray diffraction analysis, microhardness test and wear test were performed for Co-Cr-Mo alloy specimens after the isothermal aging. It was found that the FCC to HCP phase transformation occurred in the temperature range between 700 and 970 °C. During the aging treatment, phase fraction of the HCP martensite increased with longer aging time. The FCC to HCP phase transformation was completed after 12 h, because very fine lamellae in different orientations thoroughly dispersed within FCC grains were observed. These lamella structures could be well correlated with formation of the HCP martensite. Small amounts of carbides were found at grain boundaries and grain intersections in the samples aged for 6 and 12 h. In addition, by longer aging time, the average grain size of the aged alloy became a little bit larger, while the hardness noticeably increased. For the examined Co-Cr-Mo alloy, higher amount of the emerged HCP martensitic phase led to the increased hardness value, but reduced friction coefficient and wear rate.
Similar content being viewed by others
References
M. Niinomi, Recent Metallic Materials for Biomedical Applications, Metall. Mater. Trans. A, 2002, 33, p 478–486
R. Pilliar and S.D. Ramsay, Cobalt-Base Alloys, Materials for Medical Devices, ASM Handb., 2012, 23, p 211–219
S. Yang, Cryogenic Burnishing of Co–Cr–Mo Biomedical Alloy for Enhanced Surface Integrity and Improved Wear Performance. Dissertation; 2012, University of Kentucky, USA, p 1–45
P.V. Muterlle, Microstructural and Mechanical Properties of Co and Ti Alloys for Biomedical Applications Produced by Metal Injection Molding (MIM). Dissertation; 2010, University of Trento, Italy, p 14–24
K.P. Gupta, The Co–Cr–Mo (Cobalt–Chromium–Molybdenum) System, J Phase Equilibria Diffusion, 2005, 26(1), p 87–92
R.T. Estrada, A.S. Rodriguez, and H.F. Lopez, FCC to HCP Transformation Kinetics in a Co–27Cr–5Mo–0.23C Alloy, J. Mater. Sci., 2011, 46, p 254–262
E. Rabinowicz, Friction and Wear of Materials, 2nd ed., Wiley, New York, 1995
K. Rajan, Phase Transformations in a Wrought Co–Cr–Mo–C Alloy, Metall. Trans., 1982, 13A, p 1161–1182
C. Song, H. Park, H. Seong, and H.F. Lopez, Development of Athermal and Isothermal ε-Martensite in Atomized Co–Cr–Mo–C Implant Alloy Powders, Metall. Mater. A, 2006, 37, p 3197–3203
A.J.S. Garcia, A.M. Medrano, and A.S. Rodriguez, Formation of HCP Martensite During the Isothermal Aging of an FCC Co–27Cr–5Mo–0.05C Orthopedic Implant Alloy, Metall. Mater. A, 1999, 30, p 1177–1184
S.H. Lee, E. Takahashi, N. Nomura, and A. Chiba, Effect of Carbon Addition on Microstructure and Mechanical Properties of a Wrought Co–Cr–Mo Implant Alloy, Mater. Trans., 2006, 47(2), p 287–290
H.F. Lopez and A.J. Saldivar Garcia, Martensitic Transformation in a Cast Co–Cr–Mo–C Alloy, Metall. Mater. A, 2008, 39, p 8–16
A.S. Taha and F.H. Hammad, Application of the Hall-Petch Relation to Microhardness Measurements on Al, Cu, Al–MD 105, and Al–Cu Alloys, Phys. Status Solidi (a), 1990, 119, p 455–462
Acknowledgments
The authors would like to acknowledge the “King Mongkut’s University of Technology Thonburi”, “KMUTT 55th Anniversary Commemorative Fund” and “Iron and Steel Institute of Thailand” for supporting the heat treatment, “Thai Parkerizing Ltd.” for supporting the tribometer, “Thai—German Institute” for supporting the wear measurement and “Celestica (Thailand) Ltd.” for metallography analysis.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Khaimanee, P., Choungthong, P. & Uthaisangsuk, V. Effects of Isothermal Aging on Microstructure Evolution, Hardness and Wear Properties of Wrought Co-Cr-Mo Alloy. J. of Materi Eng and Perform 26, 955–968 (2017). https://doi.org/10.1007/s11665-017-2525-x
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11665-017-2525-x