Abstract
Surface-textured Mo thin film is fabricated by magnetron sputtering through the adjustment of deposition parameters, which exhibits a high absorptance of 0.80 and a low emittance of 0.09. The single-layer Mo deposited on stainless steel (SS) is characterized by x-ray diffraction (XRD), ultra-high resolution scanning electron microscope, atomic force microscope and optical measurement. The controlled surface roughness combined with larger aspect ratio contributes much to the high absorptance and low emittance. Based on the SS/Mo coating, a spectrally selective coating (SS/Mo/Al2O3) is designed and fabricated. The coating shows an amorphous structure and exhibits an absorptance of 0.90 and an emittance of 0.08. Tauc-Lorentz and Drude free-electron models are used to modeling the optical properties of Al2O3 and Mo layers by phase-modulated spectroscopic ellipsometry.
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Q. Geng, X. Zhao, X. Gao, H. Yu, and S. Yang, Optimization Design of CuCrxMn2-xO4-Based Paint Coatings Used for Solar Selective Applications, Sol. Energy Mater. Sol. Cells, 2012, 105, p 293–301
S.K. Kumar, S. Suresh, S. Murugesan, and S.P. Raj, CuO Thin Films Made of Nanofibers for Solar Selective Absorber Applications, Sol. Energy, 2013, 94, p 299–304
D. Katzen, E. Levy, and Y. Mastai, Thin Films of Silica-Carbon Nanocomposites for Selective Solar Bsorbers, Appl. Surf. Sci., 2005, 248, p 514–517
C.E. Kennedy, Review of Mid- to High-Temperature Solar Selective Absorber Materials, NREL/TP-520-31267, National Renewable Energy Laboratory, Colorado, 2002
F. Cao, K. McEnaney, G. Chen, and Z. Ren, A Review of Cermet-Based Spectrally Selective Solar Absorbers, Energy Environ. Sci., 2014, 7, p 1615–1627
Q.-C. Zhang, Y. Yin, and D.R. Mills, High Efficiency Mo-Al2O3 Cermet Selective Surfaces for High-Temperature Application, Sol. Energy Mater. Sol. Cells, 1996, 40, p 43–53
E. Céspedes, M. Wirz, J.A. Sánchez-García, L. Alvarez-Fraga, R. Escobar-Galindo, and C. Prieto, Novel Mo-Si3N4 Based Selective Coating for High Temperature Concentrating Solar Power Applications, Sol. Energy Mater. Sol. Cells, 2014, 122, p 217–225
A. Antonaia, A. Castaldo, M.L. Addonizio, and S. Esposito, Stability of W-Al2O3 Cermet Based Solar Coating for Receiver Tube Operating at High Temperature, Sol. Energy Mater. Sol. Cells, 2010, 94, p 1604–1611
F. Cao, D. Kraemer, T. Sun, Y. Lan, G. Chen, and Z. Ren, Enhanced Thermal Stability of W-Ni-Al2O3 Cermet-Based Spectrally Selective Solar Absorbers with Tungsten Infrared Reflectors, Adv. Energy Mater., 2015, 5, p 1401042
Y. Xue, C. Wang, W. Wang, Y. Liu, Y. Wu, Y. Ning, and Y. Sun, Spectral Properties and Thermal Stability of Solar Selective Absorbing AlNi-Al2O3 Cermet Coating, Sol. Energy, 2013, 96, p 113–118
S. Esposito, A. Antonaia, M.L. Addonizio, and S. Aprea, Fabrication and Optimisation of Highly Efficient Cermet-Based Spectrally Selective Coatings for High Operating Temperature, Thin Solid Films, 2009, 517, p 6000–6006
Q.-C. Zhang, Y. Yin, and D.R. Mills, High Efficiency Mo-Al2O3 Cermet Selective Surfaces for High-Temperature Application, Sol. Energy Mater. Sol. Cells, 1996, 40, p 43–53
Y. Liu, Z. Wang, D. Lei, and C. Wang, A New Solar Spectral Selective Absorbing Coating of SS-(Fe3O4)/Mo/TiZrN/TiZrON/SiON for High Temperature Application, Sol. Energy Mater. Sol. Cells, 2014, 127, p 143–146
A. Lasagni, M. Nejati, R. Clasen, and F. Mücklich, Periodical Surface Structuring of Metals by Laser Interference Metallurgy as a New Fabrication Method Of Textured Solar Selective Absorbers, Adv. Eng. Mater., 2006, 8, p 580–584
A.A. Shah and M.C. Gupta, Spectral Selective Surfaces for Concentrated Solar Power Receivers by Laser Sintering of Tungsten Micro and Nano Particles, Sol. Energy Mater. Sol. Cells, 2013, 117, p 489–493
V. Teixeira, E. Sousa, M.F. Costa, C. Nunes, L. Rosa, M.J. Carvalho, M. Collares-Pereira, E. Roman, and J. Gago, Spectrally Selective Composite Coatings of Cr-Cr2O3 and Mo-Al2O3 for Solar Energy Applications, Thin Solid Films, 2001, 392, p 320–326
H. Saia, H. Yugamia, Y. Kanamorib, and K. Hane, Solar Selective Absorbers Based on Two-Dimensional W Surface Gratings with Submicron Periods for High-Temperature Photo Thermal Conversion, Sol. Energy Mater. Sol. Cells, 2003, 79, p 35–49
F. Ghmari, T. Ghbara, M. Laroche, R. Carminati, and J.-J. Greffet, Influence of Microroughness on Emissivity, J. Appl. Phys., 2004, 96, p 2656–2664
S. Lal, S. Link, and N.J. Halas, Nano-optics From Sensing to Waveguiding, Nat. Photonics, 2007, 1, p 641–648
X. He, Y. Li, L. Wang, Y. Sun, and S. Zhang, High Emissivity Coatings for High Temperature Application: Progress and Prospect, Thin Solid Films, 2009, 517, p 5120–5129
A. Biswas, D. Bhattacharyya, H.C. Barshilia, N. Selvakumar, and K.S. Rajam, Spectroscopic Ellipsometric Characterization of TiAlN/TiAlON/Si3N4 Tandem Absorber for Solar Selective Applications, Appl. Surf. Sci., 2008, 254, p 1694–1699
G.E. Jellison, Jr, and F.A. Modine, Parameterization of the optical functions of amorphous materials in the interband region, Appl. Phys. Lett., 1996, 69, p 371–373
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This work was financially supported by NSFC (51402315), the Western Light Talents Training Program of CAS and the Science and Technology Support Program of Gansu Province (Grant 1304GKCA025).
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Gao, XH., Guo, ZM., Geng, QF. et al. Microstructure and Optical Properties of SS/Mo/Al2O3 Spectrally Selective Solar Absorber Coating. J. of Materi Eng and Perform 26, 161–167 (2017). https://doi.org/10.1007/s11665-016-2445-1
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DOI: https://doi.org/10.1007/s11665-016-2445-1