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Studies on Adsorption and Corrosion Inhibitive Properties of Indoline Compounds on N80 Steel in Hydrochloric Acid

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Abstract

Corrosion inhibition performance of synthesized indoline compounds, namely, 3′-(4-(1-acetyl-5-(4-methoxyphenyl)-4,5-dihydro-1H-pyrazol-3-yl)phenyl)spiro[indoline-3,2′-thiazolidine]-2,4′-dione (MPIT) and 1-(4-(1-acetyl-5-(4-methoxyphenyl)-4,5-dihydro-1H-pyrazol-3-yl)phenyl)spiro[imidazolidine-2,3′-indoline]-2′,5-dione (MPII) on N80 steel in 15% HCl solution was studied using weight loss measurement, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) techniques. Polarization studies showed that both studied inhibitors were of mixed type in nature. The adsorption of inhibitors on the N80 steel surface obeys Langmuir adsorption isotherm. The potential of zero charge (E PZC) for the N80 steel was determined by EIS method. Scanning electron microscopy, energy-dispersive x-ray spectroscopy, and atomic force microscopy were used to characterize the surface morphology of uninhibited and inhibited N80 steel specimens. The density functional theory was employed for theoretical calculations.

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References

  1. M. Yadav, D. Behera, and U. Sharma, Corrosion Protection of N80 Steel in Hydrochloric Acid by Substituted Amino Acids, Corros. Eng. Sci. Technol., 2013, 48, p 19–27

    Article  Google Scholar 

  2. M. Yadav, D. Behera, and U. Sharma, Nontoxic Corrosion Inhibitors for N80 Steel in Hydrochloric Acid, Arab. J. Chem., 2012, doi:10.1016/j.arabjc.2012.03.011.

  3. M. Yadav and U. Sharma, Eco-Friendly Corrosion Inhibitors for N80 Steel in Hydrochloric Acid, J. Mater. Environ. Sci., 2011, 2, p 407–414

    Google Scholar 

  4. M. Yadav, S. Kumar, and D. Sharma, Experimental and Quantum Chemical Studies on Corrosion Inhibition Effect of Synthesized Organic Compounds on N80 Steel in Hydrochloric Acid, Ind. Eng. Chem. Res., 2013, 52, p 14019–14029

    Article  Google Scholar 

  5. S. Vishwanatham and P.K. Sinha, Corrosion Protection of N80 Steel in HCl by Condensation Products of Aniline and Phenol, Anti-Corros. Methods Mater., 2009, 56, p 139–144

    Article  Google Scholar 

  6. T. Kumar, S. Vishawanatam, and G. Udaybhanu, Synergistic Effect of Formaldehyde and Alcoholic Extract of Plants Leaves for Protection of N80 Steel in 15% HCl, Corros. Eng. Sci. Technol., 2004, 39, p 327–332

    Article  Google Scholar 

  7. R. Solmaz, G. Kardaş, M. Çulha, and M. Erbil, Investigation of Adsorption and Inhibitive Effect of 2-Mercaptothiazoline on Corrosion of Mild Steel in Hydrochloric Acid Media, Electrochim. Acta, 2008, 53, p 5941–5952

    Article  Google Scholar 

  8. D. Bhambi, C. Sharma, V.K. Salvi, and G.L. Talesara, Synthesis and Pharmacological Studies of Some Phthalimidoxy Substituted Spiro- Thiazolidinone Derivatives of Isatin, Indian J. Chem. B, 2009, 48, p 1006–1012

    Google Scholar 

  9. I.B. Obot and N.O. Obi-Egbedi, Indeno-1-one [2,3-b]quinoxaline as an effective inhibitor for the corrosion of mild steel in 0.5 M H2SO4 solution, Mater. Chem. Phys., 2010, 122, p 325–328

    Article  Google Scholar 

  10. C. Lee, W. Yang, and R.G. Parr, Development of the Colle-Salvetti Correlation-Energy Formula into a Functional of the Electron Density, Phys. Rev. B, 1988, 37, p 785–789

    Article  Google Scholar 

  11. A.D. Becke, A New Mixing of Hartree-Fock and Local Density-Functional Theories, J. Chem. Phys., 1993, 98, p 1372–1377

    Article  Google Scholar 

  12. X. Wang, H. Yang, and F. Wang, An Investigation of Benzimidazole Derivative as Corrosion Inhibitor for Mild Steel in Concentrated HCl Solutions, Corros. Sci., 2011, 53, p 113–121

    Article  Google Scholar 

  13. D. Jayaperumal, Effect of Alcohol Based Inhibitors on Corrosion of Mild Steel in Hydrochloric Medium, Mater. Chem. Phys., 2010, 119, p 478–484

    Article  Google Scholar 

  14. E.S. Ferreira, C. Giancomlli, F.C. Giacomlli, and A. Spinelli, Evaluation of the Inhibitor Effect of l-Ascorbic Acid on the Corrosion of Mild Steel, Mater. Chem. Phys., 2004, 83, p 129–134

    Article  Google Scholar 

  15. M. Lebrini, F. Robert, A. Lecante, and C. Roos, Corrosion Inhibition of C38 Steel in 1 M Hydrochloric Acid Medium by Alkaloids Extract from Oxandra asbeckii plant, Corros. Sci., 2007, 49, p 2254–2269

    Article  Google Scholar 

  16. H. Gerengi and H.I. Sahin, Schinopsis lorentzii Extract as a Green Corrosion Inhibitor for Low Carbon Steel in 1 M HCl Solution, Ind. Eng. Chem. Res., 2012, 51, p 780–787

    Article  Google Scholar 

  17. B. El Mehdi, B. Mernari, M. Traisnel, F. Bentiss, and M. Lagrenee, Synthesis and Comparative Study of the Inhibitive Effect of Some New Triazole Derivatives Towards Corrosion of Mild Steel in Hydrochloric Acid Solution, Mater. Chem. Phys., 2002, 77, p 489–496

    Article  Google Scholar 

  18. M. Behpour, S.M. Ghoreishi, N. Soltani, M. Salavati-Niasari, M. Hamadanian, and A. Gandomi, Electrochemical and Theoretical Investigation on the Corrosion Inhibition of Mild Steel by Thiosalicylaldehyde Derivatives in Hydrochloric Acid Solution, Corros. Sci., 2008, 50, p 2172–2181

    Article  Google Scholar 

  19. R.G. Pearson, Absolute Electronegativity and Hardness: Application to Inorganic Chemistry, Inorg. Chem., 1988, 27, p 734–740

    Article  Google Scholar 

  20. A.Y. Musa, A.H. Kadhum, A.B. Mohamad, and M.S. Takriff, Experimental and Theoretical Study on the Inhibition Performance of Triazole Compounds for Mild Steel Corrosion, Corros. Sci., 2010, 52, p 3331–3340

    Article  Google Scholar 

  21. P. Mourya, S. Banerjee, R.B. Rastogi, and M.M. Singh, Inhibition of Mild Steel Corrosion in Hydrochloric and Sulfuric Acid Media Using a Thiosemicarbazone Derivative, Ind. Eng. Chem. Res., 2013, 52, p 12733–12747

    Article  Google Scholar 

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Acknowledgment

Authors acknowledge Indian School of Mines, Dhanbad for financial support.

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  1. Department of Applied Chemistry, Indian School of Mines, Dhanbad, 826004, India

    M. Yadav, T. K. Sarkar & Taniya Purkait

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  1. M. Yadav
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Yadav, M., Sarkar, T.K. & Purkait, T. Studies on Adsorption and Corrosion Inhibitive Properties of Indoline Compounds on N80 Steel in Hydrochloric Acid. J. of Materi Eng and Perform 24, 4975–4984 (2015). https://doi.org/10.1007/s11665-015-1765-x

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  • DOI: https://doi.org/10.1007/s11665-015-1765-x

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