Abstract
The effect of heat treatment on the microstructure, electrical conductivity, and tensile strength of deformation-processed Cu-7Cr in situ composites produced by thermo-mechanical processing was investigated. The Cr fibers in the Cu-7Cr in situ composite underwent coarsening, break-up, and spheroidization after exposure to elevated temperatures. The conductivity and tensile strength of the in situ composite first increased with increasing isochronal heat treatment temperature, reached a peak value, and decreased at higher temperatures. The isothermal heat treatment temperature was determined to be 625 °C. The Z (Z is an optimization parameter to evaluate the service performance of deformation-processed Cu-based in situ composites) value of the deformation-processed Cu-7Cr in situ composite, at η = 7 (η is a cumulative cold deformation strain) after the heat treatment at 625 °C for 1 h, reached the peak value of 3.46 × 107 MPa2 % International Annealed Copper Standard (IACS). The isochronal heat treatment time was determined to be 1 h. The following combination of conductivity and tensile strength of the deformation-processed Cu-7Cr in situ composite with a cumulative cold deformation strain of eight after isochronal aging treatments for 1 h could be attained respectively as (i) 76.0% IACS and 889 MPa; (ii) 76.8% IACS and 876 MPa; or (iii) 77.5% IACS and 779 MPa.
Similar content being viewed by others
References
X. Sauvage, P. Jessner, F. Vurpillot, and R. Pippan, Nanostructure and Properties of a Cu-Cr Composite Processed by Severe Plastic Deformation, Scr. Mater., 2008, 58, p 1125–1128
D. Raabe, S. Ohsaki, and K. Hono, Mechanical Alloying and Amorphization in Cu-Nb-Ag In Situ Composite Wires Studied by Transmission Electron Microscopy and Atom Probe Tomography, Acta Mater., 2009, 57, p 5254–5263
Z.X. Xie, H.Y. Gao, J. Wang, and B.D. Sun, Effect of Homogenization Treatment on Microstructure and Properties for Cu-Fe-Ag In Situ Composites, Mater. Sci. Eng. A, 2011, 529, p 388–392
J.P. Ge, H. Zhao, Z.Q. Yao, and S.H. Liu, Microstructure and Properties of Deformation-Processed Cu-Fe In Situ Composites, Trans. Nonferrous Met. Soc. China, 2005, 15, p 971–977
H. Fernee, J. Nairn, and A. Atrens, Precipitation Hardening of Cu-Fe-Cr Alloys, Part I, Mechanical and Electrical Properties, J. Mater. Sci., 2001, 36, p 2711–2719
Y.S. Kim, J.S. Song, and S.I. Hong, Thermo-Mechanical Processing and Properties of Cu-Fe-Cr Microcomposites, J. Mater. Process. Technol., 2002, 130–131, p 278–282
S.I. Hong, J.S. Song, and H.S. Kim, Thermo-Mechanical Processing and Properties of Cu-9Fe-1.2Co Microcomposite Wires, Scr. Mater., 2001, 45, p 1295–1300
K.L. Lee, The Thermo-Mechanical Behaviour of Cu-Cr In Situ Composite, J. Mater. Sci., 2004, 39, p 3047–3055
D. Raabe and J. Ge, Experimental Study on the Thermal Stability of Cr Filaments in a Cu-Cr-Ag In Situ Composite, Scr. Mater., 2004, 51, p 915–920
Y. Jin, K. Adachi, T. Takeuchi, and H.G. Suzuki, Ageing Characteristics of Cu-Cr In Situ Composite, J. Mater. Sci., 1998, 33, p 1333–1341
J.Q. Deng, X.Q. Zhang, S.Z. Shang, F. Liu, Z.X. Zhao, and Y.F. Ye, Effect of Zr Addition on the Microstructure and Properties of Cu-10Cr In Situ Composites, Mater. Des., 2009, 30, p 4444–4449
K.M. Liu, D.P. Lu, H.T. Zhou, A. Atrens, Z.B. Chen, J. Zou, and S.M. Zeng, Influence of Ag Micro-alloying on the Microstructure and Properties of Cu-7Cr In Situ Composite, J. Alloys Compd., 2010, 500, p L22–L25
H. Gao, J. Wang, and B. Sun, Effect of Ag on the Thermal Stability of Deformation Processed Cu-Fe In Situ Composites, J. Alloys Compd., 2009, 469, p 580–586
J.S. Song, S.I. Hong, and Y.G. Park, Deformation Processing and Strength/Conductivity Properties of Cu-Fe-Ag Microcomposites, J. Alloys Compd., 2005, 388, p 69–74
H. Gao, J. Wang, D. Shu, and B. Sun, Effect of Ag on the Aging Characteristics of Cu-Fe In Situ Composites, Scr. Mater., 2006, 54, p 1931–1935
W.A. Spitzig, L.S. Chumbley, J.D. Verhoeven, Y.S. Go, and H.L. Downing, Effect of Temperature on the Strength and Conductivity of a Deformation Processed Cu-20%Fe Composite, J. Mater. Sci., 1992, 27, p 2005–2011
F. Heringhaus, H. Schneider-Muntau, and G. Gottstein, Analytical Modeling of the Electrical Conductivity of Metal Matrix Composites: Application to Ag-Cu and Cu-Nb, Mater. Sci. Eng. A, 2003, 347, p 9–20
K.M. Liu, D.P. Lu, H.T. Zhou, A. Atrens, J. Zou, Y.L. Yang, and S.M. Zeng, Effect of Ag Micro-alloying on the Microstructure and Properties of Cu-14Fe In Situ Composite, Mater. Sci. Eng. A, 2010, 527, p 4953–4958
K.M. Liu, D.P. Lu, H.T. Zhou, Z.B. Chen, A. Atrens, and L. Lu, Influence of a High Magnetic Field on the Microstructure and Properties of a Cu-Fe-Ag In Situ Composite, Mater. Sci. Eng. A, 2013, 584, p 114–120
H. Gao, J. Wang, D. Shu, and B. Sun, Microstructure and Properties of Cu-11Fe-6Ag In Situ Composite After Thermo-Mechanical Treatments, J. Alloys Compd., 2007, 438, p 268–273
L.M. Peng, X.M. Mao, K.D. Xu, and W.J. Ding, Property and Thermal Stability of In Situ Composite Cu-Cr Alloy Contact Cable, J. Mater. Process. Technol., 2005, 166, p 193–198
K.M. Liu, D.P. Lu, H.T. Zhou, Y.L. Yang, A. Atrens, and J. Zou, Microstructure and Properties of a Deformation-Processed Cu-Cr-Ag In Situ Composite by Directional Solidification, J. Mater. Eng. Perform., 2013, 22, p 3723–3727
J.S. Song, H.S. Kim, C.T. Lee, and S.I. Hong, Deformation Processing and Mechanical Properties of Cu-Cr-X (X = Ag or Co) Microcomposites, J. Mater. Process. Technol., 2002, 130–131, p 272–277
K.M. Liu, Z.Y. Jiang, J.W. Zhao, J. Zou, Z.B. Chen, and D.P. Lu, Effect of Directional Solidification Rate on the Microstructure and Properties of Deformation-Processed Cu-7Cr-0.1Ag In Situ Composites, J. Alloys Compd., 2014, 612, p 221–226
Acknowledgments
This project was supported by the National Natural Science Foundation of China (51461018), the International Science and Technology Cooperation Project of Jiangxi Province (20151BDH80006), the Key Program of Natural Science Foundation of Jiangxi Province (20133BAB20008; 20144ACB20013), the Science and Technology Innovation Team Project of Jiangxi Province (20115BCB29018), and the China Scholarship Council (2011836024).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Liu, K., Jiang, Z., Zhou, H. et al. Effect of Heat Treatment on the Microstructure and Properties of Deformation-Processed Cu-7Cr In Situ Composites. J. of Materi Eng and Perform 24, 4340–4345 (2015). https://doi.org/10.1007/s11665-015-1747-z
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11665-015-1747-z