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Effect of Quenching Process on the Microstructure and Hardness of High-Carbon Martensitic Stainless Steel

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Abstract

The microstructure and hardness of high-carbon martensitic stainless steel (HMSS) were investigated using thermal expansion analyzer, Thermo-calc, scanning electron microscope, x-ray diffraction, and Ultra-high temperature confocal microscope. The results indicate that the experimental steel should be austenitized in the temperature range of 1025-1075 °C, which can give a maximum hardness of 62 HRc with the microstructure consisting of martensite, retained austenite, and some undissolved carbides. With increasing austenitizing temperature, the amount of retained austenite increases, while the volume fraction of carbides increases first and then decreases. The starting temperature and finish temperature of martensite formation decrease with increasing cooling rates. Air-quenched samples can obtain less retained austenite, more compact microstructure, and higher hardness, compared with that of oil-quenched samples. For HMSS, the martensitic transformation takes place at some isolated areas with a slow nucleation rate.

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References

  1. L.D. Barlow and M. Du Toit, Effect of Austenitizing Heat Treatment on the Microstructure and Hardness of Martensitic Stainless Steel AISI, 420, J. Mater. Eng. Perform., 2012, 21, p 1327–1336

    Article  Google Scholar 

  2. A.T. Behnam, A. Fakhreddin, and H. Ali Morad, Influence of Retained Austenite on the Mechanical Properties of Low Carbon Martensitic Stainless Steel Castings, ISIJ Int., 2011, 51(3), p 471–475

    Article  Google Scholar 

  3. A. Rajasekhar, G.M. Reddy, T. Mohandas, and V.S.R. Murti, Influence of Austenitizing Temperature on Microstructure and Mechanical Properties of AISI, 431 Martensitic Stainless Steel Electron Beam Welds, Mater. Des., 2009, 30, p 1612–1624

    Article  Google Scholar 

  4. S.C. Krishna, N.K. Gangwar, A.K. Jha, B. Pant, and K.M. George, Effect of Heat Treatment on the Microstructure and Hardness of 17Cr-0.17N-0.43C-1.7Mo Martensitic Stainless Steel, J. Mater. Eng. Perform., 2015, 24, p 1656–1662

    Article  Google Scholar 

  5. M. Kianezhad and S.A. Sajjadi, Improvement of Quench Factor Analysis in Phase and Hardness Prediction of a Quenched Steel, Metall. Mater. Trans. A, 2013, 44, p 2053–2059

    Article  Google Scholar 

  6. S.K. Ghosh and S. Mondal, Effect of Heat Treatment on Microstructure and Mechanical Properties of Duplex Stainless Steel, Trans. Indian Inst. Met., 2008, 61(1), p 33–37

    Article  Google Scholar 

  7. J.Y. Li, P. Zhao, J. Yanagimoto, S. Sugiyama, and Y.L. Chen, Effects of Heat Treatment on the Microstructures and Mechanical Properties of a New Type of Nitrogen-Containing Die Steel, Int. J. Miner. Metall. Mater., 2012, 19(6), p 511–517

    Article  Google Scholar 

  8. Z.L. Song, X.D. Du, Y.Q. Chen, J.Q. Wang, C. Ye, and L.Y. Li, Trans. Mater. Heat. Treat., 2011, 32(5), p 95–99

    Google Scholar 

  9. W.X. Song, Metallography, 2nd ed., Metallurgical Industry Press, Beijing, 2010, p 353

    Google Scholar 

  10. S.Y. Lu, K.F. Yao, Y.B. Chen, M.H. Wang, Y. Shao, and X.Y. Ge, Effects of Austenitizing Temperature on the Microstructure and Electrochemical Behavior of a Martensitic Stainless Steel, J. Appl. Electrochem., 2015, 45, p 375–383

    Article  Google Scholar 

  11. J.Y. Park and Y.S. Park, The Effects of Heat-Treatment Parameters on Corrosion Resistance and Phase Transformations of 14Cr-3Mo Martensitic Stainless Steel, Mater. Sci. Eng. A, 2007, 449, p 1131–1134

    Article  Google Scholar 

  12. H.G. Fu, Y.H. Qu, J.D. Xing, X.H. Zhi, Z.Q. Jiang, M.W. Li, and Y. Zhang, Investigations on Heat Treatment of a High-Speed Steel Roll, J. Mater. Eng. Perform., 2008, 17, p 535–542

    Article  Google Scholar 

  13. C. Garcia De Andres, L.F. Alvarez, and V. Lopez, Effects of Carbide-Forming Elements on the Response to Thermal Treatment of the X45Cr13 Martensitic Steel, J. Mater. Sci., 1998, 33(16), p 4095–4100

    Article  Google Scholar 

  14. M.A. Alvarado-Meza, E. Garcia-Sanchez, O. Covarrubias-Alvarado, A. Salinas-Rodriguez, M.P. Guerrero-Mata, and R. Colas, Effect of the High-Temperature Deformation on the M s Temperature in a Low C Martensitic Stainless Steel, J. Mater. Eng. Perform., 2013, 22, p 345–350

    Article  Google Scholar 

  15. B.B. He and M.X. Huang, Revealing the Intrinsic Nanohardness of Lath Martensite in Low Carbon Steel, Metall. Mater. Trans. A, 2015, 46, p 688–694

    Article  Google Scholar 

  16. Y.H. He, Q.H. Rao, and Y.H. Tan, Investigation on the Morphology of Martensite in Carbon Steels, J. Cent. South Univ. Technol, 1996, 3(2), p 122–134

    Article  Google Scholar 

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Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (Grant No. 51444004), and China Postdoctoral Science Foundation (Grant No. 2014M560047).

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Correspondence to Qin-tian Zhu.

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Zhu, Qt., Li, J., Shi, Cb. et al. Effect of Quenching Process on the Microstructure and Hardness of High-Carbon Martensitic Stainless Steel. J. of Materi Eng and Perform 24, 4313–4321 (2015). https://doi.org/10.1007/s11665-015-1723-7

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  • DOI: https://doi.org/10.1007/s11665-015-1723-7

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