Abstract
The scanning vibrating electrode technique (SVET) has been used to study the in-situ corrosion phenomena on AA2024T3 aluminum alloy. Three distinct sequential stages of corrosion attack, with time, on the alloy have been revealed (0-75, 75-180 min, and after 180 min). The increase and decrease in the intensity of the anodic activities at the surface of the alloy, which give a corresponding increase and decrease in the net current density values, with time, are responsible for the stepwise changes in the corrosion stages. The work also revealed mild etch-like attack regions on the surface of the alloy after the immersion test.
Similar content being viewed by others
References
D. Dzhurinskiy, E. Maeva, E. Leshchinsky, and R.G. Maev, Corrosion Protection of Light Alloys Using Low Pressure Cold Spray, J. Therm. Spray Technol., 2012, 21(2), p 304–313
C. Luo, X. Zhou, G.E. Thompson, and A.E. Hughes, Observations of Intergranular Corrosion in AA2024-T351: The Influence of Grain Stored Energy, Corros. Sci., 2012, 61, p 35–44
Y. Tan, Understanding the Effects of Electrode Inhomogeneity and Electrochemical Heterogeneity on Pitting Corrosion Initiation on Bare Electrode Surfaces, Corros. Sci., 2011, 53(5), p 1845–1864
A. Hughes, A. Boag, and A. Glenn, Corrosion of AA2024-T3 Part II: Co-operative Corrosion, Corros. Sci., 2011, 53(1), p 27–39
W. Zhang and G. Frankel, Anisotropy of Localized Corrosion in AA2024-T3, Electrochem. Solid State Lett., 2000, 3(6), p 268–270
G.O. Ilevbare, O. Schneider, R.G. Kelly, and J.R. Scully, In Situ Confocal Laser Scanning Microscopy of AA 2024-T3 Corrosion Metrology, J. Electrochem. Soc., 2004, 151(8), p B453
L.F. Jaffe and R. Nuccitelli, An Ultrasensitive Vibrating Probe for Measuring Steady Extracellular Currents, J. Cell Biol., 1974, 63(2), p 614–628
D. Battocchi, D.E. Tallman, G.P. Bierwagen, and A.M. Simões, SVET and SECM Imaging of Cathodic Protection of Aluminium by a Mg-Rich Coating, Corros. Sci., 2007, 49(10), p 3838–3849
A.M. Simões, Y. González-García, R.M. Souto, S. González, A.C. Bastos, and M.G. Ferreira, Use of SVET and SECM to Study the Galvanic Corrosion of an Iron–Zinc Cell, Corros. Sci., 2007, 49(2), p 726–739
G. Williams, H. ap Llwyd Dafydd, and R. Grace, The Localised Corrosion of Mg Alloy AZ31 in Chloride Containing Electrolyte Studied by a Scanning Vibrating Electrode Technique, Electrochim. Acta, 2013, 109, p 489–501
G. Williams and H.N. McMurray, Localized Corrosion of Magnesium in Chloride-Containing Electrolyte Studied by a Scanning Vibrating Electrode Technique, J. Electrochem. Soc., 2008, 155(7), p C340–C349
T. Hashimoto, X. Zhou, C. Luo, K. Kawano, G.E. Thompson, A.E. Hughes, P. Skeldon, P.J. Withers, T.J. Marrow, and A.H. Sherry, Nanotomography for Understanding Materials Degradation, Scr. Mater., 2010, 63(8), p 835–838
A. Boag and D. McCulloch, Combined Nuclear Microprobe and TEM Study of Corrosion Pit Nucleation by Intermetallics in Aerospace Aluminium Alloys, Nucl. Instrum. Meth., 2005, 231, p 457–462
X. Zhou, C. Luo, T. Hashimoto, A.E. Hughes, and G.E. Thompson, Study of Localized Corrosion in AA2024 Aluminium Alloy Using Electron Tomography, Corros. Sci., 2012, 58, p 299–306
F. Queiroz, M. Magnani, I. Costa, and H. De Melo, Investigation of the Corrosion Behaviour of AA 2024-T3 in Low Concentrated Chloride Media, Corros. Sci., 2008, 50, p 2646–2657
A. Boag, A. Hughes, and A. Glenn, Corrosion of AA2024-T3 Part I: Localised Corrosion of Isolated IM Particles, Corros. Sci, 2011, 53(1), p 17–26
A. Boag, R. Taylor, and T. Muster, Stable Pit Formation on AA2024-T3 in a NaCl Environment, Corros. Sci., 2010, 52(1), p 90–103
N. Dimitrov, Copper Redistribution During Corrosion of Aluminum Alloys, J. Electrochem. Soc., 1999, 146(1), p 98
N. Dimitrov, J.A. Mann, M. Vukmirovic, and K. Sieradzki, Dealloying of Al2CuMg in Alkaline Media, J. Electrochem. Soc., 2000, 147(9), p 3283–3285
D. Battocchi, J. He, G.P. Bierwagen, and D.E. Tallman, Emulation and Study of the Corrosion Behavior of Al Alloy 2024-T3 Using a Wire Beam Electrode (WBE) in Conjunction with Scanning Vibrating Electrode Technique (SVET), Corros. Sci., 2005, 47(5), p 1165–1176
U. Donatus, G.E. Thompson, H. Liu, X. Zhou, and Z. Liu, Understanding the Galvanic Interactions Between AA2024T3 and Mild Steel Using the Scanning Vibrating Electrode Technique, Mater. Chem. Phys., 2015, 161, p 228–236
A. Glenn, T. Muster, C. Luo, and X. Zhou, Corrosion of AA2024-T3 Part III: Propagation, Corros. Sci., 2011, 53(1), p 40–50
P. King, I. Cole, P. Corrigan, A. Hughes, and T. Muster, FIB/SEM Study of AA2024 Corrosion Under a Seawater Drop: Part I, Corros. Sci., 2011, 53(3), p 1086–1096
Acknowledgments
The authors acknowledge EPSRC for the provision of grants through the LATEST2 Programme Grant. One of the authors, Mr. U. Donatus, acknowledges the PTDF for support of his studentship.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Donatus, U., Thompson, G.E., Liu, H. et al. Analyses of the Sequential Stages of Corrosion on AA2024T3 Using the Scanning Vibrating Electrode Technique (SVET). J. of Materi Eng and Perform 24, 3808–3814 (2015). https://doi.org/10.1007/s11665-015-1701-0
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11665-015-1701-0