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Investigation of Wear and Corrosion of a High-Carbon Stellite Alloy for Hip Implants

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Abstract

Low-carbon Stellite 21 has been used as hip implant material for a number of decades; however, its limited metal-on-metal bearing has resulted in loosening between the femoral head and the acetabular cup of hip implants. In order to improve the metal-on-metal bearing, it is proposed that a high-carbon alloy, Stellite 720, surface coating be applied on Stellite 21 hip implants to improve mechanical and tribological performance. For this coating to be practical, it must also meet the requirements of corrosion resistance for orthopedic implant materials. In this research, Stellite 720 is investigated with pin-on-disk wear tests, and electrochemical and immersion corrosion tests in simulated human body fluid (Hank’s solution; pH 7.4 at temperature of 37°C). The experimental results demonstrate that Stellite 720 exhibits much better wear resistance than Stellite 21, and has the potential for better corrosion resistance as well. The applicability of coating Stellite 21 hip implants with Stellite 720 is discussed.

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References

  1. G. Manivasagam, D. Dhinasekaran, and A. Rajamanickam, Biomedical Implants: Corrosion and Its Prevention: A Review, Recent Patents Corros. Sci., 2010, 2, p 40–54

    Article  Google Scholar 

  2. E.N. Codaro, P. Melnikov, I. Ramires, and A.C. Guastaldi, Corrosion Behavior of a Cobalt-Chromium-Molybdenum Alloy, Russian Journal of Electrochemistry, 2000, 36(10), p 1117–1121

    Article  Google Scholar 

  3. Y. Yan, A. Neville, and D. Dowson, Tribo-Corrosion Properties of Cobalt-Based Medical Implant Alloys in Simulated Biological Environments, Wear, 2007, 263(7–12), p 1105–1111

    Article  Google Scholar 

  4. J. Nevelos, J.C. Shelton, and J. Fisher, Metallurgical Considerations in the Wear of Metal-on-Metal Hip Bearings, Hip Int., 2004, 14(1), p 1–10

    Google Scholar 

  5. M. Sivakumar, K.S.K. Dhanadurai, and S. Rajeswari, Failures in Stainless Steel Orthopaedic Implant Devices: A Survey, Journal of Material Science Letters, 1995, 14(5), p 351–354

    Article  Google Scholar 

  6. M. Sivakumar, U.K. Mudali, and S. Rajeswari, Investigation of Failures in Stainless Steel Orthopaedic Implant Devices: Fatigue Failure Due to Improper Fixation of a Compression Bone Plate, Journal of Material Science Letters, 1994, 13, p 142–145

    Article  Google Scholar 

  7. Canadian Institute for Health Information, Canadian Joint Replacement Registry (CJRR) 2008–2009 Annual Report, CIHI, Ottawa, 2009

    Google Scholar 

  8. H.P. Sieber, C.B. Rieker, and P. Kottig, Analysis of 118 Second-Generation Metal-on-Metal Retrieved Hip Implants, J. Bone Joint Surg., 1999, 81(1), p 46–50

    Article  Google Scholar 

  9. A. Matthies, R. Underwood, P. Cann, K. Ilo, Z. Nawaz, J. Skinner, and A.J. Hart, Retrieval Analysis of 240 Metal-on-Metal Hip Components, Comparing Modular Total Hip Replacement with Hip Resurfacing, Journal of Bone and Joint Surgery. British Volume, 2011, 93(3), p 307–314

    Article  Google Scholar 

  10. P.F. Doom, J.M. Mirra, P.A. Campbell, and H.C. Amstutz, Tissue Reaction to Metal on Metal Total Hip Prostheses, Clinical Orthopaedics and Related Research, 1996, 329, p 187–205

    Article  Google Scholar 

  11. J. Fisher, X.Q. Hu, T.D. Stewart, S. Williams, J.L. Tipper, E. Ingham, M.H. Stone, C. Davies, P. Hatto, J. Bolton, M. Riley, C. Hardaker, G.H. Isaac, and G. Berry, Wear of Surface Engineered Metal-on-Metal Hip Prostheses, Journal of Materials Science. Materials in Medicine, 2004, 15(3), p 225–235

    Article  Google Scholar 

  12. S. Williams, J.L. Tipper, E. Ingham, M.H. Stone, and J. Fisher, In Vitro Analysis of the Wear, Wear Debris and Biological Activity of Surface-Engineered Coatings for Use in Metal-on-Metal Total Hip Replacements, Proc. Inst. Mech. Eng. H., 2003, 217(3), p 155–163

    Article  Google Scholar 

  13. J.J. Jacobs, A.K. Skipor, P.F. Doom, P. Campbell, T.P. Schmalzried, J. Black, and H.C. Amstutz, Cobalt and Chromium Concentrations in Patients with Metal on Metal Total Hip Replacements, Clinical Orthopaedics and Related Research, 1996, 329, p 256–263

    Article  Google Scholar 

  14. E. Frigerio, P.D. Pigatto, G. Guzzi, and G. Altomare, Metal Sensitivity in Patients with Orthopaedic Implants: A Prospective Study, Contact Dermat., 2011, 64(5), p 273–279

    Article  Google Scholar 

  15. J.R. Davis, Nickel, Cobalt, and Their Alloys, ASM International, Materials Park, 2000, p 362–406

    Google Scholar 

  16. J.D. Bolton, J. Hayden, and M. Humphreys, A Study of Corrosion Fatigue in Cast Cobalt-Chrome-Molybdenum Alloys, Eng. Med., 1982, 11, p 59–68

    Article  Google Scholar 

  17. V. Anand, A.J. Hickl, P. Kumar, B.A. Boeck, and T.H. Sanders, Jr., Relationships Between Processing, Microstructure, and Properties of a Co-Cr-Mo Alloy, Prog. Powd. Metall., 1984, 39, p 445–490

    Google Scholar 

  18. M. Farhani, A. Amadeh, H. Kashani, and A. Saeed-Akbari, The Study of Wear Resistance of a Hot Forging Die, Hard faced by a Cobalt-Base Superalloy, Materials Forum, 2006, 30, p 212–218

    Google Scholar 

  19. S.M. Guadalupe, S. Mischler, M. Cantoni, W.J. Chitty, C. Falcand, and D. Hertz, Mechanical and Chemical Mechanisms in the Tribocorrosion of a Stellite Type Alloy, Wear, 2013, doi:10.1016/j.wear.2013.04.007

    Google Scholar 

  20. C.D. Opris, R. Liu, M.X. Yao, and X.J. Wu, Development of Stellite Alloy Composites with Sintering/HIPing Technique for Wear-Resistant Applications, Materials and Design, 2007, 28, p 581–591

    Article  Google Scholar 

  21. Y. Ning, P.C. Patnaik, R. Liu, M.X. Yao, and X.J. Wu, Effects of Fabrication Process and Coating of Reinforcements on the Microstructure and Wear Performance of Stellite Alloy Composites, Materials Science and Engineering A, 2005, 391(1–2), p 313–324

    Article  Google Scholar 

  22. R. Liu, Q. Yang, and F. Gao, Tribological Behavior of Stellite 720 Coating under Block–on–Ring Wear Test, Mater. Sci. Appl., 2012, 3, p 756–762

    Google Scholar 

  23. S. Kapoor, R. Liu, X.J. Wu, and X.X. Yao, Microstructure and Wear Resistance Relations of Stellite Alloys, Inter. J. Adv. Mater. Sci., 2013, 4(3), p 231–248

    Google Scholar 

  24. ASTM G99-95, Standard Test Method for Wear Testing with a Pin-on-Disk Apparatus, ASTM, West Conshohocken, 2010

    Google Scholar 

  25. ASTM G5-13, Standard Reference Test Method for Making Potentiostatic and Potentiodynamic Anodic Polarization Measurements, ASTM, West Conshohocken, 2011

    Google Scholar 

  26. U.K. Mudali, T.M. Sridhar, and B. Raj, Corrosion of Bio Implants, Sadhana, 2003, 28(3–4), p 601–637

    Google Scholar 

  27. R.W. Revie and H.H. Uhlig, Corrosion and Corrosion Control: An Introduction to Corrosion Science and Engineering, 4th ed., Wiley, New York, 2008, p 53–82

    Book  Google Scholar 

  28. E.E. Stansbury, Handbook of Environmental Degradation of Materials, M. Kutz, Ed., Amsterdam, Boston, 2012, p 87–126

  29. A. Lasia, Modern Aspects of Electrochemistry, Vol 32, B.E. Conway, J. Bockris, R.E. White, Ed., Kluwer Academic/Plenum, New York, 1999, p 143–248

  30. ASTM G102-89, Standard Practice for Calculation of Corrosion Rates and Related Information from Electrochemical Measurements, ASTM, West Conshohocken, 1999

    Google Scholar 

  31. J.R. Macdonald, Impedance Spectroscopy, Annals of Biomedical Engineering, 1992, 20(3), p 289–305

    Article  Google Scholar 

  32. E. Oral, S.D. Christensen, A.S. Malhi, K.K. Wannomae, and O.K. Muratoglu, Wear Resistance and Mechanical Properties of Highly Cross-Linked, Ultrahigh-Molecular Weight Polyethylene Doped with Vitamin E, Journal of Arthroplasty, 2006, 21(4), p 580–591

    Article  Google Scholar 

  33. G.A. McRae, M.A. Maguire, C.A. Jeffrey, D.A. Guzonas, and C.A. Brown, A Comparison of Fractal Dimensions Determined from Atomic Force Microscopy and Impedance Spectroscopy of Anodic Oxides on Zr-2.5Nb, Applied Surface Science, 2002, 191, p 94–105

    Article  Google Scholar 

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Acknowledgment

The authors are grateful for financial support from the Natural Science & Engineering Research Council of Canada (NSERC), in-kind support from National Research Council Canada (NRC), and both financial and in-kind support of Kennametal Stellite Inc.

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Authors and Affiliations

  1. Department of Mechanical and Aerospace Engineering, Carleton University, 1125 Colonel By Drive, Ottawa, ON, K1S 5B6, Canada

    P. S. Hu, R. Liu, J. Liu & G. McRae

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  1. P. S. Hu
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  2. R. Liu
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  3. J. Liu
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  4. G. McRae
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Correspondence to R. Liu.

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Hu, P.S., Liu, R., Liu, J. et al. Investigation of Wear and Corrosion of a High-Carbon Stellite Alloy for Hip Implants. J. of Materi Eng and Perform 23, 1223–1230 (2014). https://doi.org/10.1007/s11665-014-0887-x

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  • DOI: https://doi.org/10.1007/s11665-014-0887-x

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