Abstract
The aim of this article is to study the effect of time and temperature of sintering on the properties and microstructure of Al/B4C-AlB12-Al2O3 nanocomposite synthesized via in situ processing method. In this method, a mixture of Al-B2O3-C, as starting materials, was activated and reacted in a planetary ball mill under Argon atmosphere. The phase analysis, morphology, and particles size were studied by x-ray diffraction and scanning electron microscopy methods. The composite powders were compressed with uniaxial cold press and then were sintered at different temperatures (470-600 °C) for various times (30-90 min). The density, hardness, and compressive strength of sintered samples were investigated. The results revealed that by increasing the sintering temperature and sintering time, both hardness and compaction strength of nanocomposite reach to maximum at 560 °C. The results showed that the sample sintered at 560 °C for 90 min had highest sintered density (≈2590 kg/m3) and highest hardness value of ~88 BHN with compaction strength of ~313 MPa. Nanosize and homogeneous distribution of in situ formed ceramic particles were observed in the synthesized composite.
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References
S. Scudino, K.B. Surreddi, S. Sager, M. Sakaliyska, J.S. Kim, W. Loser, and J. Eckert, Production and Mechanical Properties of Metallic Glass-Reinforced Al-Based Metal Matrix Composites, J. Mater. Sci., 2008, 43(13), p 4518–4526
D. Poirier, R.A.L. Drew, M.L. Trudeau, and R. Gauvin, Fabrication and Properties of Mechanically Milled Alumina/Aluminum Nanocomposites, Mater. Sci. Eng. A, 2010, 527(29–30), p 7605–7614
C. Nie, J. Gu, J. Liu, and D. Zhang, Investigation on Microstructures and Interface Character of B4C Particles Reinforced 2024Al Matrix Composites Fabricated by Mechanical Alloying, J. Alloy. Compd., 2008, 454(1–2), p 118–122
H. Abdoli, H. Asgharzadeh, and E. Salahi, Sintering Behavior of Al-AlN-Nanostructured Composite Powder Synthesized by High-Energy Ball Milling, J. Alloy. Compd., 2009, 473(1), p 116–122
S.C. Tjong and Z.Y. Ma, Microstructural and Mechanical Characteristics of In Situ Metal Matrix Composites, Mater. Sci. Eng., 2000, 29(3–4), p 49–113
B.S.B. Reddy, K. Das, and S. Das, A Review on the Synthesis of In Situ Aluminum Based Composites by Thermal, Mechanical and Mechanical-Thermal Activation of Chemical Reactions, J. Mater. Sci., 2007, 42(22), p 9366–9378
P. Balaz, Mechanochemistry in nanoscience and minerals engineering, 1st ed., Springer, Berlin, Heidelberg, 2008, p 103–126
A.K. Suri, C. Subramanian, J.K. Sonber, and T.S.R.Ch. Murthy, Synthesis and Consolidation of Boron Carbide: A Review, Int. Mater. Rev., 2010, 55(1), p 4–40
E. Mohammad Sharifia, F. Karimzadeha, and M.H. Enayati, A Study on Mechanochemical Behavior of B2O3-Al System to Produce Alumina-Based Nanocomposite, J. Alloy. Compd., 2009, 482(1–2), p 110–113
M. Kubota (2010) Solid-State Reaction in Mechanically Milled and Spark Plasma Sintered Al-B4C Composite Materials, J. Alloy. Compd., 5045(S1):S319–S322.
J. Abenojar, F. Velasco, and M.A. Martınez, Optimization of Processing Parameters for the Al + 10% B4C System Obtained by Mechanical Alloying, J. Mater. Process. Technol., 2007, 184(1–3), p 441–446
M. Alizadeh, Strengthening Mechanisms in Particulate Al/B4C Composites Produced by Repeated Roll Bonding Process, J. Alloy. Compd., 2011, 509(5), p 2243–2247
M. Alizadeh, Comparison of Nanostructured Al/B4C Composite Produced by ARB and Al/B4C Composite Produced by RRB Process, Mater. Sci. Eng. A, 2010, 528(2), p 578–582
M. Rahimiana, N. Ehsani, N. Parvin, and H.R. Baharvandi, The Effect of Particle Size, Sintering Temperature and Sintering Time on the Properties of Al-Al2O3 Composites, Made By Powder Metallurgy, J. Mater. Process. Technol., 2009, 209(14), p 5387–5393
M. Tabandeh Khorshid, S.A. Jenabali Jahromi, and M.M. Moshksar, Mechanical Properties of Tri-Modal Al Matrix Composites Reinforced by Nano- and Submicron-Sized Al2O3 Particulates Developed by Wet Attrition Milling and Hot Extrusion, Mater. Des., 2010, 31(8), p 3880–3884
O. Torabi and R. Ebrahimi-Kahrizsangi, Synthesis of B4C, Al2O3 and AlB12 Reinforced Al Matrix Nano Composites Via Mechanochemical Method, J. Comp. Mater., 2012, 46(18), p 2227–2237
Z.X. Yan, J. Deng, and Z.M. Luo, A Comparison Study of the Agglomeration Mechanism of Nano- and Micrometer Aluminum Particles, Mater. Charact., 2010, 61(2), p 198–205
J.R. Groza, Nanocrystalline Powder Consolidation Methods, Nanostructured Materials, 1st ed., C.C. Koch, Ed., William Andrew, New York, 2002, p 115–161
M. Khodaei, M.H. Enayati, and F. Karimzadeh, The Structure and Mechanical Properties of Fe3Al-30 vol.% Al2O3 Nanocomposite, J. Alloy. Compd., 2009, 488(1), p 134–137
R.M. German, Sintering Theory and Practice, Wiley, New York, 1996
K.A. Padmanabhan, Mechanical Properties of Nanostructured Materials, Mater. Sci. Eng. A, 2001, 304–306, p 200–205
Y.S. Kwon and A. Savitskii, Solid-State Sintering of Metal Powder Mixtures, J. Mater. Synth. Process., 2001, 9(6), p 299–317
C.S. Pande and K.P. Cooper, Nanomechanics of Hall-Petch Relationship in Nanocrystalline Materials, Prog. Mater Sci., 2009, 54(6), p 689–706
W.S. Miller and F.J. Humphreys, Strengthening Mechanisms in Particulate Metal Matrix Composites, Scripta. Metall. Mater., 1991, 25(1), p 33–38
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Torabi, O., Ebrahimi-Kahrizsangi, R. Sintering Behavior of Al/B4C-AlB12-Al2O3 Nanostructure Composite Synthesized by In Situ Processing Method. J. of Materi Eng and Perform 22, 1405–1411 (2013). https://doi.org/10.1007/s11665-012-0404-z
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DOI: https://doi.org/10.1007/s11665-012-0404-z