Skip to main content
Log in

Modeling the Gas Nitriding Process of Low Alloy Steels

  • Published:
Journal of Materials Engineering and Performance Aims and scope Submit manuscript

Abstract

The effort to simulate the nitriding process has been ongoing for the last 20 years. Most of the work has been done to simulate the nitriding process of pure iron. In the present work a series of experiments have been done to understand the effects of the nitriding process parameters such as the nitriding potential, temperature, and time as well as surface condition on the gas nitriding process for the steels. The compound layer growth model has been developed to simulate the nitriding process of AISI 4140 steel. In this paper the fundamentals of the model are presented and discussed including the kinetics of compound layer growth and the determination of the nitrogen diffusivity in the diffusion zone. The excellent agreements have been achieved for both as-washed and pre-oxided nitrided AISI 4140 between the experimental data and simulation results. The nitrogen diffusivity in the diffusion zone is determined to be constant and only depends on the nitriding temperature, which is ~5 × 10−9 cm2/s at 548 °C. It proves the concept of utilizing the compound layer growth model in other steels. The nitriding process of various steels can thus be modeled and predicted in the future.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. V. Zinchenko and V. Syropyatov, New Possibilities of Gas Nitriding as a Method for Anticorrosion Treatment of Machine Parts, Met. Sci. Heat Treat., 1998, 40(7), p 261–265

    Article  CAS  Google Scholar 

  2. M.A.J. Somers and E.J. Mittemeijer, Layer-Growth Kinetics on Gaseous Nitriding of Pure Iron—Evaluation of Diffusion-Coefficients for Nitrogen in Iron Nitrides, Metall. Mater. Trans. A, 1995, 26(1), p 57–74

    Article  Google Scholar 

  3. M.A.J. Somers and E.J. Mittemeijer, Modeling the Kinetics of the Nitriding and Nitrocarburizing of Iron. Heat Treating 1997: Proceedings of the 17th Conference, Vol 15–18, No. 3, ASM International, 2000, p 321–330

  4. L. Torchane et al., Control of Iron Nitride Layers Growth Kinetics in the Binary Fe-N System, Metall. Mater. Trans. A, 1996, 27(7), p 1823–1835

    Article  Google Scholar 

  5. M. Yang et al., Simulation of the Ferritic Nitriding Process, Int. Heat Treat. Surf. Eng., 2011, 5(3), p 122–126

    Article  CAS  Google Scholar 

  6. M. Yang and R.D. Sisson Jr., Modeling the Nitriding of Steel, Materials Performance and Characterization, J. ASTM Int., 2012, 9(5). doi:10.1520/MPC104390

  7. W.E. Boggs, R.H. Kachik, and G.E. Pellissier, The Effect of Oxygen Pressure on the Oxidation of Zone-Refined Iron, J. Electrochem. Soc., 1965, 112(6), p 539–546

    Article  CAS  Google Scholar 

  8. M. Yang, R.D. Sisson, B. Yao, and Y. Sohn, Private Communication, 2011

Download references

Acknowledgments

The support of the Center for Heat Treating Excellence (CHTE) at Worcester Polytechnic Institute and the member companies is gratefully acknowledged. Special thanks to Bluewater Reidsville and Bodycote Worcester for their support through facilities and experimental work.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Yang.

Additional information

This article is an invited paper selected from presentations at the 26th ASM Heat Treating Society Conference, held October 31 through November 2, 2011, in Cincinnati, Ohio, and has been expanded from the original presentation.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yang, M., Zimmerman, C., Donahue, D. et al. Modeling the Gas Nitriding Process of Low Alloy Steels. J. of Materi Eng and Perform 22, 1892–1898 (2013). https://doi.org/10.1007/s11665-012-0368-z

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11665-012-0368-z

Keywords

Navigation