Skip to main content
Log in

Comparing Reactivation Behavior of TIG and Laser Beam Welded Alloy 690

  • Published:
Journal of Materials Engineering and Performance Aims and scope Submit manuscript

Abstract

The nickel base Alloy 690 was subjected to simulated autogenous welding treatment employing two different techniques, laser beam welding (LBW) and tungsten inert gas (TIG) welding. The resultant weld fusion zone (WFZ) and heat-affected zone (HAZ) were compared by studying the reactivation behavior. The chromium depletion effect was assessed by measuring the degree of sensitization (DOS) from the electrochemical potentiodynamic reactivation (EPR) test. A double-loop EPR test for Alloy 690 was employed to measure the DOS at different regions of weldments by masking the remaining regions. The results clearly demonstrated that Alloy 690 showed no sensitization in the parent material and the WFZ region of both TIG and laser weldments. However, it exhibited reactivation in the HAZ region of both the weldments. The DOS values measured for Alloy 690 were very low for all the regions of the LBW weldment as compared to that in the TIG weldment. The HAZ region of the LBW weldment showed the highest DOS value in any region of the weldment but even this value was quite low indicating absence of sensitization in LBW weldment. The attack along the grain boundaries for the weldments after EPR experiments were studied using optical and scanning electron microscopy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Special Metals Corporation, “INCONEL alloy 600,” Publication Number SMC-027, 2004, p 11

  2. Special Metals Corporation, “INCONEL Alloy 690,” Publication Number SMC-079, 2003, p 12

  3. D.C. Agarwal, Nickel and Nickel Alloys, Uhlig’s Corrosion Handbook, R.W. Revie, Ed., Wiley, Hoboken, NJ, 2000, p 831

    Google Scholar 

  4. R.B. Rebak, Corrosion of Non-ferrous Alloys I, Nickel-, Cobalt-, Copper-, Zirconium-and Titanium-Based Alloys, Corrosion & Environmental Degradation, Vol II, Wiley, Weinheim, p 69

  5. J.R. Crum, Stress Corrosion Cracking Testing of Inconel Alloy 600 and 690 Under High-Temperature Caustic Conditions, Corrosion, 1986, 42(6), p 368–372

    Article  CAS  Google Scholar 

  6. D.L. Harrod, R.E. Gold, B. Larsson, and G. Bjoerkman G, Proceedings of 5th International Symposium on Environmental Degradation of Materials in Nuclear Power Systems—Water Reactors, California, American Nuclear Society, TMS, NACE, 1991, p 849

  7. A.J. Smith, and R.P. Stratton, Proceedings of 5th International Symposium on Environmental Degradation of Materials in Nuclear Power Systems—Water Reactors, California, American Nuclear Society, TMS, NACE, 1991, p 855

  8. T. Sakai, T. Senjuh, K. Aoki, T. Shigemitsu, and Y. Kishi, Proceedings of 5th International Symposium on Environmental Degradation of Materials in Nuclear Power Systems—Water Reactors, California, American Nuclear Society, TMS, NACE, 1991, p 764

  9. G.P. Yu and H.C. Yao, Relation Between the Resistance of IGA and IGSCC and the Chromium Depletion of Alloy 690, Corrosion, 1990, 46, p 391

    Article  CAS  Google Scholar 

  10. J.J. Kai, G.P. Yu, C.H. Tsai, M. Niliu, and S.C. Yao, The Effects of Heat Treatment on the Chromium Depletion, Precipitate Evolution, and Corrosion Resistance of INCONEL Alloy 690, Metall. Trans. A, 1989, 20A, p 2057

    CAS  Google Scholar 

  11. K. Norring, K. Stiller, and J.O. Nilsson, Proceedings of 5th International Symposium on Environmental Degradation of Materials in Nuclear Power Systems—Water Reactors, California, American Nuclear Society, TMS, NACE, 1991, p 482.

  12. H. Coriou, L. Grall, C. Mahieu, and M. Pelas, Sensitivity to Stress Corrosion and Intergranular Attack of High-Nickel Austenitic Alloys, Corrosion, 1966, 22, p 280

    CAS  Google Scholar 

  13. H. Coriou, L. Grall, Y. Legall, and S. Vettier S, Proceedings of the Third Metallurgy Conference on Corrosion, Saclay, North Holland Pub. Co., Amsterdam, 1959, p 161

  14. J. Blanchet, H. Coriou, L. Grall, C. Mahieu, C. Otter, and G. Turluer, Proceedings of the Stress Corrosion Cracking and Hydrogen Embrittlement of Iron Base Alloys, NACE, Houseton, TX, 1973, p 1149

  15. R. Kilian, N. Wieling, and L. Stieding, Corrosion Resistance of SG Tubing Material Incoloy 800 Mod and Inconel 690 TT, Werkstoffe und Korrosion, 1991, 42, p 490–496

    Article  CAS  Google Scholar 

  16. V. Kain and Y. Watanabe, Development of a Single Loop EPR Test Method and Its Relation to Grain Boundary Microchemistry for Alloy 600, J. Nucl. Mater., 2002, 302, p 49–59

    Article  CAS  Google Scholar 

  17. G.S. Was, H.H. Tischner, and R.M. Latanision, Influence of Thermal Treatment on the Chemistry and Structure of Grain Boundaries in Inconel 600, Metall. Mater. Trans. A, 1981, 12A, p 1397–1408

    Google Scholar 

  18. P.M. Scott, An Overview of Materials Degradation by Stress Corrosion in PWRs, Corrosion Issues in Light Water Reactors: Stress Corrosion Cracking, D. Féron and J.M. Olive, Ed., Woodhead, Cambridge, 2007, p 3–24

    Chapter  Google Scholar 

  19. V. Kain, R.C. Prasad, and P.K. De, Testing Sensitization and Predicting Susceptibility to Intergranular Corrosion and Intergranular Stress Corrosion Cracking in Austenitic Stainless Steels, Corrosion, 2002, 58(1), p 15–37

    Article  CAS  Google Scholar 

  20. ASTM Annual Book of Standards, “G28-02 Standard Test Methods for Detecting Susceptibility to Intergranular Corrosion in Wrought, Nickel-Rich, Chromium Bearing Alloys,” 2008

  21. V. Cihal, T. Shoji, V. Kain, Y. Watanabe, and R. Stefec, “EPR—A Comprehensive Review,” 2004, FRRI Publication, p 152

  22. R. Kaul, S. Mahajan, V. Kain, P. Ganesh, K. Chandra, I. Samajdar, A.K. Nath, and R.C. Prasad, Laser Surface Treatment for Enhancing Intergranular Corrosion Resistance of AISI, 304 Stainless Steel, Corrosion, 2008, 64(10), p 755–763

    Article  CAS  Google Scholar 

  23. K. Chandra, V. Kain, and P. Ganesh, Controlling End Grain Corrosion of Austenitic Stainless Steels, ASM J. Mater. Eng. Perform., 2008, 17(1), p 115–122

    Article  CAS  Google Scholar 

  24. J.D. Kim, C.J. Kim, and C.M. Chung, Repair Welding of Etched Tubular Components of Nuclear Power Plant by Nd:YAG Laser, J. Mater. Process. Technol., 2001, 114, p 51–56

    Article  CAS  Google Scholar 

  25. T. Nagashima, A. Yokoyama, T. Akaba, Y. Nagura, O. Matsumoto, and T. Ishide, Development of YAG Laser Welding Robot System for Repairing Heat Exchanger Tubes, Weld. World, 1994, 34, p 133–138

    CAS  Google Scholar 

  26. ASTM Annual Book of Standards, “E 1473-09; Standard Test Methods for chemical analysis of nickel, cobalt and high temperature alloys”

  27. R.S. Dutta, R. Tewari, and P.K. De, Effects of Heat-Treatment on the Extent of Chromium Depletion and Caustic Corrosion Resistance of Alloy 690, Corros. Sci., 2007, 49, p 303–318

    Article  CAS  Google Scholar 

  28. D. Radaj, Heat Effects of Welding: Temperature Field, Residual Stress, Distortion, Springer, New York, 1992

    Book  Google Scholar 

  29. H.T. Lee and J.L. Wu, The Effects of Peak Temperature and Cooling Rate on the Susceptibility to Intergranular Corrosion of Alloy 690 by Laser Beam and Gas Tungsten Arc Welding, Corros. Sci., 2009, 51, p 439–445

    Article  CAS  Google Scholar 

  30. W.M. Steen, Laser Material Processing, Springer, New York, 1991

    Google Scholar 

  31. B.T. Lu, Z.K. Chen, J.L. Luo, B.M. Patchett, and Z.H. Xu, Pitting and Stress Corrosion Cracking Behavior in Welded Austenitic Stainless Steel, Electrochim. Acta, 2005, 50, p 1391–1403

    Article  CAS  Google Scholar 

  32. S. Kou, Welding Metallurgy, Wiley, New York, 1987

    Google Scholar 

  33. G. Bao, K. Shinozaki, S. Iguora, M. Inkyo, M. Yamoto, Y. Mahara, and H. Watanabe, Stress Corrosion Cracking Sealing in Overlaying of Inconel 182 by Laser Surface Melting, J. Mater. Process. Technol., 2006, 173, p 330–336

    Article  CAS  Google Scholar 

  34. J.D. Kim and J.H. Moon, C-ring Stress Corrosion Test for Inconel 600 and Inconel 690 Sleeve Joint Welded by Nd: YAG Laser, Corros. Sci., 2004, 46, p 807–818

    Article  CAS  Google Scholar 

  35. R.J. Jacko, EPRI NP-6721-SD, 1990

  36. R.J. Jacko, EPRI NP-4665S-SR, 1986

  37. S. Xia, B. Zhou, and W. Chen, Effect of Single-Step Strain and Annealing on the Grain Boundary Character Distribution and Intergranular Corrosion of Alloy 690, J. Mater. Sci., 2008, 43(9), p 2990–3000

    Article  CAS  Google Scholar 

  38. H.T. Lee and J.L. Wu, Intergranular Corrosion Resistance of Nickel-Based Alloy 690 Weldments, Corros. Sci., 2010, 52, p 1545–1550

    Article  CAS  Google Scholar 

  39. S.M. Bruemmer, B.W. Arey, and L.A. Charlot, Proceedings of 6th International Symposium on Environmental Degradation of Materials in Nuclear Power Systems—Water Reactors, California, American Nuclear Society, TMS, NACE, 1993, p 277

  40. S. Roychowdhury, V. Kain, M. Gupta, and R.C. Prasad, IGSCC Crack Growth in Simulated BWR Environment—Effect of Nitrogen Content in Non-sensitised and Warm Rolled Austenitic Stainless Steel, Corros. Sci., 2011, 53(3), p 1120–1129

    Article  CAS  Google Scholar 

  41. J. Hou, Q.J. Peng, Z.P. Lu, T. Shoji, J.Q. Wang, E.H. Han, and W. Ke, Effects of Cold Working Degrees on Grain Boundary Characters and Strain Concentration at Grain Boundaries in Alloy 600, Corros. Sci., 2011, 53(3), p 1137–1142

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Geogy J. Abraham.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Abraham, G.J., Bhambroo, R., Kain, V. et al. Comparing Reactivation Behavior of TIG and Laser Beam Welded Alloy 690. J. of Materi Eng and Perform 22, 427–432 (2013). https://doi.org/10.1007/s11665-012-0249-5

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11665-012-0249-5

Keywords

Navigation