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Corrosion Mechanism of Low-Carbon Steel in Industrial Water and Adsorption Thermodynamics in the Presence of Some Plant Extracts

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Abstract

The effects of radish leaves and black cumin as plant extracts on the corrosion behavior of low-carbon steel in industrial water in the temperature range of 30 to 80 °C and velocity range of 1.44 to 2.02 m s−1 using potentiodynamic polarization, electrochemical impedance spectroscopy, and mass loss measurements have been investigated. The inhibition efficiency increased with increasing concentration of the plant extracts up to a critical value but it slightly decreased with increasing temperature. Inhibition efficiency values obtained from mass loss and potentiodynamic data were in reasonable agreement. Potentiodynamic polarization clearly indicated that radish leaves and black cumin extracts acted as anodic inhibitors. The adsorption behavior was found to obey the Flory-Huggins isotherm model. The associated activation parameters and thermodynamic data of adsorption were evaluated and discussed. The results show that radish leaves and black cumin could serve as effective inhibitors for low-carbon steel in industrial water media, with black cumin providing better protection than radish leaves.

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References

  1. A. M. Abdel-Gaber, B.A. Abd-El-Nabey, I.M. Sidahmed, A.M. El-Zayady, M. Saadawy, “Inhibitive Action of Some Plant Extracts on the Corrosion of Steel in Acidic Media”, Corros. Sci. 48 (2006) 2765–2779

    Article  CAS  Google Scholar 

  2. R. M. Saleh, A.A. Ismail, A.A. El-Hosary, “Corrosion Inhibition by Naturally Occurring Substances. VII. The Effect of Aqueous Extracts of Some Leaves and Fruit Peels on the Corrosion of Steel, Aluminum, Zinc and Copper in Acids”, Br. Corros. J. 17 (1982) 131–135.

    Article  CAS  Google Scholar 

  3. K. Srivatsava, P. Srivatsava, “Studies on Plant Materials as Corrosion Inhibitors”, Br. Corros. J. 16 (1981) 221–223

    Article  Google Scholar 

  4. A. Y. El-Etre, “Natural Honey as Corrosion Inhibitor for Metals and Alloys. I. Copper in Neutral Aqueous Solution”, Corros. Sci. 40 (1998) 1845–1850

    Article  CAS  Google Scholar 

  5. A. Y. El-Etre, M. Abdallah, “Natural Honey as Corrosion Inhibitor for Metals and Alloys. II. C Steel in High Saline Water”, Corros. Sci. 42 (2000) 731–738

    Article  CAS  Google Scholar 

  6. E. Khamis, N. Al-Andis, “Herbs as New Type of Green Inhibitors for Acidic Corrosion of Steel”, Materwiss. Werkstofftech. 33 (2002) 550–554

    Article  CAS  Google Scholar 

  7. A. Chetouani, B. Hammouti, “Corrosion Inhibition of Iron in Hydrochloric Acid Solutions by Naturally Henna”, Bull. Electrochem. 19 (2003) 23–25

    CAS  Google Scholar 

  8. B. Hammouti, S. Kertit, M. Melhaoui, “Bgugaine: A Natural Pyrolidine Alkaloid Product as Corrosion Inhibitor of Iron in HCl Medium”, Bull. Electrochem. 11 (1995) 553–555

    CAS  Google Scholar 

  9. B. Hammouti, S. Kertit, M. Mellhaoui, “Electrochemical Behaviour of Gugaine as Corrosion Inhibitor of Iron in HCl Medium”, Bull. Electrochem. 13 (1997) 97–98

    CAS  Google Scholar 

  10. M. K. Gomma, M.H. Wahdan, “Schiff Bases as Corrosion Inhibitors for Aluminum in Hydrochloric Acid Solution”, Mater. Chem. Phys. 39 (1995) 209–213

    Article  CAS  Google Scholar 

  11. M. G. Fontana, N. D. Green, Corrosion Engineering, 2nd ed., McGraw-Hill, New York, 1978

    Google Scholar 

  12. M.A. Ameer, E. Khamis, G. Al-Senani, “Effect of Temperature on Stability of Adsorbed Inhibitors on Steel in Phosphoric Acid Solution”, J. Appl. Electrochem. 32 (2002) 149–156

    Article  CAS  Google Scholar 

  13. B. A. Abd-ENabey, E. Khamis, M.Sh. Ramadan. A. El-Gindy, Application of the Kinetic-Thermodynamic Model for Inhibition of Acid Corrosion of Steel by Inhibitors Containing Sulfur and Nitrogen, Corrosion 52 (1996) 671–679

    Article  CAS  Google Scholar 

  14. N. H. Helal, M.M. El-Rabiee, Gh.M. Abd El-Hafez, W.A. Badawy, “Environmentally Safe Corrosion Inhibition of Pb in Aqueous Solutions”, J. Alloys Compd. 456 (2008) 372–379

    Article  CAS  Google Scholar 

  15. J. Cruz, R. Martínez, J. Genesca, E. García-Ochoa, “Experimental and Theoretical Study of 1-(2-Ethylamino)-2-methylimidazoline as an Inhibitor of Carbon Steel Corrosion in Acid Media”, J. Electroanal. Chem. 566 (2004) 111–121

    Article  CAS  Google Scholar 

  16. Hosseini, M., Mertens, S.F.L. and Ghorbani, M., M.R. Arshadi, “Asymmetrical Schiff Bases as Inhibitors of Mild Steel Corrosion in Sulphuric Acid Media” Mater. Chem. Phys. 78 (2003) 800–808

    Article  CAS  Google Scholar 

  17. O. Benali, L. Larabi, M. Traisnel, L. Gengembre, Y. Harek, “Electrochemical, Theoretical and XPS Studies of 2-Mercapto-1-methylimidazole Adsorption on Carbon Steel in 1 M HClO4” Y. Harek, Appl. Surf. Sci., 253 (2007) 6130–6139

    Article  CAS  Google Scholar 

  18. F. Bentiss, M. Lagrenée, M.Traisnel, J. C.Hornez, “Corrosion Inhibition of Mild Steel in 1 M Hydrochloric Acid by 2,5-Bis(2-Aminophenyl)-1,3,4-Oxadiazole” Corrosion 55 (1999) 968–976

    Article  CAS  Google Scholar 

  19. T. F. Tadros, Applied Surfactants, 3rd ed., Wiley-VCH, Weinheim, 2005, p.87

    Book  Google Scholar 

  20. E. E. Oguzie, C. Unaegbu, C.N. Ogukwe, B.N. Okolue, A.I. Onuchukwu, “Inhibition of Mild Steel Corrosion in Sulphuric Acid Using Indigo Dye and Synergistic Halide Additives”, Mater. Chem. Phys. 84 (2004) 363–368

    Article  CAS  Google Scholar 

  21. S.S. Abd El Rehim, M.A.M. Ibrahim, K.F. Khalid, “The Inhibition of 4-(2′-Amino-5′-methylphenylazo) antipyrine on Corrosion of Mild Steel in HCl Solution” Mater. Chem. Phys. 70 (2001) 268–273

    Article  CAS  Google Scholar 

  22. F.M. Donahue, K. Nobe, “Theory of Organic Corrosion Inhibitors: Adsorption and Linear Free Energy Relationships”, J. Electrochem. Soc. 112 (1965) 886–891

    Article  CAS  Google Scholar 

  23. E. Khamis, F. Bellucci, R. M. Latanision, E.S.H. El-Ashry, “Acid Corrosion Inhibition of Nickel by 2-(Triphenosphoranylidene) Succinic Anhydride”, Corrosion 47 (1991) 677–686

    Article  CAS  Google Scholar 

  24. M. Soleimani, T. Kaghazchi, “The Investigation of the Potential of Activated Hard Shell of Apricot Stones as Gold Adsorbents”, J. Ind. Eng. Chem. 14 (2008) 28–37

    Article  CAS  Google Scholar 

  25. U. Inel, D. Topalogln, A. Askin, F. Tumsek, “Evaluation of the Thermodynamic Parameters for the Adsorption of Some Hydrocarbons on 4A and 13X Zeolites by Inverse Gas Chromatography”, Chem. Eng. J. 88 (2002) 255–262

    Article  CAS  Google Scholar 

  26. L. Warren, C.S. Julian, and P. Hariott, Unit Operations of Chemical Engineering, 4th ed., McGraw Hill, New York, 1985, p 217–219, 690

  27. H. Armoosh, The Herbs in Book, 1st ed. House of the Gems, Damascus, 1999

    Google Scholar 

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Acknowledgments

One of the authors (A. M. Badiea) is thankful to Mr. Nasr Humaidy, deputy of PEPA and Dr. Ahmed Abdillah, Chairman of PEPA (Ministry of Oil, Yemen) for providing some financial support and to Ms. Marry (Düsseldorf, Germany) for her help.

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  1. Department of Chemistry, University of Mysore, Manasagangotri, Mysore, 570 006, India

    A. M. Badiea & K. N. Mohana

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  1. A. M. Badiea
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  2. K. N. Mohana
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Correspondence to A. M. Badiea.

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Badiea, A.M., Mohana, K.N. Corrosion Mechanism of Low-Carbon Steel in Industrial Water and Adsorption Thermodynamics in the Presence of Some Plant Extracts. J. of Materi Eng and Perform 18, 1264–1271 (2009). https://doi.org/10.1007/s11665-009-9378-x

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  • DOI: https://doi.org/10.1007/s11665-009-9378-x

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