Skip to main content
Log in

The Role of Silicon Content on Environmental Degradations of T91 Steels

  • Published:
Journal of Materials Engineering and Performance Aims and scope Submit manuscript

Abstract

T91 grade steels showed a gradual enhancement in tensile ductility at ambient temperature due to an increase in Si content from 0.5 to 2.0 weight percent (wt.%). However, the ultimate tensile strength was reduced only above 1.5 wt.% Si. The corrosion potential became more active in an acidic solution with increasing temperature. The cracking susceptibility in a similar environment under a slow-strain-rate (SSR) condition was enhanced at higher temperatures showing reduced ductility, time to failure, and true failure stress. Cathodic potentials applied to the test specimens in SSR testing caused an enhanced cracking tendency at 30 and 60 °C, suggesting hydrogen embrittlement as a possible mechanism of failure. Cracking of precracked and wedge-loaded double-cantilever-beam specimens was enhanced at higher initial stress intensity factors. In general, steels with 2.0 wt.% Si showed inferior corrosion resistance. A combination of cleavage and intergranular brittle failure was seen in the tested specimens depending on the type of testing.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. F. Venneri, M.A. Williamson, N. Li, M.G. Houts, R.A. Morley, D.E. Beller, W. Sailor, G. Lawrence (2000) Disposition of Nuclear Waste using Subcritical Accelerator-Driven Systems: Technology Choices and Implementation Scenarios. Nucl. Technol. 132: 15

    Article  CAS  Google Scholar 

  2. A.K. Roy, M.K. Hossain (2005) Environment-Assisted Cracking of Structural Materials Under Different Loading Conditions. Corrosion 61(4): 364

    Article  CAS  Google Scholar 

  3. A.K. Roy, M.K. Hossain (2006) Cracking of Martensitic Alloy EP-823 Under Controlled Potential. J. Mater. Eng. Perform. 15(3): 336

    Article  CAS  Google Scholar 

  4. T. Hayashi, M. Takamoto, K. Ito, K. Tanaka (2005) The Effect of Nb and W Alloying Additions to the Thermal Expansion Anisotropy and Elastic Properties of Mo5Si3. Met. Mat. Tran. 36A(3): 533

    Article  CAS  Google Scholar 

  5. J.L. Boutard, Y. Dai, and K. Ehrlich, MEGAPIE General Meeting

  6. A.M. Huntz, V. Bague, G. Beauplé, C. Haut, C. Sévérac, P. Lecour, X. Longaygue, F. Ropital (2003) Effect of Silicon on the Oxidation Resistance of 9% Cr Steels. Appl. Surf. Sci. 207(1–4): 255

    Article  CAS  Google Scholar 

  7. R. Nishimura, K. Yamakawa, J. Ishiga (1998) Highly Corrosion Resistant Stainless Steel with Si Implanted/Deposited Phase. Mat. Chem. Phys. 54(1–3): 289

    Article  CAS  Google Scholar 

  8. ASTM Designation E 8-2004, Standard Test Methods for Tensile Testing of Metallic Materials, American Society for Testing and Materials (ASTM) International, 2004

  9. ASTM Designation G 38, Standard Practice for Making and Using C-Ring Stress-Corrosion Test Specimens, American Society for Testing and Materials (ASTM) International, 2001

  10. ASTM Designation G 30, Standard Practice for Making and Using U-Bend Stress-Corrosion Test Specimens, American Society for Testing and Materials (ASTM) International, 1997

  11. NACE Standard TM0177, Laboratory Testing of Metals for Resistance to Sulfide Cracking in H2S Environments, National Association of Corrosion Engineers (NACE), 1990, p 16

  12. ASTM Designation E 399, Standard Test Method for Linear-Elastic Plain-Strain Fracture Toughness K1C of Metallic Materials, American Society for Testing and Materials (ASTM) International, 1999

  13. D. Maitra, Tensile Deformation and Environmental Degradation of T91 Grade Steels with Different Silicon Content, PhD Dissertation, Mech. Eng., UNLV (2007)

  14. A.K. Roy, V. Virupaksha (2007) Performance of Alloy 800H for High-Temperature Heat Exchanger Applications. Mat. Sci. Eng. A 452–453: 665

    Article  Google Scholar 

  15. A.K. Roy, A.V. Kaiparambil (2006) Tensile and Corrosion Behavior of Zr705 for Nuclear Hydrogen Generation. Mat. Sci. Eng. A 427: 320

    Article  Google Scholar 

  16. R. Prabhakaran, A.K. Roy (2006) Degradations of Type 422 Stainless Steel in Aqueous Environments. Mat. Sci. Eng. A 421: 290

    Article  Google Scholar 

  17. ASTM G 5-94, Standard Reference Test Method for Making Potentiostatic and Potentiodynamic Anodic Polarization Measurements, American Society for Testing and Materials (ASTM) International, 1999

  18. B.V.N. Rao, M.S. Rashid (1983) Direct Observations of Deformation-Induced Retained Austenite Transformation in a Vanadium-Containing Dual-Phase Steel Metallography 16: 19

    Article  CAS  Google Scholar 

  19. L.C. Covington (1979) The Influence of Surface Condition and Environment on the Hydriding of Titanium. Corrosion 35(8): 378

    Article  CAS  Google Scholar 

  20. B. Mintz (2000) Role of Silicon in Influencing Strength and Impact Behavior of Ferrite and its Likely Influence at Ultrafine Grain Size. Struc. Mat. Mat. Cong. 16: 1282

    CAS  Google Scholar 

  21. J.M. Rigsbee and P.J. Vanderarend, Formable HSLA and Dual-Phase Steels, New York, TMS-AIME, 1977, p 56

  22. A.K. Roy D.L. Fleming B.Y. Lum, Localized Corrosion Behavior of Candidate Nuclear Waste Package Container Materials, Mat. Perform., 1998, 37, 54

    CAS  Google Scholar 

  23. I. Azkarate, A. Pelayo, and L. Victori, Progress in the Understanding and Prevention of Corrosion, vol. 2, 1993, p 1573

Download references

Acknowledgment

This work was funded by the United States Department of Energy under grant number DE-FC07-06 ID14781.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A.K. Roy.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Roy, A., Maitra, D. & Kumar, P. The Role of Silicon Content on Environmental Degradations of T91 Steels. J. of Materi Eng and Perform 17, 612–619 (2008). https://doi.org/10.1007/s11665-007-9191-3

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11665-007-9191-3

Keywords

Navigation