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Electrical and Physical Characterization of Bulk Ceramics and Thick Layers of Barium Titanate Manufactured Using Nanopowders

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Fine powders of BaTiO3 are synthesized by hydrothermal processing at 250 °C for 7 h. Two different starting mixtures were used, TiCl3 + BaCl2 and TiO2 + BaCl2. The size of the resulting crystallites was close to 20 nm in both cases. The powders were formed into ceramic pellets or thick layers. The samples were characterized for microstructure and electrical permittivity. The impact of the microstructure on the electrical properties is emphasized, and is correlated to the powder characteristics and the powder realization process.

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References

  1. Campbell C.K., van Wyk J.D., Karl Holm M.F. (1998) Development of large-Area BaTiO3 Ceramics with Optimized Depletion Regions as Dielectrics for Planar Power Electronics. IEEE Trans. Comp. Packag. Manuf. Technol. 21:492-499

    Article  CAS  Google Scholar 

  2. Wolmarans P.J., van-Wyk J.D., van-Wyk J.D. Jr., Campbell C.K. (2002) Technology for Integrated RF-EMI Transmission Line Filters for Integrated Power Electronic Modules. IEEE-Industry-Appl.-Conference.-37th-IAS-Annual-Meeting-Cat.-No.02CH37344. 3:1774-1780

    Article  Google Scholar 

  3. Boulos M., Guillemet-Fritsch S., Mathieu F., Durand B., Lebey T., Bley V. (2005) Hydrothermal Synthesis of Nanosized BaTiO3 Powders and Dielectric Properties of Corresponding Ceramics. Solid State Ionics 176:1301-1309

    Article  CAS  Google Scholar 

  4. Wang S.-F., Thomas C.K., Yang, Wang Y.-R., Kuromitsu Y. (2001) Effect of Glass Composition on the Densification and Dielectric Properties of BaTiO3 Ceramics. Ceram. Int. 27:157-162

    Article  CAS  Google Scholar 

  5. Park M.-B., Hwang S.-J., Cho N.-H. (2003) Effect of the Grain Size and Chemical Feature on the Phase Transition and Physical Characteristics of Nanograined BaTiO3 Ceramics. Mater. Sci. Eng. B99:155-158

    Article  CAS  Google Scholar 

  6. Xuab H., Gaob L. (2004) Hydrothermal Synthesis of High-Purity BaTiO3 Powders: Control of Powder Phase and Size, Sintering Density, and Dielectric Properties. Mater. Let. 58:1582-1586

    Article  Google Scholar 

  7. Stojanovic B.D., Foschinic C.R., Pejovicd V.Z., Pavlovice V.B., Varelaa J.A. (2004) Electrical Properties of Screen Printed BaTiO3 Thick Films. J. Eur. Ceram. Soc. 24:1467-1471

    Article  CAS  Google Scholar 

  8. Stojanovica B.D., Foschinia C.R., Pavlovicd V.B., Pavlovice V.M., Pejovicf V., Varelaa J.A. (2002) Barium Titanate Screen-Printed Thick Films. Ceram. Int. 28:293-298

    Article  Google Scholar 

  9. Yoon D.-H., Zhang J., Lee B.I. (2003) Dielectric Constant and Mixing Model of BaTiO3 Composite Thick Films. Mater. Res. Bull. 38:765-772

    Article  CAS  Google Scholar 

  10. Lee B.I., Zhang J. (2001) Dielectric Thick Films Deposition by Particle Coating Method. Mater. Res. Bull. 36:1065-1074

    Article  CAS  Google Scholar 

  11. S. Guillemet, Th. Lebey, and F. Costa, Study of Some Ferroelectric Materials In View of Passive Components Integration in Power Electronic. IEEE Int. Symposium Electr. Insul. Mater., 2001, p 823–827

  12. J.C. Niepce, Diélectriques à grains très fins. In Nanomatériaux, ARAGO no 27,OFTA Editor, Paris, 2001, p. 149–158

  13. Lu S.W., Lee B.I., Wang Z.L., Samuels W.D. (2000) Hydrothermal Synthesis and Structural Characterization of BaTiO3 Nanocrystals. J. Crystal Growth 219:269-276

    Article  Google Scholar 

  14. Park M.B., Hwang S.J., Cho N.H. (2003) Effect of the Grain Size and Chemical Features on the Phase Transition and Physical Characteristics Of Nano-Grained BaTiO3 Ceramics. Mater. Sci. Eng. B99:155

    Article  CAS  Google Scholar 

  15. Yoon D.-H., Lee B.I. (2004) Processing of Barium Titanate Tapes with Deferent Binders for MLCC Applications—Part I: Optimization Using Design of Experiments. J. Eur. Ceram. Soc. 24:739-752

    Article  CAS  Google Scholar 

  16. Yoon D.-H., Lee B.I. (2004) Processing of Barium Titanate Tapes with Deferent Binders for MLCC Applications—Part II: Comparison of the Properties. J. Eur. Ceram. Soc. 24:753-761

    Article  CAS  Google Scholar 

  17. Cole K.S., Cole R.H. (1941) Dispertion and Absoption in Dielectric: I. Alternating Current Characteristics. J. Chem. Phys. 9:341-351

    Article  CAS  Google Scholar 

  18. Coelho R., Aladenize B. (1993) Les Diélectriques. Hermès, Paris, pp. 123-145

    Google Scholar 

  19. F. Bertrandias and J.P. Bertrandias, Mathématiques pour les sciences de la nature et de la vie. Presses Universitaires de Grenoble, 1990

  20. Daniel V.V. (1967) Dielectric Relaxation. Academic Press, London and New York

    Google Scholar 

  21. Butcher C.J.F., Bordewijk P. (1978) Theory of Electric Polarization. Elsevier, Amsterdam

    Google Scholar 

  22. MacDonald J.R. (1987) Impedance Spectroscopy, Emphasising Solid Materials and Systems. Wiley, New York

    Google Scholar 

  23. J.-M. Laffargue, A. Loubiere, and A. Bui, A Characterisation Method of Varistor Degradation Based on Complex Plan Analysis CPA. Proc. 4th International Conference on Electronic Ceramics & Applications, Aachen (Germany), 1994, p. 619–622

  24. L.L. Hench and J.K. West, Principles of Electronic Ceramics. USA, 1990, p. 220

  25. Kinoshita K., Yamaji A. (1976) Grain Size Effect On Dielectric Properties in Barium Titanate Ceramics. J.Appl. Phys. 47(1):371-373

    Article  CAS  Google Scholar 

  26. Wang X.H., Chen R.Z., Gui Z.L., Li L.T. (2003) The Grain Size Effect On Dielectric Properties of BaTiO3 Based Ceramics. Mater. Sci. Eng. B99:199-202

    Article  CAS  Google Scholar 

  27. Bernaben N., Leriche A., Thierry B., Niepce J.C., Waser R. (1995) Pure Barium Titanate Ceramics: Crystalline Structure and Dielectric Properties as a Function of Grain Size. Fourth Eur. Ceramics 5:203-210

    Google Scholar 

  28. Duran P., Gutierrez D., Tartaj J., Moure C. (2002) Densification Behaviour, Microstructure Development and Dielectric Properties of Pure BaTiO3 Prepared by Thermal Decomposition of (Ba,Ti)-Citrate Polyester Resins. Cera. Inter 28:283-292

    Article  CAS  Google Scholar 

  29. Hirata Y., Nitta A., Sameshima S., Kamino Y. (1996) Dielectric Properties of Barium Titanate Prepared by Hot Isostatic Pressing. Mater. Lett. 29:229-234

    Article  Google Scholar 

  30. Miot C., Proust C., Husson E. (1995) Dense Ceramics of BaTiO3, Produced from Powders Prepared by a Chemical Process. J. Eur Cera Soc. 15:1163-1170

    Article  CAS  Google Scholar 

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Correspondence to Thierry Lebey or Sophie Guillemet-Fritsch.

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Nguyen, D.Q., Lebey, T., Castelan, P. et al. Electrical and Physical Characterization of Bulk Ceramics and Thick Layers of Barium Titanate Manufactured Using Nanopowders. J. of Materi Eng and Perform 16, 626–634 (2007). https://doi.org/10.1007/s11665-007-9110-7

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  • DOI: https://doi.org/10.1007/s11665-007-9110-7

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