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Effects of Re3+ (Re = Y, La, Gd) Co-doping on Luminescence Properties of MSi2O2N2:Eu2+ (M = Ca, Sr) Phosphors

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Abstract

Re3+ ions (Re = Y, La, Gd)-doped MSi2O2N2:Eu2+ (M = Ca, Sr) phosphors were prepared by the solid-state reaction method. The effects of co-dopants (Y3+, La3+, Gd3+) and Eu2+ doping concentration on the luminescent performance of MSi2O2N2:Eu2+ have been investigated. The co-doping with Re3+ (Re = Y, La, Gd) significantly improved the luminescent performance of MSi2O2N2:Eu2+ (M = Ca, Sr) overall. Re3+ co-doping had a greater enhancing effect on higher Eu2+ concentration samples and the Re3+-doped CaSi2O2N2:Eu2+ phosphors exhibited better luminescence properties than Re3+-doped SrSi2O2N2:Eu2+ ones. In addition, incorporation of Y3+ ions to SrSi2O2N2:Eu2+ showed the strongest emission among the three dopants (Y3+, La3+, and Gd3+), while the Gd3+ doping ions in CaSi2O2N2:Eu2+ exhibited superior luminescence properties compared to Y3+ and La3+.

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References

  1. N.C. George, K.A. Denault, and R. Seshadri, Phosphors for solid-state white lighting. Annu. Rev. Mater. Res. 43, 481 (2013).

    Article  CAS  Google Scholar 

  2. F. Wang, H.H. Chen, and S.W. Zhang, Preparation and luminescent properties of a novel orange-red phosphor Sr2RE8(SiO4)6O2:Eu(2+,3+) (RE = Y, Gd, La) for LEDs. Chem. Zvesti. 75, 5803 (2021).

    CAS  Google Scholar 

  3. Y.F. Liu, X. Zhang, Z.D. Hao, X.J. Wang, and J.H. Zhang, Generation of broadband emission by incorporating N3− into Ca3Sc2Si3O12: Ce3+ garnet for high rendering white LEDs. J. Mater. Chem. 21, 6354 (2011).

    Article  CAS  Google Scholar 

  4. Y.B. Hua, and W.G. Ran, Jae Su Yu, Strong red emission with excellent thermal stability in double-perovskite type Ba2GdSbO6:Eu3+ phosphors for potential field-emission displays. J. Alloys Compd. 835, 155389 (2020).

    Article  CAS  Google Scholar 

  5. M.M. Shang, J. Fan, H.Z. Lian, Y. Zhang, D.L. Geng, and J. Lin, A double substitution of Mg2+-Si4+/Ge4+ for Al(1)3+-Al(2)3+ in Ce3+-doped garnet phosphor for white LEDs. Inorg. Chem. 53, 7748 (2014).

    Article  CAS  PubMed  Google Scholar 

  6. Y. Luo and Z.G. Xia, Effect of Al/Ga substitution on photoluminescence and phosphorescence properties of garnet-type Y3Sc2Ga3–xAlxO12:Ce3+ phosphor. J. Phys. Chem. C 118, 23297 (2014).

    Article  CAS  Google Scholar 

  7. J. Zhang, Y.Y. Gao, J.K. Xiao, C.F. Xu, Y.X. Liu, and Q.B. Yang, Relationship between microstructure evolution and the luminescent properties of Eu3+-doped yttrium aluminum garnet and Y2O3 nano-powders. J. Mater. Sci. Technol. 29, 225 (2013).

    Article  Google Scholar 

  8. F.W. Kang, H.S. Zhang, L. Wondraczek, X.B. Yang, Y. Zhang, D.Y. Lei, and M.Y. Peng, Band-gap modulation in single Bi3+-doped yttrium-scandium-niobium vanadates for color tuning over the whole visible spectrum. Chem. Mater. 28, 2692 (2016).

    Article  CAS  Google Scholar 

  9. S.X. Wang, Z. Song, and Q.L. Liu, J. Mater. Chem. C. 11, 48 (2022).

    Article  Google Scholar 

  10. S.J. Zhao, S.Z. Liao, Z.X. Qiu, S.X. Lian, and J.L. Zhang, Comparison of luminescence between Eu2+-activated Na2CaPO4F and NaCaPO4 green-emitting phosphors for pc-wLEDs. Ceram. Int. 49, 11285 (2023).

    Article  CAS  Google Scholar 

  11. L.L. Zhang, J.H. Zhang, X. Zhang, Z.D. Hao, H.F. Zhao, and Y.S. Luo, New yellow-emitting nitride phosphor SrAlSi4N7:Ce3+ and important role of excessive AlN in material synthesis. ACS Appl. Mater. Interfaces 5, 12839 (2013).

    Article  CAS  PubMed  Google Scholar 

  12. X. Wang, T. Seto, Z. Zhao, Y. Li, Q. Wu, H. Li, and Y.J. Wang, Preparation of Sr1−xCaxYSi4N7:Eu2+ solid solutions and their luminescence properties. J. Mater. Chem. C. 2, 4476 (2014).

    Article  CAS  Google Scholar 

  13. T. Suehiro, N. Hirosaki, and R.J. Xie, Synthesis and photoluminescent properties of (La, Ca)3Si6N11:Ce3+ fine powder phosphors for solid-state lighting. ACS Appl. Mater. Interfaces 3, 811 (2011).

    Article  CAS  PubMed  Google Scholar 

  14. G.G. Li, C.C. Lin, W.T. Chen, M.S. Molokeev, V.V. Atuchin, C.Y. Chiang, W.Z. Zhou, C.W. Wang, W.H. Li, H.S. Sheu, T.S. Chan, C.G. Ma, and R.S. Liu, Photoluminescence tuning via cation substitution in oxonitridosilicate phosphors: DFT calculations, different site occupations, and luminescence mechanisms. Chem. Mater. 26, 2991 (2014).

    Article  CAS  Google Scholar 

  15. J.Q. Liu, X.J. Wang, T.T. Xuan, H.L. Li, and Z. Sun, Photoluminescence and thermal stability of Mn2+ co-doped SrSi2O2N2:Eu2+green phosphor synthesized by sol-gel method. J. Alloys Compd. 593, 128 (2014).

    Article  CAS  Google Scholar 

  16. C.H. Hsu, B.M. Cheng, and C.H. Lu, Photoluminescent properties and energy transfer mechanism of color-tunable CaSi2O2N2:Ce3+, Eu2+ phosphors. J. Am. Ceram. Soc. 94, 2878 (2011).

    Article  CAS  Google Scholar 

  17. R.S. Liu, Y.H. Liu, N.C. Bagkar, and S.F. Hu, Enhanced luminescence of SrSi2O2N2:Eu2+ phosphors by codoping with Ce3+, Mn2+, and Dy3+ ions. Appl. Phys. Lett. 91, 061119 (2007).

    Article  Google Scholar 

  18. J.R. Ling, Y.F. Zhou, W.T. Xu, H. Lin, S. Lu, B. Wang, and K. Wang, Red-emitting YAG: Ce, Mn transparent ceramics for warm WLEDs application. J. Adv. Ceram. 9, 45 (2020).

    Article  CAS  Google Scholar 

  19. M.B. Xie, J. Wang, and W.K. Ruan, Multi-site tunable emission of Eu2+ ions in Ca10Na(PO4)7 host. J. Lumin. 218, 116848 (2020).

    Article  CAS  Google Scholar 

  20. Y.C. Fang, P.C. Kao, Y.C. Yang, and S.Y. Chu, Effect of Si-N incorporation on color-tunable CaEuAl2-xSixO4-xNx phosphors: luminescence, thermal stability, and its application. J. Electrochem. Soc. 158, 120 (2011).

    Article  Google Scholar 

  21. O. Oeckler, F. Stadler, T. Rosenthal, and W. Schnick, Real structure of SrSi2O2N2. Solid State Sci. 9, 205 (2007).

    Article  CAS  Google Scholar 

  22. S.H. Wang, Y.Q. Xua, T. Chen, W.H. Jiang, J.M. Liu, X. Zhang, W. Jiang, and L.J. Wang, A red phosphor LaSc3(BO3)4:Eu3+ with zero-thermal-quenching and high quantum efficiency for LEDs. Chem. Eng. J. 404, 125912 (2021).

    Article  CAS  Google Scholar 

  23. B. Lei, K. Machida, T. Horikawa, and H. Hanzawa, Preparation of (Sr0.5Ba0.5) Si2N2O2:Eu2+ phosphor and its luminescence properties. Chem. Lett. 40, 140 (2011).

    Article  CAS  Google Scholar 

  24. Y.X. Gu, Q.H. Zhang, Y.G. Li, H.Z. Wang, and R.J. Xie, Enhanced emission from CaSi2O2N2:Eu2+ phosphors by doping with Y3+ ions. Mater. Lett. 63, 1448 (2009).

    Article  CAS  Google Scholar 

  25. Y.Y. Ma, F. Xiao, S. Ye, Q.Y. Zhang, and Z.H. Jiang, The effect of zinc acetate dihydrate on morphology and luminescence properties of CaSi2O2N2:Eu2+ phosphor. J. Am. Ceram. Soc. 96, 2238 (2013).

    Article  CAS  Google Scholar 

  26. Z.W. Wan, W.J. Tang, Q.L. You, B. Xiao, and G.Y. Xie, Charge compensating effect of rare earth ions Ln3+ (Ln = Y, La) on the photoluminescence improvement of Sr9MgK(PO4)7:Eu2+ phosphor. J. Lumin. 244, 118746 (2022).

    Article  CAS  Google Scholar 

  27. X. Huang, T.S. Wang, W.T. Zhang, Z. Zhao, X.M. Wang, and X. Gao, ACS Appl. Electron. Mater. 3, 4472 (2021).

    Article  CAS  Google Scholar 

  28. X.C. Li, R.F. Zhang, R.R. Cui, and C.Y. Deng, Luminescent properties of SrSi2O2N2:Eu2+ by the two-step synthesis. J. Alloys Compd. 650, 470 (2015).

    Article  CAS  Google Scholar 

  29. J.R. Hao, L. Cao, Y. Wei, C.J. Yan, and G.G. Li, Improving photoluminescence and thermal stability of CaSi2O2N2:Eu2+ phosphors by codoping lanthanide ions (Ln = Sc, La, Gd, Yb, Lu). Mater. Lett. 211, 122 (2018).

    Article  CAS  Google Scholar 

  30. E. Rai, R.S. Yadav, D. Kumar, A.K. Singh, V.J. Fulari, and S.B. Rai, Improved photoluminescence in Eu3+ doped LaVO4 phosphor via co-doping of Li+/Ca2+ ions. J. Lumin. 241, 118519 (2022).

    Article  CAS  Google Scholar 

  31. W. Lü, M.M. Jiao, B.Q. Shao, L.F. Zhao, and H.P. You, Enhancing photoluminescence performance of SrSi2O2N2:Eu2+ phosphors by Re (Re = La, Gd, Y, Dy, Lu, Sc) substitution and its thermal quenching behavior investigation. Inorg. Chem. 54, 9060 (2018).

    Article  Google Scholar 

  32. J.L. Qin, C.F. Hu, B.F. Lei, J.F. Li, Y.L. Liu, S.P. Ye, and M.Z. Pan, Temperature-dependent luminescence characteristic of SrSi2O2N2:Eu2+ phosphor and its thermal quenching behavior. J. Mater. Sci. Technol. 30, 290 (2014).

    Article  CAS  Google Scholar 

  33. J.S. Huo, W. Lü, B.Q. Shao, Y. Song, Y. Feng, S. Zhao, and H.P. You, Enhanced luminescence intensity of CaSi2O2N2:Eu2+ phosphor by using flux in the preparation process and incorporating Gd3+ ions. J. Lumin. 180, 46 (2016).

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported by the Guizhou Provincial Science and Technology Planning Project (No. ZK2023-144) and the Nature Science Foundation of Guizhou Minzu University (No. GZMUZK[2021]YB05)

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Correspondence to Fei Long or Xucheng Li.

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Wei, T., Wang, L., Xu, H. et al. Effects of Re3+ (Re = Y, La, Gd) Co-doping on Luminescence Properties of MSi2O2N2:Eu2+ (M = Ca, Sr) Phosphors. J. Electron. Mater. 53, 4880–4885 (2024). https://doi.org/10.1007/s11664-024-11243-1

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