Abstract
A low-permittivity Li5Al5Zn8Ge9O36 microwave dielectric ceramic was prepared via a conventional solid-phase reaction, and its sintering behavior, phase structure, and microwave dielectric properties were investigated. The Li5Al5Zn8Ge9O36 ceramic had a cubic spinel structure, and no other phases were detected. The microstructure of the ceramic was relatively uniform and dense. The Li5Al5Zn8Ge9O36 ceramic sintered at 1150°C exhibited excellent microwave dielectric properties (εr = 6.66, Q × f = 24,600 GHz, and τf = −38 ppm/°C), indicating that it is a good candidate for microwave equipment.
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References
T.A. Vanderah, Talking ceramics. Science 298, 1182–1184 (2002).
I.M. Reaney and D. Iddles, Microwave dielectric ceramics for resonators and filters in mobile phone networks. J. Am. Ceram. Soc. 89, 2063–2072 (2006).
M.T. Sebastian, R. Ubic, and H. Jantunen, Low-loss dielectric ceramic materials and their properties. Int. Mater. Rev. 60, 392–412 (2015).
B.K. Choi, S.W. Jang, and E.S. Kim, Dependence of microwave dielectric properties on crystallization behaviour of CaMgSi2O6 glass-ceramics. Mater. Res. Bull. 67, 234 (2015).
B. Ullah, W. Lei, Y.F. Yao, X.C. Wang, X.H. Wang, M. UrRahman, and W.Z. Lu, Structure and synergy performance of (1 - x)Sr0.25Ce0.5TiO3 -xLa(Mg0.5Ti0.5)O3 based microwave dielectric ceramics for 5G architecture. J. Alloys Compd. 763, 990 (2018).
D. Zhou, L.X. Pang, D.W. Wang, Z.M. Qi, and M. Reaney, High quality factor, ultralow sintering temperature Li6B4O9 microwave dielectric ceramics with ultralow density for antenna substrates. ACS Sustain. Chem. Eng. 6, 11138 (2018).
W. Lei, Z.Y. Zou, Z.H. Chen, B. Ullah, A. Zeb, X.K. Lan, W.Z. Lu, G.F. Fan, X.H. Wang, and X.C. Wang, Controllable τf value of barium silicate microwave dielectric ceramics with different Ba/Si ratios. J. Am. Ceram. Soc. 101, 25 (2018).
H. Yu, T. Luo, L. He, and J. Liu, Effect of ZnO on Mg2TiO4-MgTiO3-CaTiO3 microwave dielectric ceramics prepared by reaction sintering route. Adv. Appl. Ceram. 118, 98–105 (2019).
H. Zhou, X. Tan, X. Chen, and H. Ruan, Effect of raw materials pretreated by physical grinding method on the sintering ability and microwave dielectric properties of Li2MgTiO4 ceramics. J. Alloys Compd. 731, 839 (2018).
H. Zhou, J. Gong, N. Wang, and X. Chen, A novel temperature stable microwave dielectric ceramic with low sintering temperature and high quality factor. Ceram. Int. 42, 8822 (2016).
Y. Tian, Y. Tang, K. Xiao, C. Li, L. Duan, and L. Fang, Crystal structure, Raman spectroscopy and microwave dielectric properties of Li1+xZnNbO4 (0 ≤ x ≤ 0.05) ceramics. J. Alloys Compd. 777, 1–7 (2019).
Y. Ohishli, Y. Miyauchi, H. Ohsato, and K. Kakimoto, Controlled temperature coefficient of resonant frequency of A12O3-TiO2 ceramics by annealing treatment. Jpn. J. Appl. Phys. 43, L749–L751 (2004).
T. Tsunooka, M. Androu, Y. Higashida, H. Sugiura, and H. Ohsato, Effects of TiO2 on sinterability and dielectric properties of high-Q forsterite ceramics. J. Eur. Ceram. Soc. 23, 2573–2578 (2003).
H. Ohsato, T. Tsunooka, T. Sugiyama, K. Kakimoto, and H. Ogawa, Forsterite ceramics for millimeterwave dielectrics. J. Electroceram. 17, 445–450 (2006).
G. Anoop, K. Mini Krishna, and M.K. Jayaraj, The effect of Mg incorporation on structural and optical properties of Zn2GeO4: Mn phosphor. J. Electrochem. Soc. 155, J7–J10 (2008).
A. Navrotsky, Thermodynamic relations among olivine, spinel, and phenacite structures in silicates and germinates. IV. The system ZnO-MgO-GeO2. J. Solid State Chem. 12, 12–15 (1975).
S. Takahashi, A. Kan, and H. Ogawa, Microwave dielectric properties and crystal structures of spinel-structured MgAl2O4 ceramics synthesized by a molten-salt method. J. Eur. Ceram. Soc. 37, 1001–1006 (2017).
K.P. Surendran, N. Santha, P. Mohanan, and M.T. Sebastian, Temperature stable low loss ceramic dielectrics in (1–x)ZnAl2O4-xTiO2 system for microwave substrate applications. Eur. Phys. J. B 41, 301–306 (2004).
A. Belous, O. Ovchar, D. Durilin, M.M. Krzmanc, M. Valant, and D. Suvorov, High-Q microwave dielectric materials based on the spinel Mg2TiO4. J. Am. Ceram. Soc. 89, 3441–3445 (2006).
X.S. Lyu, L.X. Li, H. Sun, S. Li, J. Ye, and S. Zhang, A novel low-loss spinel microwave dielectric ceramic CoZnTiO4. J. Mater. Sci. Mater. Electron. 2015(26), 8663–8666 (2015).
H.C. Xiang, L. Fang, W.S. Fang, Y. Tang, and C.C. Li, A novel low-firing microwave dielectric ceramic Li2ZnGe3O8 with cubic spinel structure. J. Eur. Ceram. Soc. 37, 625–629 (2017).
H. Luo, L. Fang, H.C. Xiang, Y. Tang, and C.C. Li, Two novel low-firing germanates Li2MGe3O8 (M = Ni, Co) microwave dielectric ceramics with spinel structure. Ceram. Int. 43, 1622–1627 (2017).
K. Wang, H. Zhou, W. Sun, X. Chen, and H. Ruan, Solid-state reaction mechanism and microwave dielectric properties of 0.95MgTiO(3)-005CaTiO(3) ceramics. J. Mater. Sci. Mater. Electron. 29(3), 2001–2006 (2018).
M. Parastoo, T.-N. Ehsan, and T.-A. Hamid, Effect of zinc ions non-stoichiometry on the microstructure and microwave dielectric properties of Li2ZnTi3O8 ceramics. J. Alloys Compd. 695, 3772–3778 (2017).
W.S. Kim, E.S. Kim, and K.H. Yoon, Effects of Sm3+ substitution on dielectric properties of Ca1–xSm2x/3TiO3 ceramics at microwave frequencies. J. Am. Ceram. Soc. 82, 2111 (1999).
H.C. Xiang, L. Fang, X.W. Jiang, and C.C. Li, Low-firing and microwave dielectric properties of Na2YMg2V3O12 ceramic. Ceram. Int. 42, 3701–3705 (2016).
C.L. Huang and S.H. Huang, Low-loss microwave dielectric ceramics in the (Co1–xZnx) TiO3 (x = 0–0.1) system. J. Alloys Compd. 515, 8–11 (2012).
R.D. Shannon, Dielectric polarizabilities of ions in oxides and fluorides. J. Appl. Phys. 73, 348–366 (1993).
S.H. Yoon, D.W. Kim, S.Y. Cho, and K.S. Hong, Investigation of the relations between structure and microwave dielectric properties of divalent metal tungstate compounds. J. Eur. Ceram. Soc. 26, 2051–2054 (2006).
A.J. Bosman and E.E. Havinga, Temperature dependence of dielectric constants of cubic ionic compounds. Phys. Rev. 129, 1593–1600 (1963).
J. Varghese, T. Joseph, K.P. Surendran, T.P.D. Rajan, and M.T. Sebastian, Hafnium silicate: a new microwave dielectric ceramic with low thermal expansivity. Dalton Trans. 44, 5146–5152 (2015).
H.L. Dong and F. Shi, Effect of synthesis temperature on crystal structure and phonon modes of Ba[Zn1/3(Nb0.4Ta0.6)2/3]O3 ceramics. Cryst. Eng. Commun. 14, 8268–8273 (2012).
E.S. Kim, B.S. Chun, R. Freer, and R.J. Cernik, Effects of packing fraction and bond valence on microwave dielectric properties of A2+B6+O4 (A2+: Ca, Pb, Ba; B6+: Mo, W) ceramics. J. Eur. Ceram. Soc. 30, 1731–1736 (2010).
Acknowledgments
This work was supported by the Natural Science Foundation of China (Nos. 61761015 and 11664008), Natural Science Foundation of Guangxi (Nos. 2017GXNSFFA198011, 2018GXNSFFA050001 and 2017GXNSFDA198027) and High Level Innovation Team and Outstanding Scholar Program of Guangxi Institutes.
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Deng, S., Qu, X., Xiao, Y. et al. Sintering Behavior, Phase Structure, and Microwave Dielectric Properties of Low-Permittivity Li5Al5Zn8Ge9O36 Ceramics. J. Electron. Mater. 52, 2932–2939 (2023). https://doi.org/10.1007/s11664-023-10295-z
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DOI: https://doi.org/10.1007/s11664-023-10295-z