Skip to main content
Log in

Hydrothermal Synthesis of Single-Crystalline Ag-Doped ZnO Nanoneedles for Ultraviolet Detection

  • Original Research Article
  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

Abstract

In this work, Ag-doped zinc oxide (ZnO:Ag) nanoneedles (NNs) were synthesized by using a low-cost and facile hydrothermal method. The structure, morphology and optical properties of ZnO:Ag NNs were first investigated in detail. We observed a large number of needle-like ZnO:Ag rods with a top diameter in the range of 70–90 nm. The ZnO:Ag NNs were single-crystalline ZnO with hexagonal wurtzite structure. Furthermore, an ultraviolet photodetector (UV PD) was prepared using the ZnO:Ag NNs as a photoactive layer. The device exhibited excellent response to 365 nm light, and its responsivity, photosensitivity and response time were 24.64 A W−1 at 5 V, 58.42 at 0.5 V and 9.58 s, respectively. Also, the performance of ZnO:Ag NN UV PD was much better than that of the undoped ZnO PD, which was attributed to the improved electrical properties of ZnO NNs after Ag doping.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. F. Yang, J. Guo, L. Zhao, W. Shang, Y. Gao, S. Zhang, G. Gu, B. Zhang, P. Cui, G. Cheng, and Z. Du, Nano Energy 67, 104210 (2020).

    Article  CAS  Google Scholar 

  2. B. Ortiz-Casas, A. Galdámez-Martínez, J. Gutiérrez-Flores, A.B. Ibañez, P.K. Panda, G. Santana, H.A. de la Vega, M. Suar, C.G. Rodelo, A. Kaushik, Y.K. Mishra, and A. Dutt, Mater. Today 50, 533 (2021).

    Article  CAS  Google Scholar 

  3. D. Upadhaya and D.D. Purkayastha, Ceram. Int. 46, 15831 (2020).

    Article  CAS  Google Scholar 

  4. P. Gu, X. Zhu and D. Yang, J. Alloys Compd. 815, 152346 (2020).

    Article  CAS  Google Scholar 

  5. R.M. Hewlett and M.A. McLachlan, Adv. Mater. 28, 3893 (2016).

    Article  CAS  Google Scholar 

  6. T. Chen, X. Gao, J.Y. Zhang, J.L. Xu, and S.D. Wang, Adv. Opt. Mater. 8, 1901289 (2020).

    Article  CAS  Google Scholar 

  7. N. Nasiri, R. Bo, F. Wang, L. Fu, and A. Tricoli, Adv. Mater. 27, 4336 (2015).

    Article  CAS  Google Scholar 

  8. S.C. Rai, K. Wang, Y. Ding, J.K. Marmon, M. Bhatt, Y. Zhang, W. Zhou, and Z.L. Wang, ACS Nano 9, 6419 (2015).

    Article  CAS  Google Scholar 

  9. B. Zhao, F. Wang, H. Chen, L. Zheng, L. Su, D. Zhao, and X. Fang, Adv. Funct. Mater. 27, 1700264 (2017).

    Article  Google Scholar 

  10. T.H. Flemban, M.A. Haque, I. Ajia, N. Alwadai, S. Mitra, T. Wu, and I.S. Roqan, A.C.S. Appl. Mater. Interfaces 9, 37120 (2017).

    Article  CAS  Google Scholar 

  11. H. Yu, Q. Liao, Z. Kang, Z. Wang, B. Liu, X. Zhang, J. Du, Y. Ou, M. Hong, J. Xiao, Z. Zhang, and Y. Zhang, Small 16, 2005520 (2020).

    Article  CAS  Google Scholar 

  12. Z. Zhan, L. Xu, J. An, H. Du, Z. Weng, and W. Lu, Adv. Eng. Mater. 19, 1700101 (2017).

    Article  Google Scholar 

  13. H. Wu, Z. Yuan, B. Wang, F. Nie, J. He, X. Wang, and L. Liu, Opt. Mater. 122, 111683 (2021).

    Article  CAS  Google Scholar 

  14. M.A. Thomas, W.W. Sun, and J.B. Cui, J. Phys. Chem. C 116, 6383 (2012).

    Article  CAS  Google Scholar 

  15. Y. Wang, L. Zhu, Y. Feng, Z. Wang, and Z.L. Wang, Adv. Funct. Mater. 29, 1807111 (2019).

    Article  Google Scholar 

  16. J. Yu, H.J. Men, J.W. Zhang, X.W. Zhang, and N. Tian, J. Electron. Mater. 49, 4469 (2020).

    Article  CAS  Google Scholar 

  17. Y. Ji, L. Wu, Y. Liu, and Y. Yang, Nano Energy 89, 106449 (2021).

    Article  CAS  Google Scholar 

  18. K. Govatsi, G. Syrrokostas, S.N. Yannopoulos, and S.G. Neophytides, Electrochim. Acta 392, 138995 (2021).

    Article  CAS  Google Scholar 

  19. V.Q. Dang, T.Q. Trung, D.I. Kim, L.T. Duy, B.U. Hwang, D.W. Lee, B.Y. Kim, L.D. Toan, and N.E. Lee, Small 11, 3054 (2015).

    Article  CAS  Google Scholar 

  20. J.W. Oh, J.Y. Jeong, T.Y. Eom, S.D. Baek, and J.M. Myoung, Chem. Eng. J. 416, 129202 (2021).

    Article  CAS  Google Scholar 

  21. Y. Zhao, H. Zhang, X. Wu, Y. Yang, and T.L. Ren, Phys. Status Solidi - Rapid Res. Lett. 15, 2000512 (2021).

    Article  CAS  Google Scholar 

  22. P. Srinivasan and J.B.B. Rayappan, Sens. Actuators B 277, 129 (2018).

    Article  CAS  Google Scholar 

  23. Y. Al-Hadeethi, A. Umar, A.A. Ibrahim, S.H. Al-Heniti, R. Kumar, S. Baskoutas, and B.M. Raffah, Ceram. Int. 43, 6765 (2017).

    Article  CAS  Google Scholar 

  24. M.I. Khan, K.A. Bhatti, R. Qindeel, L.G. Bousiakou, and N. Alonizan, and Fazal-e-Aleem. Results Phys. 6, 156 (2016).

    Article  Google Scholar 

  25. V. Manthina, T. Patel, and A.G. Agrios, J. Am. Ceram. Soc. 97, 1028 (2014).

    Article  CAS  Google Scholar 

  26. G. Fiaschi, S. Mirabella, G. Franzò, L. Maiolo, A. Chitu, Y. Komem, and Y. Shacham-Diamand, Appl. Surf. Sci. 458, 800 (2018).

    Article  CAS  Google Scholar 

  27. F.C. Romeiro, J.Z. Marinho, A.C.A. Silva, N.F. Cano, N.O. Dantas, and R.C. Lima, J. Phys. Chem. C 117, 26222 (2013).

    Article  CAS  Google Scholar 

  28. H. Zhang, S. Yu, C. Chen, J. Zhang, J. Liu, and P. Li, Appl. Surf. Sci. 486, 482 (2019).

    Article  CAS  Google Scholar 

  29. D.A. Guzmán-Embús, M.F. Vargas-Charry, and C. Vargas-Hernández, J. Am. Ceram. Soc. 98, 1498 (2015).

    Article  Google Scholar 

  30. L. Qin, F.J. Mawignon, M. Hussain, N.K. Ange, S. Lu, M. Hafezi, and G. Dong, Materials 14, 4083 (2021).

    Article  CAS  Google Scholar 

  31. T. Shen, J. Wang, Z. Xia, X. Dai, B. Li, and Y. Feng, Sens. Actuators A 307, 111989 (2020).

    Article  CAS  Google Scholar 

  32. K.K. Khichar, S.B. Dangi, V. Dhayal, U. Kumar, S.Z. Hashmi, V. Sadhu, B.L. Choudhary, S. Kumar, S. Kaya, A.E. Kuznetsov, S. Dalela, S.K. Gupta, and P.A. Alvi, Polym. Compos. 41, 2792 (2020).

    Article  CAS  Google Scholar 

  33. G. Lal, K. Punia, S.N. Dolia, P.A. Alvi, B.L. Choudhary, and S. Kumar, J. Alloys Compd. 828, 154388 (2020).

    Article  CAS  Google Scholar 

  34. V. Dhayal, S.Z. Hashmi, U. Kumar, B.L. Choudhary, A.E. Kuznetsov, S. Dalela, S. Kumar, S. Kaya, S.N. Dolia, and P.A. Alvi, J. Mater. Sci. 55, 14829 (2020).

    Article  CAS  Google Scholar 

  35. B.L. Choudhary, U. Kumar, S. Kumar, S. Chander, S. Kumar, S. Dalela, S.N. Dolia, and P.A. Alvi, J. Magn. Magn. Mater. 507, 166861 (2020).

    Article  CAS  Google Scholar 

  36. U. Kumar, S. Upadhyay, and P.A. Alvi, Phys. B Condens. Matter 604, 412708 (2021).

    Article  CAS  Google Scholar 

  37. K. Punia, G. Lal, S. Dalela, S.N. Dolia, P.A. Alvi, S.K. Barbar, K.B. Modi, and S. Kumar, J. Alloys Compd. 868, 159142 (2021).

    Article  CAS  Google Scholar 

  38. V. Dhayal, S.Z. Hashmi, U. Kumar, B.L. Choudhary, S. Dalela, S.N. Dolia, and P.A. Alvi, Opt. Quantum Electron. 53, 1 (2021).

    Article  Google Scholar 

  39. K. Kumari, R.N. Aljawfi, A.K. Chawla, R. Kumar, P.A. Alvi, A. Alshoaibi, A. Vij, F. Ahmed, M. Abu-samak, and S. Kumar, Ceram. Int. 46, 7482 (2020).

    Article  CAS  Google Scholar 

  40. M. Sharma, S. Kumar, R.N. Aljawfi, S. Dalela, S.N. Dolia, A. Alshoaibi, and P.A. Alvi, J. Electron. Mater. 48, 8181 (2019).

    Article  CAS  Google Scholar 

  41. M. Shahid, J. Cheng, T. Li, M.A. Khan, Y. Wang, Y. Hu, M. Zhang, J. Yang, H.S. Aziz, C. Wan, H. Nishijima, and W. Pan, J. Mater. Chem. C 6, 6510 (2018).

    Article  CAS  Google Scholar 

  42. L. Yin, H. Ding, Z. Yuan, W. Huang, C. Shuai, Z. Xiong, J. Deng, and T. Lv, Opt. Mater. 80, 149 (2018).

    Article  CAS  Google Scholar 

  43. P. Wang, Y. Wang, L. Ye, M. Wu, R. Xie, X. Wang, X. Chen, Z. Fan, J. Wang, and W. Hu, Small 14, 1800492 (2018).

    Article  Google Scholar 

  44. X. Wang, K. Liu, X. Chen, B. Li, M.-M. Jiang, Z. Zhang, H. Zhao, D. Shen, and A.C.S. Appl, Mater. Interfaces 9, 5574 (2017).

    Article  CAS  Google Scholar 

  45. C. Kumar, B.K. Kushwaha, A. Kumar, D.K. Jarwal, R.K. Upadhyay, A.P. Singh, and S. Jit, IEEE Photonic Tech. Lett. 32, 337 (2020).

    Article  CAS  Google Scholar 

  46. F. Teng, W. Ouyang, Y. Li, L. Zheng, and X. Fang, Small 13, 1700156 (2017).

    Article  Google Scholar 

  47. R.N. Gayen, R. Paul, and S. Biswas, Appl. Surf. Sci. 533, 147149 (2020).

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was partially financial supported by the National Natural Science Foundation of China (Grant No. 11865002), Jiangxi Provincial Natural Science Foundation (No. 20212BAB201003), Scientific Research Project of the Education Bureau of Jiangxi Province, China (Grant No. GJJ190367), the Graduate Innovation Foundation of East China University of Technology (Grant No. YC2021-S624) and Scientific Research Project of East China University of Technology (Grant No. DHBK2019214).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to Zhaolin Yuan or Biyi Wang.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Xu, M., Yuan, Z., Wang, B. et al. Hydrothermal Synthesis of Single-Crystalline Ag-Doped ZnO Nanoneedles for Ultraviolet Detection. J. Electron. Mater. 51, 7020–7027 (2022). https://doi.org/10.1007/s11664-022-09931-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11664-022-09931-x

Keywords

Navigation