Skip to main content

Formulation and Characterization of Sinterless Barium Strontium Titanate (BST) Dielectric Nanoparticle Ink for Printed RF and Microwave Applications


Here, we report a previously unreported low-temperature curable barium strontium titanate (BaXSr1−XTiO3) or BST dielectric nanoparticle ink which shows a high dielectric tunability for printed electronics/additive manufacturing applications. The newly formulated BST ink is optimized to print in aerosol jet printers and can be cured at 150°C, which will allow the fabrication of tunable radio-frequency (RF) and microwave (MW) devices on a wide range of flexible substrates. Characterization of high-frequency dielectric properties showed a high dielectric tunability (~ 15% at 10 GHz with 10 V/µm) and a high dielectric constant (~ 16 at 10 GHz). The linear-reversible tunability, which is very important for tunable devices, was confirmed by the tunability testing at 10 GHz. Characterization of temperature-dependent dielectric properties found < 10% variations of the dielectric constant at 10 GHz from −50°C to 125°C for this BST ink. Detailed information on BST nanoparticle characterization, ink formulation and characterization of dielectric properties is discussed.


Tunable radio-frequency (RF) and microwave devices play an important role in reconfigurable systems, and when combined with additive manufacturing and printed electronics, they can provide advantages in terms of cost, size and form factor.1,2,3,4,5 The demand for printable electronics over conventional electronics is rising exponentially due to the extremely low fabrication cost, low material consumption and wastage, compatibility with flexible substrates, durability and ease of customization.

Barium strontium titanate (BST) has been extensively investigated over the last few decades due to its tunable dielectric properties.6,7,8,9,10,11,12,13,14,15,16,17,18 The dielectric constant of BST can be tailored by an applied electric field, which allows BST to be used in varactors for tunable RF and microwave (MW) applications, such as tunable filters, phase shifters, frequency selective surfaces, phased arrays and conformal antennas.2,4,19,20,21,22,23,24,25 BST has a para-electric phase above the Curie temperature (TC) due to the cubic and symmetric crystal structure, with no spontaneous polarization. Below the Curie temperature, BST has a ferroelectric phase due to the spontaneous polarization of the non-center symmetric crystal structure.26,27 In the para-electric phase, BST shows the highest dielectric properties, such as high tunability, low loss tangent and high switching speed.28

Various techniques, such as pulsed laser deposition, chemical vapor deposition and sputtering are well-established deposition techniques for the fabrication of BST-based electronic devices.17,29,30,31,32,33 However, all these techniques require high processing temperatures that are not suitable for flexible substrates and fabrics. Moreover, it is difficult to vary the highest effective dielectric constant in these deposition techniques.

Different types of direct-write noncontact functional ink printers, such as inkjet printers, aerosol jet printers and dispensing printers, are widely used in printed electronics research and development as well as in small-scale manufacturing.34,35,36,37,38,39,40,41,42,43,44 Nonetheless, these printers have different specifications and limitations. For example, the viscosity of functional inks needs to be below 1000 cP in order to be printed in Optomec aerosol jet printers with pneumatic atomization, while a viscosity of less than 10 cP is necessary to be printed in Optomec aerosol jet printers with ultrasonic atomization. Therefore, printer-specific functional inks are very important for printed electronic device fabrication. Optomec aerosol jet printers can be used to print high-resolution features as low as 10 µm with the best conditions. Also, the newest version of the Optomec AJ5X aerosol jet printer has the capability to print on any three-dimensional (3D) object using its five-axis (X, Y, Z, rotation and tilting) motion. It is necessary to have a high-quality printable BST ink in order to get the advantage of this five-axis aerosol jet printers when printing electronic devices with small feature sizes. However, there is no previously reported stable BST ink for aerosol jet printers to print high-resolution tunable electronic devices.

Functional inks are one of the most important components in printed electronics fabrication since the performance of a printed electronic device depends greatly on the properties of the functional inks and the device design. Even though device design and optimization are widely explored areas, functional ink development is a relatively unexplored area, especially for aerosol jet printing. The RF properties, including the complex dielectric constant (real part and loss tangent) and the degree of tunability of a functional ink, must be optimized to achieve the highest possible performance of devices. In addition to electromagnetic properties, there are several factors that need to be considered when developing a functional ink, such as the stability of the ink without any nanoparticle agglomeration, decreased foaming, controllable printability, long shelf life, low curing temperature, higher adhesion and good wettability on a wide range of substrates and less toxicity. Also, the number of compatible printing technologies is another key factor to be considered at the commercialization stage.

In this work, we have formulated and optimized a sinterless BST nanoparticle ink for aerosol jet printers, which is suitable for the fabrication of RF and MW applications. This ink can be cured at 150°C, and it does not need the sintering at a higher temperature. Spherical BST nanoparticles with a diameter of ~ 80 nm were used in this ink. We have provided experimental evidence for previously unreported high dielectric tunability at 10 GHz for this BST ink. In addition to that, it shows a high dielectric constant and low loss tangent in the 2–12-GHz frequency range. Most importantly, this BST ink can be processed at a relatively low temperature, which is suitable for most of the flexible and rigid substrates.

Materials and Methods

List of Materials

Barium strontium titanate (Ba0.67Sr0.33TiO3) nanoparticles and ammonium polymethacrylate in water (commercial name – NanoSperse S) were purchased from TPL Inc. (New Mexico, USA). Ethylene glycol (99%) was purchased from Fisher Scientific (USA). 1-Methoxy-2-propanol (99.5%) was purchased from Sigma-Aldrich (USA). All the chemicals were used without further purification. Paru MicroPE PG-007 silver nanoparticle ink was purchased from Paru Co., Ltd. (South Korea). Different types of substrates that are suitable for RF and MW applications were tested with BST nanoparticle ink. RO3850, RO3035, RO5780 and liquid crystal polymer (LCP) substrates were purchased from Rogers Corporation (USA). Kapton general-purpose polyamide films were purchased from DuPont (USA).

BST Ink Formulation, Printing and Curing Procedure

BST nanoparticles (50 wt.%) were added to ethylene glycol and sonicated for 8 h in the pulse mode (active = 15 s, inactive = 59 s) using a QSONICA Q500 ultrasonic processor with a 2-mm micro-tip. Then, ammonium polymethacrylate in water (~ 2 wt.%) was added into the mixture as a dispersant and sonicated for another 30 min in the pulse mode (active = 5 s, inactive = 59 s). This BST nanoparticle dispersion was used as a stock solution for the BST ink formulation. A custom-made BST nanoparticle dispersion in ethylene glycol, which had the exact same components and amounts, was directly purchased from TPL Inc.

In this work, the BST ink was formulated and optimized for aerosol jet printers. Ink was formulated by adding ethylene glycol (25 wt.%) and 1-methoxy-2-propanol (25 wt.%) to the previously prepared BST dispersion (stock solution), and the mixture was magnetically stirred overnight at 400 rpm in order to obtain a homogenous ink. This ink was developed to print thin (< 10 µm) and smaller features (< 100 µm) in aerosol jet printers and to achieve a higher dielectric tunability and a non-varying dielectric constant at higher frequencies (2–12 GHz) with a low loss tangent. Optomec AJ200 and AJ5X aerosol jet printers with pneumatic atomizers were used to print the BST ink. A Fisher Scientific vacuum oven was used to cure the printed features at 150°C for 60 min under vacuum.

Characterization Techniques

An ARES-G2 rheometer (TA Instruments) was used to measure the viscosities of the ink. Ink samples were loaded in a 400-mm diameter, 0.04-rad stainless-steel cone and plate geometry. Flow sweeps from 1 s−1 to 100 s−1 were recorded at 25°C using an Advanced Peltier System for temperature control. A Biolin Scientific Attension Theta contact angle measurement system was used to measure the contact angles of the ink on different substrates. A Scintag PAD x-ray diffractometer operating at 40 kV was used to investigate the crystal structure of BST nanoparticles. A JEOL JEM-2100 transmission electron microscope operating at 200 keV was used to obtain both conventional and high-resolution transmission electron microscopy (HRTEM) images of BST nanoparticles. A Zeiss Auriga focused ion beam scanning electron microscope (FIB) operating at 5 keV was used to investigate the surface morphology and the cross sections of printed features. A gallium liquid metal ion source at 30 kV and 50 pA was used for FIB milling. An Agilent Cary 8454 ultraviolet/visible/near-infrared (UV/Vis/NIR) spectrophotometer was used for UV–Vis absorption measurements of liquid ink. A Keyence VHX-5000 digital microscope was used for the initial investigation of cracks after the curing. Also, a 1000× lens was used for 3D stitching to investigate the surface roughness and the step heights of printed features. A VTC-50 desktop spin coater was used to prepare spin-coated BST films for tunability measurements. A Keysight N5225A PNA microwave network analyzer (50 GHz) was used to collect the S11 reflection coefficients of the BST ink-filled test devices. Fully printed concentric cylindrical capacitors were used as the test devices. Picoprobe model 40A ground-signal-ground (GSG) RF probes with an 800-µm pitch were used to probe the test devices from 2 GHz to 12 GHz. An MPI TS2000-SE probe station with an ERS temperature chuck was used to collect the temperature-dependent S11 reflection coefficients of the BST ink-filled test devices.

Extraction Method of Dielectric Properties of BST Nanoparticle Ink

Fully printed concentric cylindrical capacitors on Kapton substrates with a 200-µm gap were used as the device under test (DUT) (Figs. S1 and S2) for the extraction of the dielectric constant and the loss tangent.5,45 Paru MicroPE PG-007 silver ink was used in the Optomec AJ200 aerosol jet printer to print the DUT. The printed DUT was cured/sintered at 250°C for 3 h in a vacuum oven. The BST ink was filled into the gap of the DUT using the Nordson automatic dispensing system and cured according to the specification mentioned in “BST Ink Formulation, Printing and Curing Procedure” section. The height of the DUT was measured using the 3D profiles obtained from the Keyence VHX-5000 digital microscope before and after the BST filling to calculate the accurate height of the BST filling. S11 reflection coefficients of the DUT were collected before and after the BST filling and the dielectric constant and the loss tangent were extracted. The detailed extraction method can be found in the supporting information section.

BST layers of around 10–30 µm were spin coated on copper substrates, and then concentric cylindrical capacitors with 200-µm gaps were printed on these BST layers (Fig. S3) to extract the dielectric tunability of BST ink. S11 reflection coefficients were collected at different applied electric field strengths up to 10 V/µm. The detailed extraction method can be found in the supporting information section. Moreover, temperature-dependent S11 reflection coefficients were collected from −50°C to 125°C in order to extract the dielectric constants and the loss tangents at different temperatures to determine the variability of the dielectric properties with respect to temperature.

Results and Discussion

X-ray Diffraction Patterns and TEM/HRTEM Images of BST Nanoparticles

X-ray diffraction (XRD) patterns confirmed the single-phase cubic structure of BST nanoparticles (Fig. 1a), which confirmed the para-electric phase (nonpolar phase) of BST nanoparticles at room temperature.27 The calculated lattice constant using the XRD data was a = 3.97 Å, which is consistent with previous reports.28 In order to achieve the dielectric tunability of BST nanoparticles under an applied electric field, BST nanoparticles must be in the para-electric phase.27 Figure 1b shows the TEM image of BST nanoparticles in the BST dispersion (stock solution), and the average size of the nanoparticles is around 80 nm. The HRTEM image in Fig. 1c shows the atomic planes corresponding to BST (110) planes. The measured d-spacing is 2.81 Å, which is consistent with XRD results and closely matches previous reports.12,15

Fig. 1.
figure 1

(a) X-ray diffraction pattern of BST nanoparticles. (a) TEM image, (b) HRTEM image of BST nanoparticles.

Composition of the BST Nanoparticle Ink

In order to achieve the dielectric tunability, it is necessary to have the para-electric phase of BST nanoparticles at room temperature.27 Therefore, the Ba molar faction was set to 0.67 according to previous work.28 Detailed information about the variation of the Ba molar fraction and the operational temperature range of the para-electric phase of BST nanoparticles can be found elsewhere.28

Table I shows the composition of the BST nanoparticle ink. Spherical BST nanoparticles with Ba/Sr = 67:33 were used as the main functional material.28 Ammonium polymethacrylate was used as the dispersant to disperse BST nanoparticles in ethylene glycol, which was used as the stock solution for the BST nanoparticle ink. The BST nanoparticle dispersion was highly stable for over 1 year in the refrigerator. The high boiling point, dynamic viscosity of around 15 cP at room temperature and the solvent compatibility (with mostly used solvents for ink formulations) of ethylene glycol provide more freedom for different ink formulations.46 These are the main reasons for using ethylene glycol as the main solvent in this work. 1-Methoxy-2-propanol was used as the secondary solvent, which has a lower boiling point compared to ethylene glycol and forms a miscible solution with ethylene glycol. The relatively high vapor pressure of 1-methooxy-2-propanol increases the drying rate, which in turn will decrease the curing temperature.47,48,49 The lower curing temperature allows this ink to be used in a wide range of low-temperature flexible substrates. Also, the faster drying rate helps to remove most of the solvents right after the deposition by increasing the platen temperature of the printer. This will allow printing of multiple layers continuously without curing each layer. In addition to that, 1-methoxy-2-propanol improves aerosol generation, and most of it will evaporate during the deposition. Therefore, the contribution of 1-methoxy-2-propanol to the wet thickness of printed features is minimal. Less solvent contribution to the wet thickness always helps to minimize the cracking and the coffee ring effect during the curing of printed films. BST nanoparticles of the ink (after the curing) were randomly packed, and there were air gaps between BST nanoparticles.

Table I. BST nanoparticle ink composition

UV-Vis Absorption Spectra of the BST Nanoparticle Dispersion and the BST Nanoparticle Ink

Figure 2 shows the UV–Vis absorption spectra of the BST nanoparticle dispersion and the BST ink. The broader absorption peak around 366 nm can be assigned to the bandgap absorption of BST nanoparticles in the BST nanoparticle dispersion. The absorption peak of the BST ink is around 354 nm, which is slightly blueshifted compared to the BST nanoparticle dispersion. The blueshift of the peak can be attributed to the breaking down of the agglomerated BST nanoparticles in the BST ink due to the additional solvent, 1-methoxy-2-propanol. Agglomerated BST nanoparticles of the BST nanoparticle dispersion can also be seen in the TEM image in Fig. 1b.

Fig. 2.
figure 2

UV–Vis absorption spectra of BST nanoparticle dispersion (black) and BST ink (red) (Color figure online).

Viscosity and Contact Angles of the BST Nanoparticle Dispersion and the BST Nanoparticle Ink

Figure 3 shows the dynamic viscosity variation with the shear rate up to 100 s−1 for the BST nanoparticle dispersion and the BST ink. BST nanoparticle dispersion shows a strong shear thinning behavior mostly due to the dissociation and the settling of agglomerated BST nanoparticle clusters. The viscosity of the BST nanoparticle dispersion dropped by 94 % from 1.00 s−1 to 100 s−1. However, the BST ink only showed a 13% drop in viscosity in the same range of shear rates, and that can be attributed to the breakdown of most of the agglomerated BST nanoparticle clusters due to the secondary solvent, 1-methoxy-2-propanol. The Newtonian behavior of the viscosity over the range of shear rates is an indication of a stable ink for high-shear jetting, such as inkjet printing.50 In aerosol jet printing, inks will not experience very high shearing, but in inkjet printing, inks will experience very high shearing near the nozzle. The viscosity of the BST ink was around 22.5 cP at a 1.00-s−1 shear rate, which is in the range of viscosities that can be printed using pneumatic atomizers in aerosol jet printers as well as most of the inkjet printers.

Fig. 3.
figure 3

Viscosity vs. shear rate graphs for the BST nanoparticle dispersion (black) and the BST ink (red) (Color figure online).

Table II shows the contact angles of the ink on different substrates that are suitable for high-frequency applications. The contact angle of the BST ink was smaller than 90° for all the tested substrates, and it confirmed the good wettability of the ink. The optical images of the contact angles on different substrates can be found in Fig. S4. Even though the smaller contact angles show a higher wettability, it is necessary to have a moderate contact angle to control the dimensions of the printed features with high precision.

Table II. Contact angles of BST nanoparticle inks on different substrates

Printing and Curing of the BST Nanoparticle Ink

BST ink was printed in Optomec AJ200 and AJ5X aerosol jet printers with a pneumatic atomizer. Flow rates of 650 cm3/min, 640 cm3/min and 50 cm3/min were used for the pneumatic atomizer, the exhaust and the sheath gas, respectively. The flow rates were optimized to achieve high-quality printed lines with minimum overspraying. The deposited volume of the ink mainly depends on the difference between the flow rates of the pneumatic atomizer and the exhaust. The sheath gas flow rate was mainly used to adjust the line width; the higher the sheath gas, the lower the line width. The smallest line width achieved was around 100 µm with a 300-µm tip. If necessary, a smaller tip size (100 µm or 150 µm) can be used to achieve smaller features (~ 20 µm to 30 µm). The printing speed was 10 mm/s, and the thickness of one layer was around 4 µm. The plate was heated up to 70°C, and it helped to evaporate most of the solvents during the printing, which allowed the continuous printing of multiple layers without the complete curing of printed samples. Seven layers were printed continuously with the above printing parameters, and the layer thickness was close to 30 µm.

The curing temperature is critical for most of the printed electronics applications due to the low melting point of flexible substrates.51,52 The curing temperature of the ink in this study was 150°C for 60 min in a vacuum oven. Much of the previous work done with sintered BST nanoparticles used very high processing temperatures. According to the author’s knowledge, no work has been reported on a BST ink that could be cured below 150°C. The closest reported low-curing BST ink was a BST/cyclic olefin copolymer (COC) nanocomposite ink, which was cured at 200°C.5 The BST ink was stable when continuously printed for a few hours without clogging the aerosol jet printers.

Surface and Cross-Sectional SEM Images of the BST Nanoparticle Ink

Figure 4a and b show the SEM images of the surface and the cross section of the cured BST ink, respectively. After the curing, the printed feature only has randomly packed pure BST nanoparticles with air-filled pores that can be seen in Fig. 4b. The individual BST nanoparticles are around 80 nm, but agglomerated nanoparticles (nanoclusters) on the order of 1 µm were identified using both surface and cross-sectional SEM images. These agglomerated nanoparticles decrease the packing density, which creates air-filled pores. The air-filled pores will decrease the effective dielectric constant of the printed BST feature. As a result, the solid density of the final cured BST device is relatively low compared to sintered BST devices. Therefore, a high dielectric constant that is similar to sintered BST devices cannot be expected. Integrating a filler material is the best solution to fill the pores, which will help to increase the effective dielectric constant after the curing. However, introducing polymer materials into the aerosol jet inks is challenging due to difficulties in dissolving polymers in aerosol jet ink-compatible solvents, inefficient aerosol generation, and tip clogging. Even though the characterization of pores is not the goal of this work, several investigations are underway in parallel to this work to decrease the pore density to increase the effective dielectric constant.

Fig. 4.
figure 4

(a) Surface SEM image and the (b) cross-sectional SEM image of the cured BST ink.

Dielectric Properties of the BST Nanoparticle Ink

The dielectric constant and the loss tangent of the BST ink were extracted between 2 GHz and 12 GHz. The details of the extraction procedure can be found in the supporting information section. Figure 5a shows the variation of the dielectric constant from 2 GHz to 12 GHz. A table of dielectric constants and loss tangents at 10 GHz can be found in the Supplementary Information (Table S1). The dielectric constant of the cured BST ink did not show a large variation throughout the tested frequency range. The extracted dielectric constant and loss tangent were 16.13 ± 0.71 and 0.06 ± 0.01 at 10 GHz, respectively.

Fig. 5.
figure 5

(a) The variation of the dielectric constant between 2 GHz and 12 GHz. (b) Dielectric tunability at 10 GHz under different applied electric field strengths (Color figure online).

Figure 5b shows the dielectric tunability vs. the applied electric field strength for the BST ink. The highest tunability of around ~ 15% was achieved at 10 GHz with the applied electric field strength of 10 V/µm. This value for tunability is the highest that has been reported for non-sintered BST at 10 GHz. The tunability calculation method can be found in the supporting information (“Results and Discussion” section). The para-electric phase of the BST crystal lattice has a symmetric cubic structure, and the Ti atom is located in the center of the unit cell.27 Under an applied external electric field, the Ti atom could get shifted away from the equilibrium position.27 The Ti atom would continue to oscillate, but with less intensity, which will decrease the dielectric constant.27 The capacitance between the middle circular part of the DUT and the ground plane was used to calculate the tunability. At the device level, reversible tunability is very important to make a reliable device. The reversible tunability was tested by increasing and decreasing the applied electric field strength. In both directions, BST ink showed a very consistent tunability (Fig. S5).

There are some potential applications in space and harsh weather for BST-based tunable devices, which require thermal stability over a broad range of temperatures. Figure 6 shows the variations of the dielectric constant and the loss tangent at 10 GHz from − 50°C to 125°C for the BST ink. The temperature of the chuck of the probe station was adjusted, and after the temperature was stabilized, S11 parameters were measured in order to extract the dielectric constant in the same way as mentioned in “Extraction Method of Dielectric Properties of BST Nanoparticle Ink” section. The maximum variation of the dielectric constant between −50°C and 125°C was ~ 10%. The loss tangent increased at lower and higher temperatures compared to room temperature. The effects of structural changes of the printed silver DUT due to thermal expansion and contraction could be the possible reason for the extracted higher loss tangent at temperatures different from room temperature.

Fig. 6.
figure 6

The variation of (a) dielectric constant and (b) loss tangent from −50°C to 125°C (Color figure online).


A sinterless BST nanoparticle ink was formulated and characterized for aerosol jet printers. There are no previously reported sinterless BST nanoparticle inks that use low processing temperatures (< 150°C) and have good printing performance with similar or higher dielectric properties between the 2-GHz and 12-GHz frequency region. The dielectric constant, the loss tangent and tunability showed reproducible results, which would allow this BST nanoparticle ink to be used in printed radio-frequency and microwave applications. The maximum tunability of ~ 15% at 10 GHz was obtained with the applied electric field strength of 10 V/µm. The maximum dielectric constant variation (at 10 GHz) between −50°C and 125°C was around 10%. The BST ink was tested on several flexible and rigid substrates, and the ink was compatible with a wide range of tested substrates. This BST ink was formulated and optimized for aerosol jet printers, but it is not limited to aerosol jet printing technology. The ink could be easily modified for other printing techniques, such as inkjet, screen printing, gravure and flexographic printing technologies.


  1. A. Tombak, J. Maria, F. Ayguavives, J. Zhang, G.T. Stauf, A.I. Kingon, and A. Mortazawi, IEEE Microw. Wirel. Compon. Lett. 12, 3 (2002).

    Google Scholar 

  2. M. Haghzadeh, and A. Akyurtlu, J. Appl. Phys. 120, 184901 (2016).

    Google Scholar 

  3. M. Haghzadeh, C. Armiento, and A. Akyurtlu, IEEE Trans. Microw. Theory Tech. 65, 2030 (2017).

    Google Scholar 

  4. M. Haghzadeh, L. M. Bhowmik, C. Armiento, and A. Akyurtlu, in 2014 USNC-URSI Radio Science Meeting (Joint with AP-S Symposium), pp. 154 (2014).

  5. M. Haghzadeh, C. Armiento, and A. Akyurtlu, in 2016 IEEE MTT-S International Microwave Symposium (IMS), p. 1. (2016)

  6. H. Wang, Y. Dong, and Z. Wang, J. Alloys Compd. 745, 651 (2018).

    CAS  Google Scholar 

  7. M. Mikolajek, A. Friederich, C. Kohler, M. Rosen, A. Rathjen, K. Krüger, and J.R. Binder, Adv. Eng. Mater. 17, 1294 (2015).

    CAS  Google Scholar 

  8. B. Hou, Y. Xu, D. Wu, and Y. Sun, Powder Technol. 170, 26 (2006).

    CAS  Google Scholar 

  9. D. Dong, X. Liu, H. Yu, and W. Hu, Ceram. Int. 37, 579 (2011).

    CAS  Google Scholar 

  10. L. Huang, Z. Jia, I. Kymissis, and S. O’Brien, Adv. Funct. Mater. 20, 554 (2010).

    CAS  Google Scholar 

  11. V. Somani, and S.J. Kalita, J. Electroceram. 18, 57 (2007).

    CAS  Google Scholar 

  12. C.W. Beier, M.A. Cuevas, and R.L. Brutchey, J. Mater. Chem. 20, 5074 (2010).

    CAS  Google Scholar 

  13. E. Yustanti, M.A.E. Hafizah, and A. Manaf, AIP Conf. Proc. 1725, 020102 (2016).

    Google Scholar 

  14. S. Yang, B.R. Tull, N.K. Pervez, L. Huang, E.S. Leland, D.A. Steigart, S. O’Brien, and I. Kymissis, J. Polym. Sci. Part B Polym. Phys. 51, 35 (2013).

    CAS  Google Scholar 

  15. C.W. Beier, J.M. Sanders, and R.L. Brutchey, J. Phys. Chem. C 117, 6958 (2013).

    CAS  Google Scholar 

  16. F.A. Rabuffetti, J.S. Lee, and R.L. Brutchey, Chem. Mater. 24, 3114 (2012).

    CAS  Google Scholar 

  17. S. Ketkar, Synthesis, Characterization and Applications of Barium Strontium Titanate Thin Film Structures (2013).

  18. S. Liu, S. Xue, W. Zhang, J. Zhai, and G. Chen, J. Mater. Chem. A 2, 18040 (2014).

    CAS  Google Scholar 

  19. T. Ikeda, S. Saito, and Y. Kimura, in 2018 IEEE International Symposium on Antennas and Propagation & USNC/URSI National Radio Science Meeting, pp. 279 (2018).

  20. S.P. Bruss, and R.R. Spencer, IEEE Microw. Wirel. Compon. Lett. 19, 596 (2009).

    Google Scholar 

  21. M. Nikfalazar, C. Kohler, A. Wiens, A. Mehmood, M. Sohrabi, H. Maune, J.R. Binder, and R. Jakoby, IEEE Microw. Wirel. Compon. Lett. 26, 70 (2016).

    Google Scholar 

  22. M. Nikfalazar, M. Sazegar, A. Mehmood, A. Wiens, A. Friederich, H. Maune, J.R. Binder, and R. Jakoby, IEEE Antennas Wirel. Propag. Lett. 16, 585 (2017).

    Google Scholar 

  23. L. Ma, F. Meng, X. Liu, and P. Wang, in Proceedings of 2014 3rd Asia-Pacific Conference on Antennas and Propagation, pp. 1389 (2014).

  24. G. Velu, K. Blary, L. Burgnies, A. Marteau, G. Houzet, D. Lippens, and J. Carru, IEEE Trans. Microw. Theory Tech. 55, 438 (2007).

    CAS  Google Scholar 

  25. V. Sanchez-Romaguera et al., J. Mater. Chem. C 3, 2132 (2015).

    CAS  Google Scholar 

  26. M. Kunduraci, W. K. Simon, E. K. Akdogan, and A. Safari, in 14th IEEE International Symposium on Applications of Ferroelectrics, 2004. ISAF-04. 2004, pp. 21 (2004).

  27. S. Gevorgian, Ferroelectrics in Microwave Devices, Circuits and Systems: Physics, Modeling, Fabrication and Measurements, , p. 21 (London: Springer, 2009).

    Google Scholar 

  28. M. Haghzadeh, University of Massachusetts Lowell (2016).

  29. Y.C. Teh, N.R. Ong, Z. Sauli, J.B. Alcain, and V. Retnasamy, AIP Conf. Proc. 1885, 020290 (2017).

    Google Scholar 

  30. F.W. Jamaluddin, M.F. Khalid, M.H. Mamat, and A.S. Zoolfakar, in 2017 IEEE 13th Malaysia International Conference on Communications (MICC), pp. 63 (2017).

  31. A. Kumar, S.G. Manavalan, V. Gurumurthy, S. Jeedigunta, and T. Weller, Mater. Sci. Eng. B 139, 177 (2007).

    CAS  Google Scholar 

  32. V. Craciun, and R.K. Singh, Appl. Phys. Lett. 76, 1932 (2000).

    CAS  Google Scholar 

  33. J.-H. Lee, and S.-W. Rhee, J. Mater. Res. 14, 3988 (1999).

    CAS  Google Scholar 

  34. L. Zhang, J. Wu, M.N. Hedhili, X. Yang, and P. Wang, Journal of Materials Chemistry A 3, 2844 (2015).

    CAS  Google Scholar 

  35. E. Tekin, P.J. Smith, and U.S. Schubert, Soft Matter 4, 703 (2008).

    CAS  Google Scholar 

  36. F. Hoeng, J. Bras, E. Gicquel, G. Krosnicki, and A. Denneulin, RSC Adv. 7, 15372 (2017).

    CAS  Google Scholar 

  37. A. Teichler, J. Perelaer, and U.S. Schubert, J. Mater. Chem. C 1, 1910 (2013).

    CAS  Google Scholar 

  38. C. Sturgess, C.J. Tuck, I.A. Ashcroft, and R.D. Wildman, J. Mater. Chem. C 5, 9733 (2017).

    CAS  Google Scholar 

  39. F.-X. Wang, J. Lin, W.-B. Gu, Y.-Q. Liu, H.-D. Wu, and G.-B. Pan, Chem. Commun. 49, 2433 (2013).

    CAS  Google Scholar 

  40. J. Zhao, Y. Gao, W. Gu, C. Wang, J. Lin, Z. Chen, and Z. Cui, J. Mater. Chem. 22, 20747 (2012).

    CAS  Google Scholar 

  41. Y. Aleeva, and B. Pignataro, J. Mater. Chem. C 2, 6436 (2014).

    CAS  Google Scholar 

  42. K. Ankireddy, S. Vunnam, J. Kellar, and W. Cross, J. Mater. Chem. C 1, 572 (2013).

    CAS  Google Scholar 

  43. J.M. Meruga, A. Baride, W. Cross, J.J. Kellar, and P.S. May, J. Mater. Chem. C 2, 2221 (2014).

    CAS  Google Scholar 

  44. S. Wünscher, R. Abbel, J. Perelaer, and U.S. Schubert, J. Mater. Chem. C 2, 10232 (2014).

    Google Scholar 

  45. E. Harper, M. Haghzadeh, E. Hajisaeid, C. Armiento, and A. Akyurtlu, in 2017 89th ARFTG Microwave Measurement Conference (ARFTG) (2017), pp. 1.

  46. F.S. Jerome, J.T. Tseng, and L.T. Fan, J. Chem. Eng. Data 13, 496 (1968).

    CAS  Google Scholar 

  47. J. Varghese, K.P. Surendran, and M.T. Sebastian, RSC Adv. 4, 47701 (2014).

    CAS  Google Scholar 

  48. J. Varghese, M. Teirikangas, J. Puustinen, H. Jantunen, and M.T. Sebastian, J. Mater. Chem. C 3, 9240 (2015).

    CAS  Google Scholar 

  49. N. Joseph, J. Varghese, and M.T. Sebastian, J. Mater. Chem. C 4, 999 (2016).

    CAS  Google Scholar 

  50. X. Wang, W.W. Carr, D.G. Bucknall, and J.F. Morris, Rev. Sci. Instrum. 81, 065106 (2010).

    Google Scholar 

  51. I. Bretos, R. Jiménez, J. Ricote, and M.L. Calzada, Chem. Soc. Rev. 47, 291 (2018).

    CAS  Google Scholar 

  52. Q.-H. Lu, and F. Zheng, Advanced Polyimide Materials. ed. S.-Y. Yang (Amsterdam: Elsevier, 2018), p. 195.

    Google Scholar 

Download references


The authors would like to thank Raytheon Technologies for funding this project. The authors also would like to thank students, staff and faculty members at Printed Electronics Research Collaborative (PERC) and Raytheon UMass Lowell Research Institute (RURI) of the University of Massachusetts Lowell, USA, for their support.

Author information

Authors and Affiliations


Corresponding authors

Correspondence to Oshadha K. Ranasingha or Alkim Akyurtlu.

Ethics declarations

Conflict of interest

The authors declare that they have no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (PDF 674 kb)

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Ranasingha, O.K., Haghzadeh, M., Sobkowicz, M.J. et al. Formulation and Characterization of Sinterless Barium Strontium Titanate (BST) Dielectric Nanoparticle Ink for Printed RF and Microwave Applications. J. Electron. Mater. 50, 3241–3248 (2021).

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI:


  • Printed electronics
  • printable BST ink
  • tunable dielectrics
  • aerosol jet printing
  • additive manufacturing