Skip to main content
Log in

Fe-ZIF@C with Porous Nanostructure as Anode Material for Lithium-Ion Batteries

  • Original Research Article
  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

Abstract

Fe-zeolitic imidazolate framework (ZIF)@C (Fe-ZIF wrapped by carbon) anode material has been manufactured. It has porous nanostructure, which can effectively shorten the distance of lithium ion transmission, thus achieving excellent rate performance, and can also reduce the volume expansion in the charging and discharging process, thus reducing the attenuation of capacity. The external carbon coating avoids direct contact between Fe-ZIF and the electrolyte, inhibits decomposition of the electrolyte, and impedes formation of the solid electrolyte interphase (SEI) film, thus obtaining higher reversible capacity in the cycling process. At a current density of 100 mA/g, Fe-ZIF@C achieves a high discharge capacity of 719 mAh/g after 100 cycles. This research shows that Fe-ZIF@C has potential for use as an anode material for lithium-ion batteries.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig.1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig.6
Fig. 7

Similar content being viewed by others

References

  1. N. Emery, M.T. Sougrati, E. Panabière, S. Bach, B. Fraisse, J.C. Jumas, J.P. Pereira Ramos, and P. Willmann, J. Alloys Compd., 2017, 696, p 971.

    Article  CAS  Google Scholar 

  2. C. Ding, Y.W. Zeng, L.L. Cao, L.F. Zhao, and Y. Zhang, J. Mater. Chem. A, 2016, 4, p 5898.

    Article  CAS  Google Scholar 

  3. W.W. Hong, Y. Zhang, L. Yang, Y. Tian, P. Ge, J.G. Hu, F.W. Wei, G.Q. Zou, H.S. Hou, and X.B. Ji, Nano Energy, 2019, 65, p 104038.

    Article  CAS  Google Scholar 

  4. L. Yu, H.B. Wu, and X.W. Lou, Acc. Chem. Res., 2017, 50, p 293.

    Article  CAS  Google Scholar 

  5. M. Zhang, E. Liu, T. Cao, H. Wang, C. Shi, J. Li, C. He, F. He, L. Ma, and N. Zhao, Mater. Chem. A, 2017, 5, p 7035.

    Article  CAS  Google Scholar 

  6. Y. Lu, L. Yu, and X.W. Lou, Chem, 2018, 4(5), p 972.

    Article  CAS  Google Scholar 

  7. B.B. Jiang, C.P. Han, B. Li, Y.J. He, and Z.Q. Lin, ACS Nano, 2016, 10, p 2728.

    Article  CAS  Google Scholar 

  8. M. Sun, M. Sun, H. Yang, W. Song, Y. Nie, and S. Sun, Ceram. Int., 2017, 43(1), p 363.

    Article  CAS  Google Scholar 

  9. W.J. Yu, L.L. Zhang, P.X. Hou, F. Li, C. Liu, and H.M. Cheng, Energy Mater., 2016, 6(3), p 1501755.

    Article  Google Scholar 

  10. X. Tong, M. Zeng, J. Li, and F. Li, Appl. Surf. Sci., 2017, 392, p 897.

    Article  CAS  Google Scholar 

  11. H. Xu, X. Wang, H. Liu, J. Wang, X. Dong, G. Liu, W. Yu, Y. Yang, and H. Zhang, Mater. Sci., 2018, 53(22), p 15631.

    Article  CAS  Google Scholar 

  12. Z. Zheng, Y. Zao, Q. Zhang, Y. Cheng, H. Chen, K. Zhang, M.S. Wang, and D.L. Peng, Chem. Eng., 2018, 347, p 563.

    Article  CAS  Google Scholar 

  13. L. Wang, J.W. Wan, Y.S. Zhao, N.L. Yang, and D. Wang, Am. Chem. Soc., 2019, 141(6), p 2238.

    Article  CAS  Google Scholar 

  14. J.M. Jeong, B.G. Choi, S.C. Lee, K.G. Lee, S.J. Chang, Y.K. Han, Y.B. Lee, H.U. Lee, S. Kwon, G. Lee, C.S. Lee, and Y.S. Huh, Adv. Mater., 2013, 25, p 6250.

    Article  CAS  Google Scholar 

  15. Z.X. Tu, H.S. Qiao, Y.T. Yan, G. Guday, W. Chen, M. Adeli, and R. Haag, Angew. Chem., 2018, 130, p 11368.

    Article  Google Scholar 

  16. D. Zhang, W. Choi, Y. Oshima, U. Wiedwald, S.H. Cho, H.P. Lin, Y. Li, Y. Ito, and K. Sugioka, Nanomaterials, 2018, 8, p 631.

    Article  Google Scholar 

  17. X.H. Wang, J.Y. Wang, Z.H. Chen, K. Yang, Z.X. Zhang, Z.X. Shi, T. Mei, J.W. Qian, J.H. Li, and X.B. Wang, J. Alloys Compd., 2020, 822, p 153656.

    Article  CAS  Google Scholar 

  18. J.S. Cho, Y.J. Hong, and Y.C. Kang, ACS Nano, 2015, 9(4), p 4026.

    Article  CAS  Google Scholar 

  19. T.C. Jiang, F.X. Bu, X.X. Feng, I. Shakir, G.L. Hao, and Y.X. Xu, ACS Nano, 2017, 11(5), p 5140.

    Article  CAS  Google Scholar 

  20. F.X. Bu, M. Hu, W. Zhang, Q. Meng, L. Xu, D.M. Jiang, and J.S. Jiang, Chem. Commun., 2015, 51, p 17568.

    Article  CAS  Google Scholar 

  21. J. Zhang, Y. Sun, Y. Yao, T. Huang, and A. Yu, J. Power Sources, 2013, 222, p 59.

    Article  CAS  Google Scholar 

  22. J. Kim, M.K. Chung, B.H. Ka, J.H. Ku, S. Park, J. Ryu, and S.M. Oh, J. Electrochem Soc., 2010, 157, p A412.

    Article  CAS  Google Scholar 

  23. X. Meng, Y. Xu, X. Sun, L. Xiong, and Q. Wang, J. Power Sources, 2016, 326, p 389.

    Article  CAS  Google Scholar 

  24. G. Zhang, Y. Shi, H. Wang, L. Jiang, X. Yu, S. Jing, S. Xing, and P. Tsiakaras, J. Power Sources, 2019, 416, p 118.

    Article  CAS  Google Scholar 

  25. L. Yin, Y.J. Gao, I. Jeon, H. Yang, J.P. Kim, S.Y. Jeong, and C.R. Cho, Chem. Eng., 2019, 356, p 60.

    Article  CAS  Google Scholar 

  26. M. Tadic, D. Trpkov, L. Kopanja, S. Vojnovic, and M. Panjan, J. Alloys Compd., 2019, 792, p 599.

    Article  CAS  Google Scholar 

  27. E. Song, Y.T. Kim, and J. Choi, Electrochem. Commun., 2019, 109, p 106610.

    Article  CAS  Google Scholar 

  28. T. Chen, W. Jia, Z. Yao, Y. Liu, X. Guan, K. Li, J. Xiao, H. Liu, Y. Chen, Y. Zhou, D. Sun, and J. Li, Electrochem. Commun., 2019, 107, p 106535.

    Article  CAS  Google Scholar 

  29. W.X. Guo, W.W. Sun, L.P. Lv, S.F. Kong, and Y. Wang, ACS Nano, 2017, 11(4), p 4198.

    Article  CAS  Google Scholar 

  30. J.T. Hu, W. Li, C.K. Liu, H.T. Tang, T.C. Liu, H. Guo, X.H. Song, J.X. Zheng, Y.D. Liu, Y.D. Duan, and F. Pan, RSC Adv., 2016, 6, p 51777.

    Article  CAS  Google Scholar 

  31. M.S. Balogun, Z.P. Wu, Y. Luo, W.T. Qiu, X.L. Fan, B. Long, M. Huang, P. Liu, and Y.X. Tong, J. Power Sources, 2016, 308, p 7.

    Article  CAS  Google Scholar 

  32. L.H. Yin, Y.J. Gao, I.J. Jeon, H. Yang, J.P. Kim, S.Y. Jeong, and C.R. Cho, Chem. Eng. J., 2019, 356, p 60.

    Article  CAS  Google Scholar 

  33. Z.M. Zheng, Y. Zao, Q.B. Zhang, Y. Cheng, H.X. Chen, K.L. Zhang, M.S. Wang, and D.L. Peng, Chem. Eng. J., 2018, 347, p 563.

    Article  CAS  Google Scholar 

  34. Y. Yu, Y.C. He, N. Xu, X.L. Geng, L.Y. Wang, H.T. Sun, L.H. Zhu, and Z.H. Jing, Solid State Chem., 2019, 271, p 121.

    Article  CAS  Google Scholar 

  35. W.L. Zhang, X.H. Hou, J.D. Shen, S.J. Hua, Q. Ru, and K.H. Lam, Electrochim. Acta, 2016, 188, p 734.

    Article  CAS  Google Scholar 

  36. Z.M. Liu, X.Y. Yu, and U. Paik, Adv. Energy Mater., 2016, 6, p 1502318.

    Article  Google Scholar 

  37. W.J. Han, X.Y. Qin, J.X. Wu, M. Liu, Y. Xia, H.D. Du, B.H. Li, and F.Y. Kang, Nano Res., 2018, 11, p 892.

    Article  CAS  Google Scholar 

  38. T. Jiang, F. Bu, X. Feng, I. Shakir, G. Hao, and Y. Xu, ACS Nano, 2017, 11, p 5140.

    Article  CAS  Google Scholar 

  39. M. Sun, M. Sun, H. Yang, W. Song, Y. Nie, and S. Sun, Ceram. Int., 2017, 43, p 363.

    Article  CAS  Google Scholar 

  40. X. Chen, Z. Zhao, Y. Zhou, Y. Shu, M. Sajjad, Q. Bi, Y. Ren, X. Wang, X. Zhou, and Z. Liu, J. Alloys Compd., 2019, 776, p 974.

    Article  CAS  Google Scholar 

Download references

Funding

This work was supported by the Scientific Research Program of Hebei Province (No. 16273706D), the Basic Innovation Team of Tangshan (2017).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Shaowei Yao.

Ethics declarations

Conflict of Interest

The authors declare that they have no conflicts of interest.

Additional information

Publisher’s Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nie, J., Li, Z., Shi, G. et al. Fe-ZIF@C with Porous Nanostructure as Anode Material for Lithium-Ion Batteries. J. Electron. Mater. 50, 2831–2839 (2021). https://doi.org/10.1007/s11664-021-08773-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11664-021-08773-3

Keywords

Navigation