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Remarkably Elevated Permittivity Achieved in PVDF/1D La2TiO5 Composite Film Materials with Low-Level Dielectric Loss by Adding 2D V2C MXene Phase

Journal of Electronic Materials volume 50, pages 2182–2189 (2021)Cite this article

Abstract

High-dielectric-constant (high-k) polymer–ceramic composites with low-level dielectric loss are expected to enable excellent energy storage. However, high conductivity and high dielectric loss often occur simultaneously with high dielectric constant. To obtain a high dielectric constant but with low conductivity and low dielectric loss, in this work, we studied the ternary polyvinylidene fluoride (PVDF)/La2TiO5/V2C dielectric composite system, which takes advantage of the synergistic effect between the high content (0 wt.% to 40 wt.%) of pseudo-perovskite filler La2TiO5 and the low content (2 wt.%) of highly conductive two-dimensional filler V2C. Comparisons with the binary PVDF/La2TiO5 composite system revealed that the ternary PVDF/La2TiO5/V2C composite dielectric system enabled balance and optimization of the comprehensive electrical properties of the composite material. Significantly elevated permittivity as well as depressed low-level dielectric loss were obtained in the ternary composites. The optimized ternary composite with 40 wt.% La2TiO5 and 2 wt.% V2C exhibited high dielectric constant of 47 and low dielectric loss of 0.17 at 1 kHz. This work might enable facile fabrication of promising composite dielectric materials based on this excellent synergetic filler strategy.

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Acknowledgements

This work was supported by the General Project of Natural Science Foundation of Chongqing Science and Technology Bureau (Grant No. cstc2020jcyj-msxm0673), Science and Technology Research Program of Chongqing Municipal Education Commission (Grant Nos. KJQN201901417 and KJQN201801409), and Support Programme for Growth of Young Scientific Research Talents of Yangtze Normal University (Grant No. 0107/010721064).

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Authors and Affiliations

  1. Key Laboratory of Extraordinary Bond Engineering and Advance Materials Technology (EBEAM) of Chongqing, School of Materials Science and Engineering, Yangtze Normal University, No. 16, Juxian Avenue, Fuling District, Chongqing, 408100, People’s Republic of China

    Yefeng Feng, Peiyao Chen, Maolin Bo, Qihuang Deng, Anning Zhao & Junjie Fu

  2. Hunan Key Laboratory for Micro-Nano Energy Materials and Devices, School of Physics and Optoelectronics, Xiangtan University, Yuhu District, Xiangtan, 411105, People’s Republic of China

    Xiaomiao Zhao

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  1. Yefeng Feng
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  2. Xiaomiao Zhao
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Correspondence to Yefeng Feng or Qihuang Deng.

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Feng, Y., Zhao, X., Chen, P. et al. Remarkably Elevated Permittivity Achieved in PVDF/1D La2TiO5 Composite Film Materials with Low-Level Dielectric Loss by Adding 2D V2C MXene Phase. J. Electron. Mater. 50, 2182–2189 (2021). https://doi.org/10.1007/s11664-020-08684-9

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  • DOI: https://doi.org/10.1007/s11664-020-08684-9

Keywords

  • Dielectric
  • composite
  • La2TiO5
  • V2C
  • synergy