Skip to main content
Log in

Whisker Growth in Sn Coatings: A Review of Current Status and Future Prospects

  • TMS2020 Microelectronic Packaging, Interconnect, and Pb-free Solder
  • Published:
Journal of Electronic Materials Aims and scope Submit manuscript

Abstract

Whiskering is a spontaneous filamentary growth of material, and it is a major long-term reliability issue affecting microelectronic packages comprising Sn plating and Sn-rich solders. In particular, whisker growth out of Sn-plated surfaces has been studied extensively in recent years due to the advent of next-generation, environment-friendly, Pb-free microelectronic packaging. Here, we review this scientifically challenging and technologically important problem, especially in the light of relatively new insights gained in the recent past, intending to provide a quick overview of the important results and stimulating future studies. In particular, we discuss the mechanisms of whisker growth by critically examining the roles of stress and its regeneration, oxide layer, diffusion conduits, and crystal anisotropy in creating conditions conducive for whiskering. We also discuss the recent proposals for effectively mitigating whisker growth in Sn coatings. Finally, an outlook is provided, with details of important unresolved issues related to whisker growth.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. G.T. Galyon, IEEE Trans. Electron. Packag. Manuf. 28, 94 (2005).

    Article  CAS  Google Scholar 

  2. P. Zhang, Y. Zhang, and Z. Sun, J. Mater. Sci. Technol. 31, 675 (2015).

    Article  CAS  Google Scholar 

  3. L. Ercker, in Treaties on Ores and Assaying, 1580th ed. translated by A.G. Sisco, C.S. Smith. (University of Chicago, 1951), p. 177.

  4. H.L. Cobb, Mon. Rev. Am. Electroplat. Soc. 33, 28 (1946).

    CAS  Google Scholar 

  5. E. Chason, N. Jadhav, F. Pei, E. Buchovecky, and A. Bower, Prog. Surf. Sci. 88, 103 (2013).

    Article  CAS  Google Scholar 

  6. NASA tin whisker webpage https://nepp.nasa.gov/whisker

  7. S. M. Arnold, in Proc. IEEE Elec. Comp. Conf (1959), pp. 75–82.

  8. Y. Li, M. Sun, S. Ren, H. Ling, T. Hang, A. Ming Hu, and M. Li, Mater. Lett. 258, 126773 (2020).

    Article  CAS  Google Scholar 

  9. P. Snugovsky, Z. Bagheri, and M. Romansky, in SMTA Int. Conf. Solder. Reliab. (2008)

  10. B. Illés and B. Horváth, J. Alloys Compd. 616, 116 (2014).

    Article  CAS  Google Scholar 

  11. S.E. Koonce and S.M. Arnold, J. Appl. Phys. 25, 176 (1954).

    Article  Google Scholar 

  12. S.E. Koonce and S.M. Arnold, J. Appl. Phys. 24, 1401 (1953).

    Article  Google Scholar 

  13. K.N. Tu, Mater. Chem. Phys. 46, 217 (1996).

    Article  CAS  Google Scholar 

  14. K.N. Tu, Phys. Rev. B 49, 2030 (1994).

    Article  CAS  Google Scholar 

  15. W.J. Choi, T.Y. Lee, K.N. Tu, N. Tamura, R.S. Celestre, A.A. MacDowell, Y.Y. Bong, and L. Nguyen, Acta Mater. 51, 6253 (2003).

    Article  CAS  Google Scholar 

  16. P. Sarobol, J.E. Blendell, and C.A. Handwerker, Acta Mater. 61, 1991 (2013).

    Article  CAS  Google Scholar 

  17. N. Jadhav, E.J. Buchovecky, L. Reinbold, S. Kumar, A.F. Bower, and E. Chason, IEEE Trans. Electron. Packag. Manuf. 33, 183 (2010).

    Article  CAS  Google Scholar 

  18. P. Jagtap, A. Chakraborty, P. Eisenlohr, and P. Kumar, Acta Mater. 134, 346 (2017).

    Article  CAS  Google Scholar 

  19. W.J. Boettinger, C.E. Johnson, L.A. Bendersky, K.W. Moon, M.E. Williams, and G.R. Stafford, Acta Mater. 53, 5033 (2005).

    Article  CAS  Google Scholar 

  20. B.Z. Lee and D.N. Lee, Acta Mater. 46, 3701 (1998).

    Article  CAS  Google Scholar 

  21. R.M. Fisher, L.S. Darken, and K.G. Carroll, Acta Metall. 2, 368 (1954).

    Article  CAS  Google Scholar 

  22. K. Chen and G.D. Wilcox, Phys. Rev. Lett. 94, 066104 (2005).

    Google Scholar 

  23. K.N. Tu and J.C.M. Li, Mater. Sci. Eng., A 409, 131 (2005).

    Article  CAS  Google Scholar 

  24. K.W. Moon, C.E. Johnson, M.E. Williams, O. Kongstein, G.R. Stafford, C.A. Handwerker, and W.J. Boettinger, J. Electron. Mater. 34, 31 (2005).

    Article  Google Scholar 

  25. V.G. Karpov, Phys. Rev. Appl. 1, 044001 (2014).

    Article  CAS  Google Scholar 

  26. Y. Liu, C. Lu, P. Zhang, J. Yu, Y. Zhang, and Z.M. Sun, Acta Mater. 185, 433 (2020).

    Article  CAS  Google Scholar 

  27. J.W. Osenbach, J.M. DeLucca, B.D. Potteiger, A. Amin, R.L. Shook, and F.A. Baiocchi, IEEE Trans. Electron. Packag. Manuf. 30, 23 (2007).

    Article  CAS  Google Scholar 

  28. M.E. Williams, K.W. Moon, W.J. Boettinger, D. Josell, and A.D. Deal, J. Electron. Mater. 36, 214 (2007).

    Article  CAS  Google Scholar 

  29. E. R. Crandall, G. T. Flowers, R. Jackson, P. Lall, and M. J. Bozack, in Electr. Contacts, Proc. Annu. Holm Conf. Electr. Contacts (2011), pp. 304–308.

  30. F. Pei and E. Chason, J. Electron. Mater. 43, 80 (2014).

    Article  CAS  Google Scholar 

  31. F. Pei, E. Buchovecky, A. Bower, and E. Chason, Acta Mater. 129, 462 (2017).

    Article  CAS  Google Scholar 

  32. P. Jagtap and P. Kumar, J. Electron. Mater. 44, 1206 (2015).

    Article  CAS  Google Scholar 

  33. E. Chason, N. Jadhav, W.L. Chan, L. Reinbold, and K.S. Kumar, Appl. Phys. Lett. 92, 171901 (2008).

    Article  CAS  Google Scholar 

  34. K.N. Tu, Acta Metall. 21, 347 (1973).

    Article  CAS  Google Scholar 

  35. K.N. Tu, J.O. Suh, A.T.C. Wu, N. Tamura, and C.H. Tung, Mater. Trans. 46, 2300 (2005).

    Article  CAS  Google Scholar 

  36. C.H. Pitt and R.G. Henning, J. Appl. Phys. 35, 459 (1964).

    Article  Google Scholar 

  37. K.N. Tu and R.D. Thompson, Acta Metall. 30, 947 (1982).

    Article  CAS  Google Scholar 

  38. E. Chason, N. Jadhav, and F. Pei, JOM 63, 62 (2011).

    Article  CAS  Google Scholar 

  39. J. Christian, in The Theory of Transformations in Metals and Alloys. I. Equilibrium and General Kinetic Theory (1975).

  40. P. Jagtap, Whisker Growth from Electrodeposited Sn Coatings (Bangalore: Indian Institute of Science, 2017).

    Google Scholar 

  41. A. Baated, K.S. Kim, and K. Suganuma, J. Mater. Sci.: Mater. Electron. 22, 1685 (2011).

    CAS  Google Scholar 

  42. E.J. Buchovecky, N. Du, and A.F. Bower, Appl. Phys. Lett. 94, 1 (2009).

    Article  CAS  Google Scholar 

  43. Eric Buchovecky, Numerical Simulation of Stress Generation and Whisker Growth in Sn Films, Brown University, 2010.

  44. E. Chason and P.R. Guduru, J. Appl. Phys. 119, 191101 (2016).

    Article  CAS  Google Scholar 

  45. D.A. Pinsky, Microelectron. Reliab. 48, 675 (2008).

    Article  CAS  Google Scholar 

  46. V.K. Glazunova, Zhurnal Prikl. Khimii, Transl. from Russ. 36, 543 (1963).

  47. S. C. Britton and M. Clarke, in Proc. 6th Int. Met. Finish. Conf. (1964), pp. 205–211.

  48. M. Liu and A.-P. Xian, J. Electr. Mater. 38, 2353 (2009).

    Article  CAS  Google Scholar 

  49. T.H. Chuang, Scr. Mater. 55, 983 (2006).

    Article  CAS  Google Scholar 

  50. C.M.L. Wu and Y.W. Wong, J. Mater. Sci.: Mater. Electron. 18, 77 (2007).

    CAS  Google Scholar 

  51. T.H. Chuang, H.J. Lin, and C.C. Chi, Scr. Mater. 56, 45 (2007).

    Article  CAS  Google Scholar 

  52. F. Pei, N. Jadhav, E. Buchovecky, A.F. Bower, E. Chason, W. Liu, J.Z. Tischler, G.E. Ice, and R. Xu, J. Appl. Phys. 119, 105302 (2016).

    Article  CAS  Google Scholar 

  53. M. Dittes, P. Oberndorff, P. Crema, and V. Schroeder, in Proc. IPC-JEDEC Conf.,Frankfurt, Ger. 105 (2003).

  54. K. Suganuma, A. Baated, K.-S. Kim, K. Hamasaki, N. Nemoto, T. Nakagawa, and T. Yamada, Acta Mater. 59, 7255 (2011).

    Article  CAS  Google Scholar 

  55. F. Pei, C.L. Briant, H. Kesari, A.F. Bower, and E. Chason, Scr. Mater. 93, 16 (2014).

    Article  CAS  Google Scholar 

  56. F. Pei, A.F. Bower, and E. Chason, J. Electron. Mater. 45, 21 (2016).

    Article  CAS  Google Scholar 

  57. M. Ronay and C.F. Aliotta, Philos. Mag. A Phys. Condens. Matter. Struct. Defects Mech. Prop. 42, 161 (2020).

    CAS  Google Scholar 

  58. P. Jagtap, N. Jain, and E. Chason, Scr. Mater. 182, 43 (2020).

  59. C.K. Lin and T.H. Lin, Microelectron. Reliab. 48, 1737 (2008).

    Article  CAS  Google Scholar 

  60. C.M. Chen and Y.J. Chen, Mater. Lett. 63, 1517 (2009).

    Article  CAS  Google Scholar 

  61. P. Jagtap, V.A. Sethuraman, and P. Kumar, J. Electron. Mater. 47, 5229 (2018).

    Article  CAS  Google Scholar 

  62. T. Shibutani, Q. Yu, T. Yamashita, and M. Shiratori, IEEE Trans. Electron. Packag. Manuf. 29, 259 (2006).

    Article  CAS  Google Scholar 

  63. H. Moriuchi, Y. Tadokoro, M. Sato, T. Furusawa, and N. Suzuki, J. Electron. Mater. 36, 220 (2007).

    Article  CAS  Google Scholar 

  64. F. Yang and Y. Li, J. Appl. Phys. 104, 113512 (2008).

    Article  CAS  Google Scholar 

  65. S.K. Lin, Y. Yorikado, J. Jiang, K.S. Kim, K. Suganuma, S.W. Chen, M. Tsujimoto, and I. Yanada, J. Mater. Res. 22, 1975 (2007).

    Article  CAS  Google Scholar 

  66. J.J. Williams, N.C. Chapman, and N. Chawla, J. Electron. Mater. 42, 224 (2013).

    Article  CAS  Google Scholar 

  67. I. Lujan-Regalado, A. Kirubanandham, J.J. Williams, and N. Chawla, J. Electron. Mater. 48, 58 (2019).

    Article  CAS  Google Scholar 

  68. J. Liang, Z.H. Xu, and X. Li, J. Mater. Sci.: Mater. Electron. 18, 599 (2007).

    CAS  Google Scholar 

  69. S.D. Mahapatra and I. Dutta, Mater. Sci. Eng., A 706, 181 (2017).

    Article  CAS  Google Scholar 

  70. J.W. Osenbach, J. Appl. Phys. 106, 094903 (2009).

    Article  CAS  Google Scholar 

  71. P. L. Key, in Proc. IEEE Electron. Components Technol. Conf. 155 (1970).

  72. J. Cheng, P.T. Vianco, J. Subjeck, and J.C.M. Li, J. Mater. Sci. 46, 263 (2011).

    Article  CAS  Google Scholar 

  73. Y. Wang, J.E. Blendell, and C.A. Handwerker, J. Mater. Sci. 49, 1099 (2014).

    Article  CAS  Google Scholar 

  74. H.P. Kehrer and H.G. Kadereit, Appl. Phys. Lett. 16, 411 (1970).

    Article  CAS  Google Scholar 

  75. P. Singh and M. Ohring, J. Appl. Phys. 56, 899 (1984).

    Article  CAS  Google Scholar 

  76. T. Kakeshita, K. Shimizu, R. Kawanaka, and T. Hasegawa, J. Mater. Sci. 17, 2560 (1982).

    Article  CAS  Google Scholar 

  77. S. Das Mahapatra, B. S. Majumdar, and I. Dutta, in Proc. 16th Intersoc. Conf. Therm. Thermomechanical Phenom. Electron. Syst. ITherm 2017 (Institute of Electrical and Electronics Engineers Inc., 2017), pp. 1425–1432.

  78. S.D. Mahapatra, B.S. Majumdar, I. Dutta, and S. Bhassyvasantha, J. Electron. Mater. 46, 4062 (2017).

    Article  CAS  Google Scholar 

  79. H.P. Howard, J. Cheng, P.T. Vianco, and J.C.M. Li, Acta Mater. 59, 1957 (2011).

    Article  CAS  Google Scholar 

  80. M. Sobiech, M. Wohlschlögel, U. Welzel, E.J. Mittemeijer, W. Hügel, A. Seekamp, W. Liu, and G.E. Ice, Appl. Phys. Lett. 94, 221901 (2009).

    Article  CAS  Google Scholar 

  81. J. Hektor, J.-B. Marijon, M. Ristinmaa, S.A. Hall, H. Hallberg, S. Iyengar, J.-S. Micha, O. Robach, F. Grennerat, and O. Castelnau, Scr. Mater. 144, 1 (2018).

    Article  CAS  Google Scholar 

  82. J. Hektor, J.S. Micha, S.A. Hall, S. Iyengar, and M. Ristinmaa, Acta Mater. 168, 210 (2019).

    Article  CAS  Google Scholar 

  83. A. Chakraborty and P. Eisenlohr, J. Appl. Phys. 124, 025302 (2018).

    Article  CAS  Google Scholar 

  84. A. Chakraborty, Using Chemo-Thermo-Mechanically Coupled Crystal Plasticity Simulations to Investigate the Process of Whisker Formation in β − Sn Thin Films (East Lansing.: Michigan State University, 2018).

    Google Scholar 

  85. W.H. Chen, P. Sarobol, J.R. Holaday, C.A. Handwerker, and J.E. Blendell, J. Mater. Res. 29, 197 (2014).

    Article  CAS  Google Scholar 

  86. B.F. Dyson, T.R. Anthony, and D. Turnbull, J. Appl. Phys. 38, 3408 (1967).

    Article  CAS  Google Scholar 

  87. D.C. Yeh and H.B. Huntington, Phys. Rev. Lett. 53, 1469 (1984).

    Article  CAS  Google Scholar 

  88. J. Stein, C.A.C. Tineo, U. Welzel, W. Huegel, and E.J. Mittemeijer, J. Electron. Mater. 44, 886 (2015).

    Article  CAS  Google Scholar 

  89. J. Franks, Nature 177, 984 (1956).

    Article  CAS  Google Scholar 

  90. J. Franks, Acta Metall. 6, 103 (1958).

    Article  CAS  Google Scholar 

  91. J.D. Eshelby, Phys. Rev. 91, 755 (1953).

    Article  Google Scholar 

  92. S. Amelinckx, W. Bontinck, W. Dekeyser, and F. Seitz, Philos. Mag. 2, 355 (1957).

    Article  CAS  Google Scholar 

  93. U. Lindborg, Acta Metall. 24, 181 (1976).

    Article  CAS  Google Scholar 

  94. W.C. Ellis, D.F. Gibbons, and R.C. Treuting, in Growth and Perfection of Crystals, ed. by R.H. Doremus, B.W. Roberts, and D. Turnbull (John Wiley, New York, 1958), pp. 102–120.

  95. J.B. LeBret and M.G. Norton, J. Mater. Res. 18, 585 (2003).

    Article  CAS  Google Scholar 

  96. G.T.T. Sheng, C.F. Hu, W.J. Choi, K.N. Tu, Y.Y. Bong, and L. Nguyen, J. Appl. Phys. 92, 64 (2002).

    Article  CAS  Google Scholar 

  97. R. Morris and W. Bonfield, Scripta Metall. 8, 231 (1974).

  98. K.S. Kumar, L. Reinbold, A.F. Bower, and E. Chason, J. Mater. Res. 23, 2916 (2008).

    Article  CAS  Google Scholar 

  99. P.T. Vianco and J.A. Rejent, J. Electron. Mater. 38, 1815 (2009).

    Article  CAS  Google Scholar 

  100. F. Pei, N. Jadhav, and E. Chason, Appl. Phys. Lett. 100, 221902 (2012).

    Article  CAS  Google Scholar 

  101. F. Humphreys and M. Hatherly, Recrystallization and Related Annealing Phenomena (Amsterdam: Elsevier, 2012).

    Google Scholar 

  102. M.A. Bhatia, I. Adlakha, G. Lu, and K.N. Solanki, Scr. Mater. 123, 21 (2016).

    Article  CAS  Google Scholar 

  103. J. Weertman and J.E. Breen, J. Appl. Phys. 27, 1189 (1956).

    Article  CAS  Google Scholar 

  104. E. Chason, F. Pei, C.L. Briant, H. Kesari, and A.F. Bower, J. Electron. Mater. 43, 4435 (2014).

    Article  CAS  Google Scholar 

  105. J. Cheng, P.T. Vianco, and J.C.M. Li, Appl. Phys. Lett. 96, 184102 (2010).

    Article  CAS  Google Scholar 

  106. J. Smetana, IEEE Trans. Electron. Packag. Manuf. 30, 11 (2007).

    Article  CAS  Google Scholar 

  107. A.C. Vasko, G.R. Warrell, E.I. Parsai, V.G. Karpov, and D. Shvydka, J. Appl. Phys. 118, 125301 (2015).

    Article  CAS  Google Scholar 

  108. V. Borra, O. Oudat, D.G. Georgiev, V.G. Karpov, and D. Shvydka, MRS Adv. 3, 3367 (2018).

  109. D. Shvydka and V.G. Karpov, J. Appl. Phys. 119, 085301 (2016).

    Article  CAS  Google Scholar 

  110. P. Jagtap, P.R. Narayan, and P. Kumar, J. Electron. Mater. 47, 4177 (2018).

    Article  CAS  Google Scholar 

  111. C. Xu, Y. Zhang, C. Fan, and J.A. Abys, IEEE Trans. Electron. Packag. Manuf. 28, 31 (2005).

    Article  CAS  Google Scholar 

  112. G.T. Galyon and L. Palmer, IEEE Trans. Electron. Packag. Manuf. 28, 17 (2005).

    Article  CAS  Google Scholar 

  113. W.J. Boettinger, M.D. Vaudin, M.E. Williams, L.A. Bendersky, and W.R. Wagner, J. Electron. Mater. 32, 511 (2003).

    Article  CAS  Google Scholar 

  114. S.A. Belyakov and C.M. Gourlay, Intermetallics 25, 48 (2012).

    Article  CAS  Google Scholar 

  115. S.A. Belyakov and C.M. Gourlay, Acta Mater. 71, 56 (2014).

    Article  CAS  Google Scholar 

  116. N. V. and M. Tsuriya, in Proc. ECO Des. Japan Symp., 120 (2002).

  117. C.H. Su, H. Chen, H.Y. Lee, and A.T. Wu, Appl. Phys. Lett. 99, 131906 (2011).

    Article  CAS  Google Scholar 

  118. A.T. Wu and Y.C. Ding, Microelectron. Reliab. 49, 318 (2009).

    Article  CAS  Google Scholar 

  119. M.A. Ashworth, D. Haspel, L. Wu, G.D. Wilcox, and R.J. Mortimer, J. Elec. Mater. 44, 442 (2015).

  120. S. Han, M. Osterman, S. Meschter, and M. Pecht, J. Electron. Mater. 41, 2508 (2012).

    Article  CAS  Google Scholar 

  121. S. Zhan, M.H. Azarian, and M.G. Pecht, IEEE Trans. Electron. Packag. Manuf. 29, 217 (2006).

    Article  Google Scholar 

  122. N. Jadhav, M. Williams, F. Pei, G. Stafford, and E. Chason, J. Electron. Mater. 42, 312 (2013).

    Article  CAS  Google Scholar 

  123. J.L. Jo, S. Nagao, K. Hamasaki, M. Tsujimoto, T. Sugahara, and K. Suganuma, J. Electron. Mater. 43, 1 (2014).

    Article  CAS  Google Scholar 

  124. S. Banerjee, I. Dutta, and B.S. Majumdar, Mater. Sci. Eng., A 666, 191 (2016).

    Article  CAS  Google Scholar 

  125. B. Horváth, B. Illés, T. Shinohara, and G. Harsányi, Thin Solid Films 520, 5733 (2012).

    Article  CAS  Google Scholar 

  126. A. Chakraborty and P. Eisenlohr, J. Electron. Mater. 48, 85 (2019).

    Article  CAS  Google Scholar 

  127. E. Buchovecky, N. Jadhav, A.F. Bower, and E. Chason, J. Electron. Mater. 38, 2676 (2009).

    Article  CAS  Google Scholar 

  128. P. Jagtap and P. Kumar, in Proc. 2016 IEEE 18th Electron. Packag. Technol. Conf. EPTC 2016, pp. 165–170 (2017).

  129. E. Chason and F. Pei, JOM 67, 2416 (2015).

    Article  CAS  Google Scholar 

  130. N. Jadhav, J. Wasserman, F. Pei, and E. Chason, J. Electron. Mater. 41, 588 (2012).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Piyush Jagtap.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jagtap, P., Kumar, P. Whisker Growth in Sn Coatings: A Review of Current Status and Future Prospects. J. Electron. Mater. 50, 735–766 (2021). https://doi.org/10.1007/s11664-020-08440-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11664-020-08440-z

Keywords

Navigation