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Effect of Ni Doping on ZnO Nanorods Synthesized Using a Low-Temperature Chemical Bath

  • Thembinkosi Donald MalevuEmail author
  • Benard Samwel Mwankemwa
  • Mustafa A. M. Ahmed
  • Tshwafo Elias Motaung
  • Kamohelo George Tshabalala
  • Richard Opio Ocaya
Article
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Abstract

The present study evaluates the effects of Ni doping of ZnO nanorods synthesized using the low-temperature chemical bath method. The article is motivated by the apparent variability in the literature which report contrasting results on the effect of Ni doping of the ZnO host matrix. The choice of method was decided by the accepted belief of its high reproducibility and accuracy. The concentration of Ni in the ZnO nanostructure host matrix is varied from 0%, 5%, 7.5% and 10% Ni. The products were characterized using several standard techniques. The various results are found to reinforce each other and show that the presence of Ni enters the host matrix as Ni2+ and alters the ZnO nanostructure dimensions and morphology significantly. This study provides direct spectroscopic evidence of the modification of the ZnO crystal structure by the incorporation of Ni. This article therefore provides much needed clarification of the mechanisms of local ZnO nanorod symmetry modification by Ni.

Keywords

ZnO nanorods photoluminescence Raman properties XPS  low-temperature chemical bath method 

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Notes

Acknowledgments

The authors wish to thank Dr. Mbuso Mlambo (Department of Physics, University of Pretoria) for the Raman spectroscopy, and the University of KwaZulu-Natal for the financial support through a UCDP grant.

Supplementary material

11664_2019_7490_MOESM1_ESM.doc (329 kb)
Supplementary material 1 (doc 329 KB)

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Copyright information

© The Minerals, Metals & Materials Society 2019

Authors and Affiliations

  1. 1.School of Chemistry and PhysicsUniversity of KwaZulu-NatalDurbanSouth Africa
  2. 2.Department of Physics, School of Physical Sciences, College of Natural and Mathematical SciencesUniversity of DodomaDodomaTanzania
  3. 3.Department of Physics, Faculty of EducationUniversity of KhartoumOmdurmanSudan
  4. 4.Department of ChemistryUniversity of ZululandKwaDlangezwaSouth Africa
  5. 5.Department of PhysicsUniversity of the Free StatePhuthaditjhabaSouth Africa

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