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Journal of Electronic Materials

, Volume 48, Issue 10, pp 6675–6685 | Cite as

Synergistic Effects of Optical and Photoluminescence Properties, Charge Transfer, and Photocatalytic Activity in MgAl2O4:Ce and Mn-Codoped MgAl2O4:Ce Phosphors

  • Shifa WangEmail author
  • Chaoli Chen
  • Yanwu Li
  • Qing Zhang
  • Yanlan Li
  • Huajing GaoEmail author
Article
  • 18 Downloads

Abstract

A gamma-ray irradiation-assisted polyacrylamide gel method has been used to synthesize MgAl2O4:Ce and Mn-codoped MgAl2O4:Ce phosphors. Ce ion doping improved the photoluminescence properties of MgAl2O4 but did not change the cubic spinel structure of the host. Transmission electron microscopy showed that the mean particle size of the Ce- and Mn-codoped MgAl2O4 nanoparticles was smaller than that of the MgAl2O4 nanoparticles. Ce and Mn codoping improved the light absorption capacity and utilization, the separation efficiency of photogenerated carriers, and the photocatalytic activity of the MgAl2O4 nanoparticles. The MgAl2O4:Ce:Mn nanoparticles exhibited high photocatalytic activity for photodegradation of methylene blue dye under simulated sunlight irradiation due to the synergistic effects of the band-edge position, the light absorption capacity and utilization, and the separation efficiency of photogenerated carriers.

Keywords

Mn-codoped MgAl2O4:Ce phosphor photoluminescence properties light absorption capacity photocatalytic activity band-edge position 

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Notes

Acknowledgments

This work was supported by the Talent Introduction Project (09924601), Major Cultivation Projects (18ZDPY01), and Research project of higher education teaching reform (JGZC1903) of Chongqing Three Gorges University, the Chongqing basic research and frontier exploration (general project) (cstc2019jcyj-msxm1327).

Conflict of interest

The authors declare that they have no competing interests.

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Copyright information

© The Minerals, Metals & Materials Society 2019

Authors and Affiliations

  1. 1.School of Electronic and Information EngineeringChongqing Three Gorges UniversityChongqing, WanzhouChina
  2. 2.Chongqing Key Laboratory of Geological Environment Monitoring and Disaster Early-Warning in Three Gorges Reservoir AreaChongqing Three Gorges UniversityChongqing, WanzhouChina
  3. 3.School of Environmental and Chemical EngineeringChongqing Three Gorges UniversityChongqing, WanzhouChina
  4. 4.State Key Laboratory of Advanced Processing and Recycling of Non-ferrous MetalsLanzhou University of TechnologyLanzhouChina
  5. 5.School of ScienceLanzhou University of TechnologyLanzhouChina

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