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Enhanced Anti-Corrosion Protection of Carbon Steel with Silica-Polypyrrole-Dodecyl Sulfate Incorporated into Epoxy Coating

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Abstract

Nanocomposites based on silica, polypyrrole, and sodium dodecyl sulfate dopant (SiO2-PPy-DoS) were synthesized by an in situ polymerization method. The characterizations of the synthesized materials were analyzed using Fourier-transform infrared spectroscopy, energy dispersive x-ray analysis, scanning electron microscopy, thermal gravimetric analysis, and x-ray photoelectron spectroscopy. The results showed that the SiO2-PPy-DoS composite had spherical shape with size of around 250–500 nm. The electrical conductivity of the SiO2-PPy-DoS nanocomposite was measured to be around 0.287 S/cm, which was larger than that of SiO2-PPy (0.101 S/cm). An enhanced anti-corrosion protection of carbon steel substrate (CT3) using an epoxy coating containing SiO2-PPy-DoS was achieved with an impedance modulus value of 108 Ω cm−2 at 10 mHz after 840 h soaked in NaCl solution of 3%, indicating that DoS can be used as an additive to improve anti-corrosion capacity for carbon steel.

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Acknowledgments

This research was funded by the Vietnam National Foundation for Science and Technology Development (NAFOSTED) under Grant Number “104.06-2014.12”.

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Authors and Affiliations

  1. Institute for Tropical Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam

    Thom Nguyen Thi, Thanh Dinh Thi Mai, Nam Pham Thi, Phuong Nguyen Thu & Van Vu Thi Hai

  2. University of Science and Technology of Hanoi, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam

    Thanh Dinh Thi Mai & Minh Ngo Quang

  3. Graduate University of Science and Technology, Vietnam Academy of Science and Technology, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam

    Thanh Dinh Thi Mai

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  1. Thom Nguyen Thi
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  2. Thanh Dinh Thi Mai
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Correspondence to Thanh Dinh Thi Mai.

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Nguyen Thi, T., Dinh Thi Mai, T., Pham Thi, N. et al. Enhanced Anti-Corrosion Protection of Carbon Steel with Silica-Polypyrrole-Dodecyl Sulfate Incorporated into Epoxy Coating. J. Electron. Mater. 48, 3931–3938 (2019). https://doi.org/10.1007/s11664-019-07146-1

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  • DOI: https://doi.org/10.1007/s11664-019-07146-1

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