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Synthesis and Characterization of Bi0.85−xCa0.15ZrxO1.5−δ Oxygen Ion Conductors

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Abstract

Bi0.85−xCa0.15ZrxO1.5−δ (0.12 ≤ x ≤ 0.24) oxygen ion conductors were synthesized by solid-state reaction method. Small quantities of CaZrO3 and Ca0.15Zr0.85O0.85 second phases were observed on the grain boundaries of the Bi0.85−xCa0.15ZrxO1.5−δ matrix with cubic fluorite structure. The lattice parameter a of Bi0.85−xCa0.15ZrxO1.5−δ lay within the range of 5.512 Å to 5.525 Å. The conductivity of all the Bi0.85−xCa0.15ZrxO1.5−δ samples increased with temperature. The Bi0.70Ca0.15Zr0.15O1.5−δ sample exhibited the highest conductivity of 0.05 S/cm at 750°C. The typical impedance spectra of the Bi0.85−xCa0.15ZrxO1.5−δ samples showed that the main resistance resulted from charge-transfer polarization at low temperatures, while the grain-boundary resistance dominated when the temperature was increased to above 600°C because of the CaZrO3 and Ca0.15Zr0.85O1.85 second phases appearing at grain boundaries.

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Authors and Affiliations

  1. Department of Chemical Engineering and Materials Science, Yuan Ze University, Taoyuan, Taiwan

    I-Ming Hung, Yu-Ting Chiou & Yi-Hung Wang

  2. Hierarchical Green-Energy Materials (Hi-GEM) Research Center, National Cheng Kung University, Tainan, 70101, Taiwan

    I-Ming Hung

  3. Nuclear Fuels and Materials Division, Institute of Nuclear Energy Research, Atomic Energy Council, New Taipei, Taiwan

    Tai-Nan Lin

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  1. I-Ming Hung
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Correspondence to I-Ming Hung.

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Hung, IM., Chiou, YT., Wang, YH. et al. Synthesis and Characterization of Bi0.85−xCa0.15ZrxO1.5−δ Oxygen Ion Conductors. J. Electron. Mater. 47, 5833–5841 (2018). https://doi.org/10.1007/s11664-018-6459-3

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  • DOI: https://doi.org/10.1007/s11664-018-6459-3

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