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Phase Equilibria and Thermodynamics of Selected Compounds in the Ag–Fe–Sn–S System

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Abstract

Polythermal sections in the vicinity of the quaternary compounds Ag2FeSnS4 and Ag2FeSn3S8 have been modeled. The mechanism of formation of these quaternary compounds and their thermal stability have been investigated. Measurements of electromotive force allowed calculations of the standard thermodynamic functions ΔG°, ΔH°, and S° of the Ag2FeSnS4 and Ag2FeSn3S8 compounds. Based on calorimetric measurements, the enthalpies of phase transitions of the selected compounds were determined. Furthermore, the heat capacities of both quaternary compounds were estimated by applying different calculation methods. Thermodynamic properties of the quaternary compounds, which are regarded as functional magnetic materials, were analyzed and are discussed in detail.

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Authors and Affiliations

  1. Johan Gadolin Process Chemistry Centre, Åbo Akademi University, Piispankatu 8, 20500, Turku, Finland

    Mykola Moroz, Fiseha Tesfaye, Daniel Lindberg & Leena Hupa

  2. Department of Inorganic Chemistry, Ivan Franko National University of Lviv, Kyryla and Mefodiya 6, Lviv, 79005, Ukraine

    Pavlo Demchenko

  3. Department of Cartography and Geospatial Modeling, Lviv Polytechnic National University, S. Bandery 12, Lviv, 79013, Ukraine

    Myroslava Prokhorenko

  4. Department of Physical and Colloid Chemistry, Ivan Franko National University of Lviv, Kyryla and Mefodiya 6, Lviv, 79005, Ukraine

    Oleksandr Reshetnyak

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  1. Mykola Moroz
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Correspondence to Mykola Moroz.

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Moroz, M., Tesfaye, F., Demchenko, P. et al. Phase Equilibria and Thermodynamics of Selected Compounds in the Ag–Fe–Sn–S System. J. Electron. Mater. 47, 5433–5442 (2018). https://doi.org/10.1007/s11664-018-6430-3

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