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Effect of A-Site Non-stoichiometry on Structure and Microwave Dielectric Properties of Ca x (Li0.36Nd0.36Bi0.14Na0.14)TiO3 Ceramics

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Abstract

By adding a small amount of calcium to the starting composition, Li0.36Nd0.36Bi0.14Na0.14TiO3, oxygen vacancies are suppressed and, therefore, the microwave properties are enhanced. This study not only obtained a kind of ceramic with excellent microwave dielectric properties, ε r ∼ 160, Q × f ∼ 1300 GHz and τ f ∼ 10 ppm/°C, but also gives a way to optimize the compositions with various donor and acceptor dopants for better performance in microwave ceramics.

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Acknowledgements

Financial supports of Guangxi Key Laboratory of Information Materials (Grant No. 151003-Z) and the National Natural Science Foundation of China (Grant No. 11464006) are gratefully acknowledged by the authors.

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Authors and Affiliations

  1. College of Powder Metallurgy Research Institute, Central South University, Changsha, 410083, People’s Republic of China

    Xiao Liu, Fenghua Luo & Xinyu Liu

  2. Guangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology, Guilin, 541004, People’s Republic of China

    Xiao Liu, Changlai Yuan, Xinyu Liu, Yuanlei Zhen, Guohua Chen & Changrong Zhou

  3. School of Mechanical and Electrical Engineering, Guilin University of Electronic Technology, Guilin, 541004, People’s Republic of China

    Fei Liu

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  1. Xiao Liu
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  2. Changlai Yuan
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Correspondence to Changlai Yuan.

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Liu, X., Yuan, C., Luo, F. et al. Effect of A-Site Non-stoichiometry on Structure and Microwave Dielectric Properties of Ca x (Li0.36Nd0.36Bi0.14Na0.14)TiO3 Ceramics. J. Electron. Mater. 47, 285–291 (2018). https://doi.org/10.1007/s11664-017-5760-x

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  • DOI: https://doi.org/10.1007/s11664-017-5760-x

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