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Fabrication and Electromagnetic Properties of Conjugated NH2-CuPc@Fe3O4

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Abstract

Conjugated amino-phthalocyanine copper containing carboxyl groups/magnetite (NH2-CuPc@Fe3O4) has been fabricated from FeCl3·6H2O and NH2-CuPc via a simple solvothermal method and its electromagnetic properties investigated. Scanning electron microscopy and transmission electron microscopy revealed that the NH2-CuPc@Fe3O4 was a waxberry-like nanomaterial with NH2-CuPc molecules effectively embedded in the interior of Fe3O4 particles in the form of beads. Introduction of NH2-CuPc effectively improved the complementarity between the dielectric and magnetic losses of the system, resulting in excellent electromagnetic performance. The minimum reflection loss of the as-prepared composite reached −33.4 dB at 7.0 GHz for coating layer thickness of 4.0 mm and bandwidth below −10.0 dB (90% absorption) of up to 3.8 GHz. These results indicate that introduction of NH2-CuPc results in a composite with potential for use as an electromagnetic microwave absorption material.

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Author notes

  1. Liang Yan and Zejun Pu contributed equally to this work.

Authors and Affiliations

  1. Research Branch of Advanced Functional Materials, School of Microelectronics and Solid-State Electronics, High Temperature Resistant Polymer and Composites Key Laboratory of Sichuan Province, University of Electronic Science and Technology of China, Chengdu, 610054, China

    Liang Yan, Zejun Pu, Mingzhen Xu, Renbo Wei & Xiaobo Liu

  2. College of Materials Science and Engineering, Sichuan University of Science and Engineering, Zigong, 643000, China

    Zejun Pu

Authors
  1. Liang Yan
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  2. Zejun Pu
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  3. Mingzhen Xu
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  4. Renbo Wei
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  5. Xiaobo Liu
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Correspondence to Renbo Wei or Xiaobo Liu.

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Yan, L., Pu, Z., Xu, M. et al. Fabrication and Electromagnetic Properties of Conjugated NH2-CuPc@Fe3O4 . J. Electron. Mater. 46, 5608–5618 (2017). https://doi.org/10.1007/s11664-017-5631-5

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  • DOI: https://doi.org/10.1007/s11664-017-5631-5

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