Abstract
La/Ni-substituted strontium hexaferrite Sr0.8La0.2Ni x Fe12-x O19 (x = 0.2 to 1.0 in steps of 0.2) nanoparticles have been produced by a coprecipitation method at reaction and calcination temperature of 80°C and 1200°C, respectively. X-ray diffraction (XRD) analysis confirmed formation of single-phase M-type hexaferrite structure. The average crystallite size and morphology of the nanoparticles were obtained from XRD analysis and transmission electron microscopy (TEM), respectively. The magnetic properties in magnetic field of 12 kOe obtained from room-temperature hysteresis loops revealed minimum and maximum magnetization for x = 0.4 and 0.8, respectively, a behavior attributed to the ionic radii of the substituted cations, canted spin structure, electron hopping between cations, and the substitutional sites of the ions. It was also confirmed that the magnetization of nanoscale particles was lower than that of bulk material, which can be explained based on the different behavior of surface versus bulk atoms. The coercivity varied with x in a similar way to the magnetization, being related to sample anisotropy. In the M-type hexaferrite structure, substitution of Fe3+ by Ni2+ occurred at octahedral sites, making the greatest contribution to the anisotropy.
Similar content being viewed by others
References
M.J. Iqbal, M.N. Ashiq, P.H. Gomez, and J.M. Munoz, J. Magn. Magn. Mater. 20, 881 (2008).
J. Amighian, M. Mozaffari, A. Arab, and M.H. Yousefi, J. Magn. Magn. Mater. 322, 748 (2010).
M. Mozaffari, A. Arab, M.H. Yousefi, and J. Amighian, J. Magn. Magn. Mater. 322, 2670 (2010).
M. Muroi, R. Street, P.G. McCormick, and J. Amighian, Phys. Rev. B 63, 184414 (2001).
Z.F. Zi, Y.P. Sun, X.B. Zhu, Z.R. Yang, J.M. Dai, and W.H. Song, J. Magn. Magn. Mater. 320, 2746 (2008).
X. Liu, P.H. Gomez, K.H.S. Zhou, Y. Wang, X. Cai, H. Sun, and B. Na, J. Magn. Magn. Mater. 305, 524 (2006).
M.J. Iqbal and M.N. Ashiq, Scr. Mater. 56, 145 (2007).
D.H. Choi, S.W. Lee, I.B. Shim, and C.S. Kim, J. Magn. Magn. Mater. 304, e243 (2006).
Q. Fang, H. Cheng, K. Huang, J. Wang, R. Li, and Y. Jiao, J. Magn. Magn. Mater. 294, 281 (2005).
D. Ravinder, P. Shalini, P. Maheshed, K.K. Rao, M. Vithal, and B.S. Boyanov, J. Alloys Compd. 364, 17 (2004).
A. Sharbati, J.M.V. Khani, and G.R. Amiri, Solid State Commun. 152, 199 (2012).
J. Bai, X. Liu, T. Xie, F. Wei, and Z. Yang, Mater. Sci. Eng. B 68, 182 (2000).
Z. Yang, G.S. Wang, X.H. Li, and H.X. Zeng, Mater. Sci. Eng. B 90, 142 (2002).
A. Arab, M.R. Mardaneh, and M.H. Yousefi, J. Magn. Magn. Mater. 374, 80 (2015).
M.J. Iqbal and M.N. Ashiq, Chem. Eng. J. 136, 383 (2008).
Y. Wang, L.C. Li, H. Liu, H. Qiu, and F. Xa, Mater. Lett. 62, 2060 (2008).
X. Liu, W. Zhong, S. Yang, Z. Yu, B. Gu, and Y. Du, J. Magn. Magn. Mater. 238, 207 (2002).
J.P. Chen, C.M. Sorensen, K.J. Klabunde, G.C. Hadjipanayis, E. Devlin, and A. Kostikas, Phys. Rev. B 54, 9288 (1996).
G.M. Suarez, K.K. Johul, H.M. Molinar, J.I.E. Garcia, and M.M.C. Guerrero, Mater. Res. Bull. 36, 2597 (2001).
M.J. Iqbal and S. Farooq, Mater. Chem. Phys. 118, 308 (2009).
J.F. Wang, C.B. Ponton, R. Grossinger, and I.R. Harris, J. Alloys Compd. 369, 170 (2004).
M.J. Iqbal, M.N. Ashiq, P.H. Gomez, and J.M. Munoz, Scr. Mater. 57, 1093 (2007).
H. Cui, Y. Liu, and W. Ren, Adv. Powder Technol. 24, 93 (2013).
C.A. Stergiou and G. Litsardakis, J. Alloys Compd. 509, 6609 (2011).
J. Li, Y. Duan, H. He, and D. Song, J. Alloys Compd. 315, 259 (2001).
M.J. Iqbal and S. Farooq, Mater. Res. Bull. 46, 662 (2011).
B.D. Cullity and C.D. Graham, Introduction to Magnetic Materials, 2nd ed. (Hoboken: Wiley, 2008), pp. 190–192.
H.M. Khan, M.U. Islam, Y. Xu, M.N. Ashiq, I. Ali, M.A. Iqbal, and M. Ishaque, Ceram. Int. 40, 6487 (2014).
E.A. Gravchikova, D.D. Zaitsev, P.E. Kazina, M.V. Popova, Y.D. Tretyakova, and M. Jansenb, Inorg. Mater. 42, 914 (2006).
N. Rezlescu, C. Doroftei, E. Rezlescu, and P.D. Popa, J. Alloys Compd. 451, 492 (2008).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Ghanbari, F., Arab, A., Shishe Bor, M. et al. Magnetic Properties of La/Ni-Substituted Strontium Hexaferrite Nanoparticles Prepared by Coprecipitation at Optimal Conditions. J. Electron. Mater. 46, 2112–2118 (2017). https://doi.org/10.1007/s11664-016-5140-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11664-016-5140-y