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Effect of Titanium Content on Dielectric and Energy Storage Properties of (Pb,La,Sr)(Zr,Sn,Ti)O3 Ceramics

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Abstract

The dielectric and energy storage properties of lead lanthanum strontium zirconate stannate titanate [(Pb0.92La0.04Sr0.02)((Zr0.70Sn0.30)1−x Ti x )O3] ceramics were investigated as a function of x (0.07 ≤ x ≤ 0.13). With increasing titanium content, the tolerance factor increased, resulting in decreased stability of antiferroelectric phase in the ceramics. As the titanium content was increased, the maximum dielectric constant increased and the temperature of the dielectric maximum shifted to lower values. According to the polarization–electric field hysteresis loops, both the charged and discharged energy densities increased consistently with the increase of titanium content. The unreleased energy densities also showed a systematic trend. From charge–discharge measurements based on the resistance load circuit, the released energy densities and power densities as a function of discharge time were determined over the investigated composition range.

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Authors and Affiliations

  1. Beijing Key Laboratory of Fine Ceramics, State Key Laboratory of New Ceramics and Fine Processing, Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing, 100084, People’s Republic of China

    Xiaozhen Song, Yong Zhang, Yongzhou Chen, Qian Zhang, Jia Zhu & Dongliang Yang

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  1. Xiaozhen Song
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  2. Yong Zhang
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  3. Yongzhou Chen
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  4. Qian Zhang
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  5. Jia Zhu
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  6. Dongliang Yang
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Correspondence to Yong Zhang.

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Song, X., Zhang, Y., Chen, Y. et al. Effect of Titanium Content on Dielectric and Energy Storage Properties of (Pb,La,Sr)(Zr,Sn,Ti)O3 Ceramics. J. Electron. Mater. 44, 4819–4824 (2015). https://doi.org/10.1007/s11664-015-4038-4

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  • DOI: https://doi.org/10.1007/s11664-015-4038-4

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