Abstract
A suite of complementary high-throughput screening systems for combinatorial films was developed at National Institute of Standards and Technology to facilitate the search for efficient thermoelectric materials. These custom-designed capabilities include a facility for combinatorial thin film synthesis and a suite of tools for screening the Seebeck coefficient, electrical resistance (electrical resistivity), and thermal effusivity (thermal conductivity) of these films. The Seebeck coefficient and resistance are measured via custom-built automated apparatus at both ambient and high temperatures. Thermal effusivity is measured using a frequency domain thermoreflectance technique. This paper will discuss applications using these tools on representative thermoelectric materials, including combinatorial composition-spread films, conventional films, single crystals, and ribbons.
Similar content being viewed by others
REFERENCES
G.S. Nolas, J. Sharp, and H.J. Goldsmid, Thermoelectrics: Basic Principles and New Materials Developments (Berlin: Springer, 2001).
K.F. Hsu, S. Loo, F. Guo, W. Chen, J.S. Dyck, C. Uher, T. Hogan, E.K. Polychroniadis, and M.G. Kanatzidis, Science 303, 818 (2004).
T.C. Harman, P.J. Taylor, M.P. Walsh, and B.E. LaForge, Science 297, 2229 (2002).
L.D. Zhao, S.H. Lo, Y. Zhang, H. Sun, and G. Tan, et al., Nature 508, 7496 (2014).
R. Venkatasubramanian, E. Siivola, T. Colpitts, and B.O. Quinn, Nature 413, 597 (2001).
Y. Hasegawa, Y. Ishikawa, T. Komine, T.E. Huber, A. Suzuki, H. Morita, and H. Shirai, Appl. Phys. Lett. 85, 917 (2004).
R. Potyrailo, K. Rajan, K. Stoewe, I. Takeuchi, B. Chisholm, and H. Lam, ACS Comb. Sci. 13, 579 (2011).
H. Koinuma, H.N. Aiyer, and Y. Matsumoto, Sci. Tech Adv Mater. 1, 1 (2000).
W. Wong-Ng, J. NIST Res. (2012). doi:10.6028/jres.117.018.
R.B. Van Dover, L.F. Schneemeyer, and R.M. Fleming, Nature 392, 162 (1998).
T. Fukumura, M. Ohtani, M. Kawasaki, Y. Okimoto, T. Kageyama, T. Koida, T. Hasegawa, Y. Tokura, and H. Koinuma, Appl. Phys. Lett. 77, 3426 (2000).
H.M. Christen, S.D. Silliman, and K.S. Harchavardhan, Rev. Sci. Instrum. 72, 2673 (2001).
M. Otani, N.D. Lowhorn, P.K. Schenck, W. Wong-Ng, and M. Green, Appl. Phys. Lett. 91, 132102 (2007).
M. Otani, K. Itaka, W. Wong-Ng, P.K. Schenck, and H. Koinuma, Appl. Surf. Sci. 254, 765 (2007).
Y.G. Yan, W. Wong-Ng, J. Martin, M. Green, and X.F. Tang, Rev. Sci. Instrum. 84, 115110 (2013).
J. Martin, Sci. Technol. 24, 085601 (2013).
L.J. van der Pauw, Philips Tech. Rev. 20, 220 (1958).
B.C. Sales, Science 272, 1325 (1996).
S. Li, R. Funahashi, I. Matsubara, H. Yamada, K. Ueno, and S. Sodeoka, Ceram. Int. 27, 321 (2001).
W. Wong-Ng, Y.F. Hu, M.D. Vaudin, B. He, M. Otani, N.D. Lowhorn, and Q. Li, J. Appl. Phys. 102, 33520 (2007).
Y. Wang, Y. Sui, P. Ren, L. Wang, X. Wang, W. Su, and H.J. Fan, Inorg. Chem. 49, 3216 (2010).
R. Robert, L. Bocher, M. Trottmann, A. Reller, and A. Weidenkaff, J. Solid State Chem. 179, 3893 (2006).
C.A. Hewitt, A.B. Kaiser, S. Roth, M. Craps, R. Czerw, and D.L. Carroll, Nano Lett. 12, 1307 (2012).
N.D. Lowhorn, W. Wong-Ng, Z.Q. Lu, J. Martin, M.L. Green, J.E. Bonevich, E.L. Thomas, N.R. Dilley, and J. Sharp, J. Mater. Res. 26, 1983 (2011).
S. Nakajima, J. Phys. Chem. Solids 24, 479 (1963).
C. Kittel, Solid State Physics, 2nd ed. (New York: Wiley, 1956), p. 296.
W. Wong-Ng, P. Zalvis, H.L. Joress, J. Martin, Y. Yan, and J. Yang, Appl. Phys. Lett. 100, 082107 (2012).
Y. Yan, W. Wong-Ng, J.A. Kaduk, G. Tan, W. Xie, and X. Tang, Appl. Phys. Lett. 98, 142106 (2011).
M. Otani, E. Thomas, W. Wong-Ng, P.K. Schenck, K.-S. Chang, N.D. Lowhorn, M.L. Green, and H. Ohguchi, Jpn. J. Appl. Phys. 48, 05EB02 (2009).
W. Wong-Ng, H. Joress, J. Martin, Y. Yan, J. Yang, M. Otani, E.L. Thomas, M.L. Green, and J. Hattrick-Simpers, Advances and Applications in Electroceramics: Ceramics Transaction, vol. 226, ed. K.M. Nair, Q. Jia, and S. Priya, (Hoboken: Wiley, 2011), p. 173
D.G. Cahill, Rev. Sci. Instrum. 75, 5119 (2004).
W. Wong-Ng, L.P. Cook, C.K. Chiang, L. Swartzendruber, L.H. Bennett, J.E. Blendell, and D. Minor, J. Mater. Res. 3, 832 (1988).
S. Block, G. Pieramini, R. Munro, and W. Wong-Ng, Ceramic Superconductors, W. J. Smothers, ed., Adv. Ceram. Mater., 2(3B) (Westerville, OH: American Ceramics Society, 1987), p. 601
T. Yagi, N. Taketoshi, and H. Kato, Phys. C 412–414, 1337 (2004).
R. Hull, eds., Properties of Crystalline Silicon (London: INSPEC, The Institution of Electrical Engineers, 1999), p. 165
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Wong-Ng, W., Yan, Y., Otani, M. et al. High Throughput Screening Tools for Thermoelectric Materials. J. Electron. Mater. 44, 1688–1696 (2015). https://doi.org/10.1007/s11664-014-3519-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11664-014-3519-1