Abstract
This paper investigates a set of theoretical equations for analyzing the thermal properties of isotropic conductive adhesives (ICAs) containing several types of Cu filler particles. The thermal conductivity of ICAs containing randomly dispersed filler particles can be simulated well by Bruggeman’s equation for spherical particles and by Kanari’s equation for flake particles. The effect on the thermal conductivity of any residual voids can be taken into account in the analysis by the additional application of Bruggeman’s or Kanari’s equations with the appropriate shape factor. The linear thermal expansion coefficient of the ICAs was analyzed using Schapery’s scheme. The thermal expansion coefficients of ICAs with 40–50 vol.% of filler particles range between Schapery’s upper and lower limits. As the particle size of the filler decreases, the thermal expansion coefficient starts to approach the lower limit at a lowr volume fraction of the filler particles. The transition behavior of the thermal expansion coefficient is related to the characteristics of the network structure formed by percolating the filler particles.
Similar content being viewed by others
References
K. Suganuma, MRS Bull. 26, 880 (2001).
J. Liu, Conductive Adhesives for Electronics Packaging (Port Erin: Electrochemical Publications, 1999).
T. Sugimura, M. Inoue, M. Yamashita, S. Yamaguchi, and K. Suganuma, J. Jpn. Inst. Electron. Packaging 7, 147 (2004) (in Japanese).
D.A.G. Bruggeman, Ann. Phys. 24, 636 (1935).
R.A. Schapery, J. Composite Mater. 2, 380 (1968).
R.E. Meridith and C.W. Tobias, J. Appl. Phys. 31, 1270 (1960).
R.E. Meridith and C.W. Tobias, J. Electrochem. Soc. 108, 286 (1961).
F.A. Johnson, Atomic Energy Research Establishment R/R 1, 2578 (1958).
K. Kanari, Kobunshi 26, 557 (1977) (in Japanese).
R.L. Hamilton and O.K. Crosser, Ind. Eng. Chem., Fundam. 1, 187 (1962).
Z. Hashin, J. Appl. Mech., Trans. ASME 29, 143 (1962).
Z. Hashin and S. Shtrikman, J. Mech. Phys. Solids 11, 127 (1963).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Inoue, M., Sugimura, T., Yamashita, M. et al. Analytical equations for predicting the thermal properties of isotropic conductive adhesives. J. Electron. Mater. 34, 1586–1590 (2005). https://doi.org/10.1007/s11664-005-0169-3
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s11664-005-0169-3