Abstract
A methodology to characterize processes of in situ leaching is developed to study various parameters that may affect the recovery of a valuable mineral and to assure a successful application of the in situ leaching technology. A leaching kinetics model is first derived based on the concept of representative elementary volume (REV) in porous ore deposits. Every parameter in the model is clearly defined and may be easy to obtain in practice. Then the governing equations are obtained for transport of both the reagent and the dissolved mineral in porous ore deposits. These equations are solved by a fully three-dimensional computer simulator. Effects on the mineral recovery of parameters such as lumped rate constant, ore porosity, injection flux, and macrodispersivities are investigated through the three-dimensional case with one injection well. It is found that all of these four parameters, interconnected through the ore porosity, significantly affect the effectiveness of the in situ leaching. Furthermore, the flow velocity of leach solution within an ore deposit may be the key parameter to the design of a real leaching mine because all of the other three parameters are site specific.
Similar content being viewed by others
References
J. Christensen, A.D. Danielson, D. Davidson, D. Hallford, D. Johnston, L.P. Scholes, R. Huff, H.G. Kreis, A. Raihl, C. Lasala, and S.A. Swan: Oilfield Rev., 1991, vol. 3 (1), pp. 8–17.
B.H. Brady and J. Liu: Proc. Mining Technology Conf., Fremantle, WA, Australia, D. Howarth, H. Gurgenci, D. Sutherland, and B. Firth, eds., Cooperative Research Center for Mining Technology and Equipment, Pinjarra Hills, QLD, Australia, 1996, pp. 150–58.
K.L. Wiley, D.S. Ramey, and M.J. Rex: Mining Eng., 1994, Aug., pp. 991–94.
A.C. Lasaga: J. Geophys. Res., 1984, vol. 89, pp. 4009–25.
M.D. Pritzker: Metall. Mater. Trans. B, 1995, vol. 26B, pp. 901–10.
R.W. Bartlett: Proc. Int. Symp. on Hydrometallurgy, D.J.I. Evans and R.S. Shoemaker, eds., American Institute of Mining, Metallurgical & Petroleum Engineers, New York, 1973, pp. 331–74.
V.V. Nguyen, W.G. Gray, G.F. Pinder, J.F. Botha, and D.A. Crerar: Water Resources Res., vol. 18 (4), pp. 1149–56.
X. Meng, X. Sun, and K.N. Han: Minerals Metall. Processing, 1995, May, pp. 97–102.
L.E. Schultze, S.P. Sandoval, and R.P. Bush: USBM RI-9556, Government Printing Office, Washington, DC, 1995.
C.D. Marozas: USBM RI-9216, Government Printing Office, Washington, DC, 1989, pp. 49–57.
S.L. Bryant and L.W. Schechter: AICHE J., 1986, vol. 32 (5), pp. 751–64.
M.P. Wash and S.L. Bryant: AICHE J., 1984, vol. 30 (5), pp. 317–28.
S.D. Rege and H.S. Fogler: AICHE J., 1989, vol. 35 (7), pp. 1177–85.
S.J. Gibowicz: in Rockbursts and Seismicity in Mines, C. Fairhurst, ed., Rotterdam, Netherlands, Brookfield, VT, 1990, pp. 3–27.
D.B. Levy, K.H. Custis, W.H. Casey, and P.A. Rock: Appl. Geochem., 1997, vol. 12, pp. 203–11.
N. Eriksson and G. Destouni: Water Resources Res., 1997, vol. 33 (3), pp. 471–83.
P.G. Baker and P.L. Bishop: J. Hazardous Mater., 1997, vol. 55, pp. 311–33.
D.P. Bents and E.J. Garboczi: Mater. Struct., 1992, vol. 25, pp. 523–33.
R. Jacobson and J.W. Murphy: Mineral Resource Eng., 1988, vol. 1 (1), pp. 67–83.
R. Jacobson and J.W. Murphy: Mineral Resource Eng., 1988, vol. 1 (3), pp. 263–74.
R. Jacobson, J.W. Murphy, and P.B. Queneau: Mineral Resource Eng., 1989, vol. 2 (2), pp. 163–87.
V.V. Nguyen, G.F. Pinder, W.G. Gray, and J.F. Btha: Chem. Eng. Sci., 1983, vol. 38 (11), pp. 1855–62.
K.C. Liddell and R.G. Bautista: Metall. Trans. B, 1994, vol. 25B, pp. 171–83.
K.C. Liddell and R.G. Bautista: Metall. Trans. B, 1995, vol. 26B, pp. 687–94.
K.C. Liddell and R.G. Bautista: Metall. Trans. B, 1995, vol. 26B, pp. 695–702.
H.W. Gao, H.Y. Sohn, and A. Wadsworth: Metall. Trans. B, 1983, vol. 14B, pp. 541–51.
H.W. Gao, H.Y. Sohn, and A. Wadsworth: Metall. Trans. B, 1983, vol. 14B, pp. 553–58.
R.D. Schmidt: USBM IC-9216, Government Printing Office, Washington, DC, 1989, pp. 58–66.
R.B. Lantz and SW. Statham: in In-Situ Recovery of Minerals II, S.A. Swan and K.R. Coyne, eds., Engineering Foundation, New York, 1994, pp. 539–89.
J.P. Montero, J.F. Munoz, R. Abeliuk, and M. Vauclin: Soil Sci. Soc. Am. J., 1994, vol. 58, pp. 678–86.
T.M. Yegulalp and K. Kim: Mining Eng., 1996, Jan., pp. 45–48.
J.F. Munoz, P. Rengifo, and M. Vauclin: J. Contaminant Hydrology, 1997, vol. 27, pp. 1–24.
D.G. Dixon and J.L. Hendrix: Metall. Trans. B, 1993, vol. 24B, pp. 1087–1101.
R.H. Parker and A. Jupe: Minerals Eng., 1997, vol. 10 (3), pp. 301–08.
J. Bear: Dynamics of Fluids in Porous Media, American Elsevier, New York, NY, 1972.
C. Vu and K.N. Kan: Trans. Inst. Min. Metall., Section C, 1977, vol. 86, pp. C119-C125.
R.R. Petrovich, R.A. Berner, and M.B. Goldhaber: Geochim. Cosmochim. Acta, 1976, vol. 40, pp. 537–48.
J.R. Schott, R.A. Berner, and E.L. Sjoberg: Geochim. Cosmochim. Acta, 1981, vol. 45, pp. 2123–35.
D.V. Andrea, W.C. Larson, and L.R. Fletcher: USBM RI-8236, Government Printing Office, Washington, DC, 1977.
J.E. Dutrizac: Can. Metall. Q., 1981, vol. 20 (3), pp. 307–15.
X. Meng and K.N. Han: Minerals Metall. Processing, 1993, August, pp. 128–34.
G.R. Holdren and R.A. Berner: Geochim. Cosmochim. Acta, 1979, vol. 43, pp. 1161–71.
D.E. Grandstaff: Proc. 3rd Int. Symp. on Water-Rock Interaction, Alberta Research Council, Edmonton, AB, Canada, 1980, pp. 72–74.
C.I. Steefel and T.B. MacQuarrie: in Reactive Transport in Porous Media. Reviews in Mineralogy Volume 34, P.C. Lichtner, C.I. Steefel, and E.H. Oelkers, eds., Mineralogical Society of America, Washington, DC, 1996, pp. 83–125.
M. Reeves, D.S. Ward, N.D. Johns, and R.M. Cranwell: Report NUREG/CR-3162, SAND83-0242, Sandia National Laboratories, Albuquerque, NM, 1986.
M. Reeves, D.S. Ward, N.D. John, and R.M. Cranwell: Report NUREG/CR-3328, SAND83-1159, Sandia National Laboratories, Albuquerque, NM, 1986.
M. Reeves, N.D. Johns, and R.M. Cranwell: Report NUREG/CR-3925, SAND83-1586, Sandia National Laboratories, Albuquerque, NM, 1986.
D.S. Ward, M. Reeves, and L.E. Duda: Report NUREG/CR-3316, SAND83-1154, Sandia National Laboratories, Albuquerque, NM, 1984.
N.C. Finley and M. Reeves: Report NUREG/CR-1968, SAND81-0410, Sandia National Laboratories, Albuquerque, NM, 1982.
D.S. Ward, D.R. Buss, J.W. Mercer, and S.S. Hughes: Water Resources Res., 1987, vol. 23 (4), pp. 603–17.
J. Liu and B.H. Brady: Int. J. Analy. Num. Methods Geomech., 1998, in press.
L.W. Gelhar, C. Welty, and K.R. Rehfeldt: Water Resources Res., 1992, vol. 22 (7), pp. 1955–74.
N.R. Sainath and S. Harpalani: Mining Eng., 1993, Oct., pp. 1303–06.
S.E. Paulson and H.L. Kuklman: USBM RI-9216, 1989, pp. 18–36.
R.E. Smelser, O. Richmond, and F.C. Schwerer: Int. J. Rock Mech. Min. Sci. Geomech. Abstr., 1984, vol. 21, pp. 13–20.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Liu, J., Brady, B.H. Evaluation of velocity-dependent in situ leaching processes: Single-porosity model. Metall Mater Trans B 29, 1227–1234 (1998). https://doi.org/10.1007/s11663-998-0045-7
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11663-998-0045-7