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Research on Depth Dechlorination by Copper Slag Valence Regulation of Synergistic High-Activity Copper in the Ultrasonic Field

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Abstract

Due to the problems of cuprous chloride resolution and low copper activity in traditional copper slag dechlorination process, depth dechlorination by copper slag valence regulation of synergistic high-activity copper in the ultrasonic field was proposed. According to a series of conditional experiments, the optimal dechlorination parameters under ultrasonic conditions are as follows: the molar ratio of Cu:Zn:Cl is 3:2:1, the chlorine concentration can be reduced from 440 to 15 mg/L at 30 minutes, 50 °C and 30 g/L acidity, and the dechlorination efficiency is 96.6 pct. Compared with conventional and ultrasonic dechlorination, ultrasonic dechlorination can reduce the amount of copper slag by 56.67 pct and zinc powder by 68.1 pct to achieve low consumption and high-efficiency dechlorination. Ultrasonic dechlorination, because of its cavitation, the mechanical effect can accelerate and deepen the reaction process and can achieve a high standard of deep chlorine removal purpose, has a broad prospect in the industrial field.

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Acknowledgments

This work was supported by the NSFC Regional Fund (No. 52264050), Basic Research Project of Science and Technology Plan of Yunnan Provincial Department of Science and Technology (No. 202201AS070031). The authors are grateful for The Kunming Key Laboratory of Special Metallurgy, Kunming Academician Workstation of Advanced Preparation for Super hard Materials Field, Kunming Academician Workstation of Metallurgical process Intensification, and Yunnan Chihong Zinc Germanium Co., Ltd. Non-ferrous Metal Electrodeposition Technology Provincial Innovation Team.

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Authors and Affiliations

  1. Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming, 650093, China

    Jiayao He, Dongbin Wang, Shuai Wang, Jing Li & Junchang Liu

  2. Kunming Key Laboratory of Special Metallurgy, Kunming University of Science and Technology, Kunming, 650093, China

    Jiayao He, Dongbin Wang, Shuai Wang & Jing Li

  3. State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming, 650093, Yunnan, China

    Jiayao He, Dongbin Wang, Shuai Wang & Jing Li

  4. National Local Joint Laboratory of Engineering Application of Microwave Energy and Equipment Technology, Kunming, 650093, Yunnan, China

    Jiayao He, Dongbin Wang, Shuai Wang & Jing Li

  5. Key Laboratory of Unconventional Metallurgy, Ministry of Education, Kunming, 650093, Yunnan, China

    Jiayao He, Dongbin Wang, Shuai Wang & Jing Li

  6. Kunming Metallurgical Research Institute Co., Ltd, Kunming, 650093, Yunnan, China

    Junchang Liu

  7. Yunnan Chihong Zn&Ge CO., LTD, Qujing, 655011, Yunnan, China

    Hongtao Qu, Zhongbin Pi, Guang Fu, Shaobin Ma, Te Zhang, Zhenguo Zhang & Chaobo Zhang

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He, J., Qu, H., Wang, D. et al. Research on Depth Dechlorination by Copper Slag Valence Regulation of Synergistic High-Activity Copper in the Ultrasonic Field. Metall Mater Trans B 54, 2320–2331 (2023). https://doi.org/10.1007/s11663-023-02824-2

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