Skip to main content
Log in

Sulfur Removal from Spent Ladle Refining Furnace Slag at High Temperature

  • Brief Communication
  • Published:
Metallurgical and Materials Transactions B Aims and scope Submit manuscript

To develop an effective method for removing sulfur from spent refining slag at high temperature, the slag was treated in argon atmosphere using desulfurization ash as desulfurization reagent. Experimental results revealed that at 1773 K, molar ratio of CaS to CaSO4 + CaSO3 of 3:1, and reaction time of 2 hours, sulfur removal efficiency reached a maximum of 67.9 pct. The optimal ratio indicates the reaction of CaS and CaSO4 + CaSO3 to generate S2 may predominante during processing.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

References

  1. X.M. Yang, M. Zhang, C.B. Shi, G.M. Chai and J. Zhang: Metall. Mater. Trans. B, 2012, vol. 43B, pp. 241–266.

    Article  Google Scholar 

  2. W.T. Lou and M.Y. Zhu: Metall. Mater. Trans. B, 2014, Vol. 45B, pp. 1706–1722.

    Article  Google Scholar 

  3. Z. Liu, F. Qi, B. Li and M. Jiang: Metall. Mater. Trans. B, 2015, vol. 46, pp. 933–952.

    Article  Google Scholar 

  4. C. Allertz and Du Sichen: Metall. Mater. Trans. B, 2015, vol. 46, pp. 2609–2615.

  5. K. Gijbels and H. Nguyen et al.: J Clean. Prod., 2019, vol. 237, pp.117793

    Article  CAS  Google Scholar 

  6. C. Pinheiro and S. Rios et al.: Constr. Build. Mater., 2020, vol. 264, pp.120271

    Article  CAS  Google Scholar 

  7. B. Xu and Y.L. Yi: Sci. Total Environ., 2020, vol. 705, pp. 135854

    Article  CAS  Google Scholar 

  8. P.N. Lemougna and J. Yliniemi et al.: Constr. Build. Mater., 2019, vol. 221, pp. 332–344

    Article  CAS  Google Scholar 

  9. H.F. Yang and Y.T. et al.: J Environ. Chem. Eng., 2018, vol. 6(5), pp. 6451–6456.

  10. E. Pantazopoulou and A. Zouboulis: J Environ. Manage., 2018, vol. 216, pp. 257–262.

    Article  CAS  Google Scholar 

  11. Y. Zhou and L.S. Wu et al.: Hydrometallurgy, 2013, vol. 140, pp.14–19

    Article  CAS  Google Scholar 

  12. V.Z. Serjun and A. Mladenovič et al.: Waste Manage., 2015, vol. 43, pp. 376–385

    Article  CAS  Google Scholar 

  13. F. Pietrini and V. Iori et al.: J Hazard. Mater., 2017, vol. 329, pp. 339–347

    Article  CAS  Google Scholar 

  14. F. Memoli, C. Mapelli, M. Guzzon: Iron and Steel Technology, 2007, vol. 4(2), pp. 68–76.

    CAS  Google Scholar 

  15. N.N. Lv and H.B. Cui et al.: J Mater. Metall. (Chinese), 2017, vol. 16 (2), pp. 128–135.

    Google Scholar 

  16. H.Y. He and J.Q. Wang et al.: J Iron Steel Res. (Chinese), 2018, vol.30 (1), pp. 26–31

  17. K. Kobayashi, T. Hiraki and T. Nagasaka: High Temp. Mater. Process., 2012, vol. 31, pp. 667–673.

    Article  CAS  Google Scholar 

  18. C. Allertz and S.C. Du : J Sustain. Metall., 2015, vol. 1(3), pp. 229–239.

  19. L.H. Zhao, L. Lin and Q.F. Wu: Int. J. Min. Metall. Mater., 2016, vol. 23, pp.33–39.

    Article  CAS  Google Scholar 

  20. A. Matsui, Y.I. Uchida and N. Kikuchi: ISIJ int., 2017, vol. 57(6), pp. 1012–1018.

    Article  CAS  Google Scholar 

  21. T. Hiraki, J. Kobayashi, S. Urushibata, K. Matsubae and T. Nagasaka: Metall. Mater. Trans. B, 2012, vol. 43, pp.703–709.

    Article  Google Scholar 

  22. L.S. Wu, C.J. Qi, B.J. Yan, J. Wang and Y.C. Dong: Metall. Mater. Trans. B, 2020, vol. 51, pp. 2339–2347.

    Article  Google Scholar 

  23. K. Wieczorek-Ciurowa: J. Thermal Anal., 1992, vol. 38, pp. 523–530

    Article  CAS  Google Scholar 

  24. E.M. van der Merwe, C.A. Strydom and J.H. Potgieter: Thermochimica Acta, 1999, vol. 340–341, pp. 431–437

    Article  Google Scholar 

  25. X.S. Yang and Z.Y. Zhang: J. Chem. Thermodyn. 2013, vol. 57, pp. 39–45.

    Article  CAS  Google Scholar 

Download references

The authors gratefully acknowledge the financial support from the National Natural Science Foundation of China (Project No. 51774001).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Liushun Wu.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Manuscript submitted November 20, 2020; accepted January 27, 2021.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wu, L., Liu, K., Xu, W. et al. Sulfur Removal from Spent Ladle Refining Furnace Slag at High Temperature. Metall Mater Trans B 52, 590–593 (2021). https://doi.org/10.1007/s11663-021-02098-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11663-021-02098-6

Navigation