Abstract
The gangue content in iron ore pellets that are used to produce direct-reduced iron (DRI) affects the slag volume during subsequent electric furnace steelmaking. Industrial and laboratory measurements and simulations have shown that unfluxed gangue from DRI also strongly affects the degree of saturation of the steelmaking slag with MgO. Laboratory tests show slag-line attack of such undersaturated slag on an MgO crucible, in support of reported refractory wear during steelmaking with higher-gangue DRI.
References
R. Sarkar and H.Y Sohn (2018) Metall. Mater. Trans. B, vol. 49, pp. 1860-82.
[2] E.B. Pretorius and R.C. Carlisle: Iron Steelmaker, 1999, vol. 26, pp. 79-88.
[3] R.A.M. de Almeida, D. Vieira, W.V. Bielefeldt, and A.C.F. Vilela: Materials Research, 2018, vol. 21, pp.1-8.
[4] C.M. Yoon, Y. Park, and D.J. Min: Metall. Mater. Trans. B, 2018, vol. 49B, pp. 2322-31.
[5] S.M. Jung, and D.J. Min: ISIJ International, 2010, vol.50, pp.1632-1636.
[6] J.J. Poveromo: The Making, Shaping and Treating of Steel. In: D.H. Wakelin, ed., Ironmaking Volume, 11th edition. AISE Steel Foundation, Pittsburgh, PA, 1999, pp. 547-642.
[7] C.W. Bale, E. Bélisle, P. Chartrand, S.A. Decterov, G. Eriksson, A.E. Gheribi, K. Hack, I.-H. Jung, Y.-B. Kang, J. Melançon, A.D. Pelton, S. Petersen, C. Robelin, J. Sangster, P. Spencer and M-A. Van Ende: CALPHAD, 2016, vol. 54, pp. 35-53
R. Selin: The role of phosphorus, vanadium and slag forming oxides in direct reduction based steelmaking, PhD thesis, Royal Institute of Technology (Stockholm, Sweden), 1987.
[9] H. Suito, R. Inoue, and M. Takada: Trans. Iron Steel Inst. Jpn., 2006, vol. 21, pp. 250-59.
[10] M. A. Tayeb, A. N. Assis, S. Sridhar, and R. J. Fruehan: Metall. Mater. Trans. B, 2015, vol. 46B, pp. 1112-14.
[11] D. Roy, P.C. Pistorius, and R.J. Fruehan: Metall. Mater. Trans. B, 2013, vol. 44B, pp. 1095–1104.
M. Cable: Corrosion of Advanced Ceramics (K.G. Nickel, ed.), Kluwer, New York, 1994, pp. 285–96.
[13] J.S. Han, J.H. Heo and J.H. Park: Ceram. Int., 2019, vol. 45, pp. 10481-91.
[14] T. K. Sherwood: Mass Transfer, McGraw-Hill Inc, New York, 1975.
[15] S. Mackwell, M. Bystricky and C. Sproni: Phys. Chem. Miner., 2005, vol. 32, pp. 418–25
M.A. Tayeb: Phosphorus control in DRI-EAF steelmaking: Thermodynamics, effect of alumina, and process modeling, PhD thesis, Carnegie Mellon University, 2015.
[17] S.A. Suvorov and V.V. Kozlov: Refractories and Industrial Ceramics, 2014, vol. 55, pp. 114-16.
R. Wei, X. Lv, Z, Yue, S. Xiang (2017) Metall. Mater. Trans. B, vol. 48, pp. 733-42.
[19] C. Wagner, C. Wenzl, D. Gregurek, D. Kreuzer, S. Luidold and H. Schnideritsch: Metall. Mater. Trans. B, 2017, vol. 48B, pp. 119-31.
[20] M. Kirschen, A. Hanna and K.-M. Zettl: Iron & Steel Technology, 2016, vol. 13(1), pp. 52-59.
The authors are grateful for the support by the industrial members of the Center for Iron and Steel-making Research, financial support by the China Scholarship Council and use of the Materials Characterization Facility at Carnegie Mellon University, supported by Grant MCF-677785.
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Manuscript submitted August 16, 2019.
Rights and permissions
About this article
Cite this article
Song, S., Zhao, J. & Pistorius, P.C. MgO Refractory Attack by Transient Non-saturated EAF Slag. Metall Mater Trans B 51, 891–897 (2020). https://doi.org/10.1007/s11663-020-01788-x
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11663-020-01788-x