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Applications of Laser-Induced Breakdown Spectroscopy (LIBS) in Molten Metal Processing

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Abstract

In order for metals to meet the demand for critical applications in the automotive, aerospace, and defense industries, tight control over the composition and cleanliness of the metal must be achieved. The use of laser-induced breakdown spectroscopy (LIBS) for applications in metal processing has generated significant interest for its ability to perform quick analyses in situ. The fundamentals of LIBS, current techniques for deployment on molten metal, demonstrated capabilities, and possible avenues for development are reviewed and discussed.

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References

  1. 1. L. J. Radziemski and D. A. Cremers: Laser-induced plasmas and applications. (M. Dekker, New York, 1989).

    Google Scholar 

  2. 2. Y. I. Lee, K. Song and J. Sneddon: Laser-induced breakdown spectrometry. (Nova Science Publishers, Huntington, N.Y., 2000).

    Google Scholar 

  3. S.N. Thakur and J.P. Singh: in Laser-Induced Breakdown Spectroscopy, S.N. Thakur and J.P. Singh, eds., Elsevier, 2007.

  4. 4. T. Hussain and M. A. Gondal, J Phys Conf Ser 2013, vol. 439, p. 012050.

    Google Scholar 

  5. 5. M. Sabsabi and P. Cielo, Applied spectroscopy 1995, vol. 49, pp. 499-507.

    Article  Google Scholar 

  6. R. Noll: in Laser-Induced Breakdown Spectroscopy: Fundamentals and Applications, R. Noll, ed., Springer, 2012.

  7. J.R. Scott, A.J. Effenberger, and J.J. Hatch: in Laser-Induced Breakdown Spectroscopy: Theory and Applications, S. Musazzi and Perini U., eds. Springer, 2014.

  8. E Tognoni, V. Palleschi, M. Corsi, G. Cristoforetti, N. Omenetto, I. Gornushkin, B.W. Smith and J.D. Winefordner: Laser-Induced Breakdown Spectroscopy: Fundamentals and Applications, A.W. Miziolek, V. Palleschi, and I. Schechter, eds., Cambridge University Press, New York, 2006.

  9. D.A. Cremers and L.J. Radziemski: Handbook of Laser-Induced Breakdown Spectroscopy, Wiley, 2013.

  10. R. Noll: in Laser-Induced Breakdown Spectroscopy: Fundamentals and Applications, R. Noll, ed., Springer, 2012.

  11. 11. C. Momma, S. Nolte, B. N. Chichkov, F. vonAlvensleben and A. Tunnermann, Appl Surf Sci 1997, vol. 109, pp. 15-19.

    Article  Google Scholar 

  12. 12. David W. Hahn and Nicoló Omenetto, Appl. Spectrosc. 2010, vol. 64, pp. 335A-366A.

    Article  Google Scholar 

  13. 13. D. W. Hahn and N. Omenetto, Applied spectroscopy 2012, vol. 66, pp. 347-419.

    Article  Google Scholar 

  14. 14. A. Bogaerts, Z. Chen, R. Gijbels and A. Vertes, Spectrochimica Acta Part B: Atomic Spectroscopy 2003, vol. 58, pp. 1867-1893.

    Article  Google Scholar 

  15. 15. J. F. Ready, In Effects of High-Power Laser Radiation, (Academic Press: New York, 1971).

    Google Scholar 

  16. 16. J. M. Vadillo, J. M. Fernández Romero, C. Rodríguez and J. J. Laserna, Surf Interface Anal 1999, vol. 27, pp. 1009-1015.

    Article  Google Scholar 

  17. 17. J. A. McMordie and P. D. Roberts, Journal of Physics D: Applied Physics 1975, vol. 8, pp. 768-781.

    Article  Google Scholar 

  18. 18. R. A. Multari, L. E. Foster, D. A. Cremers and M. J. Ferris, Applied spectroscopy 1996, vol. 50, pp. 1483-1499.

    Article  Google Scholar 

  19. 19. E.F. Runge, B. Bonfiglio and F.R. Bryan, Spectrochemica Acta 1966, vol. 22, pp. 1678-1680.

    Article  Google Scholar 

  20. K.H. Spring, C. Carlhoff, C.J. Lorenzen, K.P. Nick, and H. J. Siebeneck:-Process Optical Measurements, SPIE, Hamburg, Germany, 1989, pp. 194–96.

  21. 21. L. Paksy, B. Nemet, A. Lengyel and L. Kozma, Spectrochimica acta. Part B: Atomic spectroscopy 1996, vol. 51, pp. 279-290.

    Article  Google Scholar 

  22. 22. O. Samek, D. C. S. Beddows, J. Kaiser, S. V. Kukhlevsky, M. Liska, H. H. Telle and J. Young, Optical Engineering 2000, vol. 39, pp. 2248-2262.

    Article  Google Scholar 

  23. R. De Saro, A. Weisberg, and J. Craparo: ACEEE Summer Study on Energy Efficiency in Industry, 2005, pp 1–35.

  24. D.A. Cremers, F.L. Archuleta, and H.C. Dilworth: 5th Process Technology Conference on Measurement and Control Instrumentation in the Iron and Steel Industry, Detroit, MI, AIST, 1985.

  25. 25. A. K. Rai, F. Y. Yueh and J. P. Singh, Appl Opt 2003, vol. 42, pp. 2078-84.

    Article  Google Scholar 

  26. H. Zhang, A. Rai, J. Singh, and F.Y. Yueh: USA, 2003.

  27. 27. A. K. Rai, F. Y. Yueh, J. P. Singh and H. Zhang, Review of Scientific Instruments 2002, vol. 73, pp. 3589-3599.

    Article  Google Scholar 

  28. R. De Saro, A. Weisberg, and J. Craparo: Light Metals: Proceedings of Sessions, TMS Annual Meeting, San Antonio, TX, 2003, pp. 1103–07.

  29. R. De Saro and A. Weisberg: (2004).

  30. J.M. Lucas, M. Sabsabi, and R. Heon: United States, 2003.

  31. M. Sabsabi, L. St-Onge, V. Detalle, and J.M. Lucas: 16th World Conference on Non-Destructive Testing (Montreal, Canada), 2004.

  32. Y.W. Kim: Google Patents: 1991.

  33. 33. T. Ozaki, T. Takahashi, Y. Iwai and E. Sudo, Transaction of the Iron and Steel Institute of Japan 1984, vol. 22, pp. 463-470.

    Article  Google Scholar 

  34. C. Carlhoff, C.J. Lorenzen, and K.P. Nick: Google Patents: 1991.

  35. 35. C. J. Lorenzen, C. Carlhoff, U. Hahn and M. Jogwich, J Anal Atom Spectrom 1992, vol. 7, pp. 1029-1035.

    Article  Google Scholar 

  36. 36. C. Aragón, J. A. Aguilera and J. Campos, Applied spectroscopy 1993, vol. 47, pp. 606-608.

    Article  Google Scholar 

  37. 37. R. Noll, H. Bette, A. Brysch, M. Kraushaar, I. Mönch, L. Peter and V. Sturm, Spectrochimica Acta Part B: Atomic Spectroscopy 2001, vol. 56, pp. 637-649.

    Article  Google Scholar 

  38. 38. L. Peter, V. Sturm and R. Noll, Applied Optics 2003, vol. 42, pp. 6199-6204.

    Article  Google Scholar 

  39. 39. L. X. Sun, H. B. Yu, Z. B. Cong, Y. Xin, Y. Li and L. F. Qi, Spectrochim Acta B 2015, vol. 112, pp. 40-48.

    Article  Google Scholar 

  40. 40. L. X. Sun, Y. Xin, Z. B. Cong, Y. Li and L. F. Qi, Advanced Materials Research 2013, vol. 694-697, pp. 1260-1266.

    Article  Google Scholar 

  41. 41. J. Gruber, J. Heitz, N. Arnold, D. Bauerle, N. Ramaseder, W. Meyer, J. Hochortler and F. Koch, Applied spectroscopy 2004, vol. 58, pp. 457-62.

    Article  Google Scholar 

  42. 42. M. Sabsabi, R. Heon, P. Bouchard, R. Meilland and A. Lamande, In 4th Euro-Mediterranean Symposium dedicated to Laser Induced Breakdown Spectroscopy, (Paris, France, 2007).

    Google Scholar 

  43. S.W. Hudson, J. Craparo, R. De Saro, and D. Apelian: Light Metals: Proceedings of the TMS Annual Meeting (Nashville, TN), 2016, pp. 3137–41.

  44. S. Poynton, M. Brandt, and J. Grandfield: Light Metals: Proceedings of Sessions, TMS Annual Meeting (San Fransisco, CA), 2009, pp. 681–87.

  45. 45. J. Wannasin, D. Schwam and J. F. Wallace, Journal of Materials Processing Technology 2007, vol. 191, pp. 242-246.

    Article  Google Scholar 

  46. T.A. Utigard and I.D. Sommerville: Light Metals: Proceedings of Sessions, TMS Annual Meeting (San Francisco, CA), 2005, pp. 951–86.

  47. 47. O. Lashkari, L. Yao, S. Cockcroft and D. Maijer, Metall Mater Trans A 2009, vol. 40A, pp. 991–99.

    Article  Google Scholar 

  48. D. Neff: North American Die Casting Association Congress (Chicago, IL, 2002).

  49. D. Apelian: Proceedings of the 3rd International Conference on Molten Aluminum Processing (Orlando, FL), 1992, pp. 1–15.

  50. 50. M. M. Pande, M. X. Gu, R. Dumarey, S. Devisscher and B. Blanpain, Isij International 2011, vol. 51, pp. 1778-1787.

    Article  Google Scholar 

  51. 51. H. M. Kuss, S. Lungen, G. Muller and U. Thurmann, Anal Bioanal Chem 2002, vol. 374, pp. 1242-9.

    Article  Google Scholar 

  52. 52. H. M. Kuss, H. Mittelstaedt and G. Mueller, J Anal Atom Spectrom 2005, vol. 20, pp. 730-735.

    Article  Google Scholar 

  53. 53. H. Falk and P. Wintjens, Spectrochim Acta B 1998, vol. 53, pp. 49-62.

    Article  Google Scholar 

  54. 54. I. V. Cravetchi, M. Taschuk, Y. Y. Tsui and R. Fedosejevs, Spectrochim Acta B 2004, vol. 59, pp. 1439-1450.

    Article  Google Scholar 

  55. 55. D. W. Hahn and M. M. Lunden, Aerosol Science and Technology 2000, vol. 33, pp. 30-48.

    Article  Google Scholar 

  56. 56. D. W. Hahn, W. L. Flower and K. R. Hencken, Applied spectroscopy 1997, vol. 51, pp. 1836-1844.

    Article  Google Scholar 

  57. 57. P. K. Diwakar, K. H. Loper, A. M. Matiaske and D. W. Hahn, J Anal Atom Spectrom 2012, vol. 27, pp. 1110-1119.

    Article  Google Scholar 

  58. 58. D. W. Hahn, Appl Phys Lett 1998, vol. 72, pp. 2960-2962.

    Article  Google Scholar 

  59. 59. V. V. Nalimov: The Application of Mathematical Statistics to Chemical Analysis. (Pergamon Press, London, 1963).

    Google Scholar 

  60. S.W. Hudson and D. Apelian: Light Metals: Proceedings of Sessions, TMS Annual Meeting (San Diego, CA), Wiley, 2014, pp. 1025–29.

  61. 61. S. W. Hudson and D. Apelian, In Materials Science & Technology 2014 Conference & Exhibition, (Wiley: Pittsburgh, PA, 2014).

    Google Scholar 

  62. S.W. Hudson, J. Craparo, R. De Saro and D. Apelian: in Light Metals: Proceedings of Sessions, TMS Annual Meeting (Orlando, FL), M. Hyland, ed., 2015, pp. 987–90.

  63. 63. D. A. Cremers and L. J. Radziemski, In Handbook of Laser-Induced Breakdown Spectroscopy, (John Wiley & Sons, Ltd.: West Sussex, UK, 2013).

    Book  Google Scholar 

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Authors and Affiliations

  1. Advanced Casting Research Center, Worcester Polytechnic Institute, 100 Institute Road, Worcester, MA, 01609, USA

    Shaymus W. Hudson

  2. Energy Research Company, 1250 South Avenue, Plainfield, NJ, 07062, USA

    Joseph Craparo & Robert De Saro

  3. Worcester Polytechnic Institute, 100 Institute Road, Worcester, MA, 01609, USA

    Diran Apelian

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  1. Shaymus W. Hudson
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  2. Joseph Craparo
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  3. Robert De Saro
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  4. Diran Apelian
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Correspondence to Shaymus W. Hudson.

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Manuscript submitted March 1, 2016.

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Hudson, S.W., Craparo, J., De Saro, R. et al. Applications of Laser-Induced Breakdown Spectroscopy (LIBS) in Molten Metal Processing. Metall Mater Trans B 48, 2731–2742 (2017). https://doi.org/10.1007/s11663-017-1032-7

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  • DOI: https://doi.org/10.1007/s11663-017-1032-7

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