Metallurgical and Materials Transactions B

, Volume 48, Issue 3, pp 1494–1501 | Cite as

Continuous Extraction of Nickel from Superalloy Scraps Using Zinc Circulation

  • Ryohei Yagi
  • Toru H. Okabe


A novel technique for the continuous extraction of nickel (Ni) from Ni-based superalloy scraps using molten zinc (Zn) has been proposed, and its feasibility was experimentally demonstrated. The newly developed approach allows for extraction of Ni metal directly from superalloy scraps with simultaneous separation of the Zn from the resulting Zn-Ni alloy. The optimal conditions for the extraction of Ni and separation of valuable elements such as rhenium (Re), tantalum (Ta), and tungsten (W) were determined by varying major process parameters including the reaction time and configuration of the reaction chamber. The proposed method has been successfully utilized for the production of the superalloy containing 62.8 mass pct of Ni and 15.5 mass pct of refractory metals (Re, W, and Ta). Under certain conditions, 41 pct of the Ni contained in the superalloy could be extracted at 1173 K (900 °C) over 48 hours, producing an alloy containing 84.0 mass pct of Ni and 0.2 mass pct of the refractory metals.


Turbine Blade Reaction Chamber Refractory Metal Quartz Crucible Crucible Bottom 
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The authors are grateful to Emeritus Professor Yoshiaki Umetsu from Tohoku University as well as to Professor Shunsuke Yagi, Dr. Yu-ki Taninouchi, and Dr. Akihiro Yoshimura from The University of Tokyo, for their generous support and valuable discussions. This research study was supported by a Grant-in-Aid for Scientific Research (S) (Grant Number 26220910). Ryohei Yagi is grateful for the financial support provided by the Doctoral Student Special Incentives Program (SEUT-RA) of the University of Tokyo, Japan.


  1. 1.
    Roskill Information Services Ltd.: Markets Outlook to 2020, 10th ed., 2015.Google Scholar
  2. 2.
    R. R. Srivastava, M. S. Kim, J. C. Lee, M. K. Jha, and B. S. Kim: J. Mater. Sci., 2014, vol. 49, pp. 4,671–4,686.CrossRefGoogle Scholar
  3. 3.
    R. Yagi and T. H. Okabe: J. Jpn. Inst. Met. Mater., 2016, vol. 80, pp. 341–349. (in Japanese)CrossRefGoogle Scholar
  4. 4.
    R. Yagi and T. H. Okabe: J. Min. Mater. Process. Inst. Jpn., 2016, vol. 132, pp. 114–122. (in Japanese)Google Scholar
  5. 5.
    P.D. Laverty, G.B. Atkinson, and D.P. Desmond: US Bureau of Mines, Report of investigations 9235, 1989.Google Scholar
  6. 6.
    P.T. Brooks, G.M. Potter, and D. Martin: US Bureau of Mines, Report of investigations No. 7316, 1969.Google Scholar
  7. 7.
    A.W. Fletcher, E.R. Baggott, and R. Derry: US Patent 3,544,309, 2002.Google Scholar
  8. 8.
    L.D. Redden, R.D. Groves, and D.C. Seidel: US Bureau of Mines, Report of investigations 9210, 1988.Google Scholar
  9. 9.
    R. R. Srivastava, M. S. Kim, and J. C. Lee: Ind. Eng. Chem. Res., 2016, vol. 55, pp. 8,191–8,199.CrossRefGoogle Scholar
  10. 10.
    B.H. Rosof: US Patent 4,173,467, 1979.Google Scholar
  11. 11.
    X. Fan, W. Xing, H. Dong, J. Zhao, Y. Wu, B. Li, W. Tong, and X. Wu: Int. J. Nonferr. Met., 2013, vol. 2, pp. 63–67.CrossRefGoogle Scholar
  12. 12.
    E. Luederitz, U.R. Schlegel, P.T. Halpin, and D.L. Schneck: US Patent 8,383,070, 2013.Google Scholar
  13. 13.
    C.G. Ferron and L.E. Seeley: US Patent 8,956,582, 2015.Google Scholar
  14. 14.
    R. Yagi and T. H. Okabe: Met. Trans. B, 2017, vol. 48, pp. 335-345.CrossRefGoogle Scholar
  15. 15.
    T. B. Massalski: Binary Alloy Phase Diagrams, 2nd ed., ASM International, Materials Park, OH, USA, 1990.Google Scholar
  16. 16.
    C.T. Sims, C.M. Craighead, R.I. Jaffee, D.N. Gideon, W.W. Kleinschmidt, W.E. Nexsen Jr., G.B. Gaines, F.C. Todd, C.S. Peet, D.M. Rosenbaum, R.J. Runck, and I.E. Campbell: WADC Technical Report No. 54–371, 1956.Google Scholar
  17. 17.
    I. Barin: Thermochemical Data of Pure Substances, 3rd ed., VCH Verlagsgesellschaft mbH, Weinheim, Germany, 1995.CrossRefGoogle Scholar
  18. 18.
    T. H. Okabe, O. Takeda, K. Fukuda, and Y. Umetsu: Mater. Trans., 2003, vol. 44, pp. 798–801.CrossRefGoogle Scholar
  19. 19.
    O. Takeda, T. H. Okabe, and Y. Umetsu: J. Alloy. Compd., 2006, vols. 408-412, pp. 387–390.CrossRefGoogle Scholar

Copyright information

© The Minerals, Metals & Materials Society and ASM International 2017

Authors and Affiliations

  1. 1.Department of Materials Engineering, Graduate School of EngineeringThe University of TokyoTokyoJapan
  2. 2.Institute of Industrial ScienceThe University of TokyoTokyoJapan

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