Skip to main content
Log in

Limitation of Sulfide Capacity Concept for Molten Slags

  • Communication
  • Published:
Metallurgical and Materials Transactions B Aims and scope Submit manuscript

Abstract

The sulfide capacity concept has been widely used in pyrometallurgy to define sulfur removal capacities of slags. Typically, the sulfide capacity is considered to be a unique slag property depending only on temperature regardless of partial pressures of oxygen and sulfur. In the present study, it is demonstrated that sulfide capacities of slags in particular those of Na2O-containing slags can vary with partial pressures of oxygen and sulfur due to large solubility of sulfide in Na2O-containing slag systems.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. C. J. B. Fincham and F. D. Richardson: Proc. R. Soc. Lond. Ser. A, 1954, vol. 223, pp. 40–62.

    Article  Google Scholar 

  2. G. St. Pierre and J. Chipman: J. Metal, 1956, vol. 8, pp. 1474–83.

    Google Scholar 

  3. E. T. Turkdogan and L. S. Darken: Trans. Am. Inst. Min. Metall. Pet. Eng., 1961, vol. 221, pp. 464–74.

    Google Scholar 

  4. S. Nagashima and T. Katsura: Bull. Chem. Soc. Jpn., 1973, vol. 46, pp. 3099–103.

    Article  Google Scholar 

  5. A. H. Chan and R. J. Fruehan: Metall. Trans. B, 1986, vol. 17B, pp. 491–96.

    Article  Google Scholar 

  6. A. H. Chan and R. J. Fruehan: Metall. Trans. B, 1988, vol. 19B, pp. 334–36.

    Article  Google Scholar 

  7. Y.-B. Kang and A. D. Pelton: Metall. Mater. Trans. B, 2009, vol. 40B, pp. 979–94.

    Article  Google Scholar 

  8. E. Moosavi-Khoonsari and I.-H. Jung: Metall. Mater. Trans. B, 2015 (Submitted for publication).

  9. www.FactSage.com. FactSage 6.4 version.

  10. G. Denier: IRSID, Internal Report, No. RP. ACI. 26, cited by R. Inoue and H. Suito, Trans. Iron Steel Inst. Jpn., 1982, vol. 22, pp. 514–23.

  11. R. Derici and H.B. Bell: unpublished work, cited by R. Inoue and H. Suito: Trans. Iron Steel Inst. Jpn., 1982, vol. 22, pp. 514–23.

  12. W. H. Van Niekerk and R. J. Dippenaar: Metall. Trans. B, 1992, vol. 23B, pp. 395–97.

    Article  Google Scholar 

  13. http://www.crct.polymtl.ca/sgte. SGTE Substance Database (SGSUB).

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to In-Ho Jung.

Additional information

Manuscript submitted September 2, 2015.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jung, IH., Moosavi-Khoonsari, E. Limitation of Sulfide Capacity Concept for Molten Slags. Metall Mater Trans B 47, 819–823 (2016). https://doi.org/10.1007/s11663-016-0594-0

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11663-016-0594-0

Keywords

Navigation