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Raman Structure Investigations of CaO-MgO-Al2O3-SiO2-CrO x and Its Correlation with Sulfide Capacity

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Abstract

The structures of the Cr-containing slags were analyzed by Raman spectroscopy. The results obtained show that when the Cr contents increased from 0 to 5 pct, the depolymerization degree of the silicate matrix is increased. However, increasing Cr content to 7 pct caused the depolymerization degree to decrease. The spectral results are consistent with the results of sulfide capacity measurements. And the relationship between average bridging oxygen and sulfide capacities (logCS) was discussed accordingly.

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Reference

  1. K. Nagata, M. Hayashi: J. Non-Cryst. Solids, 2001, vol. 282, pp. 1–6.

    Article  Google Scholar 

  2. L. Wang and S. Seetharaman: Metall. Mater. Trans. B, 2010, vol. 41, pp. 367–73.

    Article  Google Scholar 

  3. L. Wang, Y. Wang, K. Chou, S. Seetharaman: Metall. Mater. Trans. B, 2015 (under consideration).

  4. Y. H. Yun and P. J. Bray: J. Non-Cryst. Solids, 1978, vol. 27, pp. 363–80.

    Article  Google Scholar 

  5. W. L. Konijnendijk and J. M. Stevels: J. Non-Cryst. Solids, 1976, vol. 20, pp. 193–224.

    Article  Google Scholar 

  6. P. I. K. Onorato, M. N. Alexander, C. W. Struck and D. R. Uhlmann D R: J. Am. Ceram. Soc.,1985, vol. 68, pp. 148–50.

    Article  Google Scholar 

  7. J. F. Stebbins and Z. Xu: Nature, 1997, vol. 390, pp. 60–62.

    Article  Google Scholar 

  8. H. Maekawa, T. Meakawa, K. Kawamura and T. Yokokawa: J. Non-Cryst. Solids, 1991, vol. 127, pp. 53–64.

    Article  Google Scholar 

  9. P. McMillan: Am. Miner., 1984, vol. 69, pp. 645–59.

    Google Scholar 

  10. B. O. Mysen: Am. Miner., 1990, vol. 75, pp. 120–34.

    Google Scholar 

  11. P. F. McMillan P F: Am. Miner., 1984, vol. 68, pp. 622–44.

  12. D. W. Matson, S. K. Sharma and J. A. Philpotts: J. Non-Cryst. Solids, 1983, vol. 58, pp. 323–52.

    Article  Google Scholar 

  13. Y. Iguchi, M. Wako, S. Ban-ya, Y. Nishina and T. Fuwa: The Second International Conference on Molten Slags, Fluxes and Salts, 1984, pp. 975–83.

  14. Y. Iguchi, S. Kashio, T. Goto, Y. Nishina and T. Fuwa: Can. Metall. Q., 1981, vol 20, pp. 51–56.

    Article  Google Scholar 

  15. K. Fukumi, J. Hayakawa and T. Komiyama: J. Non-Cryst. Solids, 1990, vol. 119, pp. 297–302.

    Article  Google Scholar 

  16. Y. Tsunawaki, N. Iwamoto, T. Hattori and A. Mitsuishi: J. Non-Cryst. Solids, 1981, vol. 44, pp. 369–78.

    Article  Google Scholar 

  17. B. O. Mysen and J. D. Frantz: Am. Miner., 1993, vol. 78, pp. 699–709.

    Google Scholar 

  18. B. O. Mysen, D. Virgo and C. Scarfe: Am. Miner., 1980, vol. 65, pp. 690–710.

    Google Scholar 

  19. J. L. You, G. C. Jiang and K. D. Xu: J. Non-Cryst. Solids, 2001, vol. 282, pp. 125–31.

    Article  Google Scholar 

  20. P. A. McMillan: Chem. Geo., 1984, vol. 69, pp. 645–59.

    Google Scholar 

  21. J. D. Frantza and B. O. Mysen: Chem. Geo., 1995, vol. 121, 155–76.

    Article  Google Scholar 

  22. B. O. Mysen and J. D. Frantz: Contri. Miner. Petro., 1994, vol. 117, pp. 1–14.

    Article  Google Scholar 

  23. J. Tan, S. Zhao, W. Wang, G. Davies and X. Mo: Mater. Sci. Eng. B, 2004, vol. 106, pp. 295–99.

    Article  Google Scholar 

  24. B. O. Mysen, L. W. Finger, D. Virgo and F. A. Seifert: Am. Miner., 1982, vol. 67, pp. 686–95.

    Google Scholar 

  25. B. M. Weckhuysen and I. F. Wachs: J. Chem. Soc, Fara. Trans., 1996, vol. 92, pp. 1969–73.

  26. Richard J. D. Tilly: Crystals and Crystal Structures, Willy, 2006, pp. 93.

  27. L. Wang, M. Hayashi, K. C. Chou and S. Seetharaman: Metall. Mater. Trans. B, 2012, vol. 43B, pp. 1338–43.

    Article  Google Scholar 

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The authors are grateful for the financial support for this work from the National Nature Science Foundation of China (No. 51104013, No. 51174022), China Postdoctoral Science Foundation (2014M560046), and Beijing Higher Education Young Elite Teacher Project (YETP0349), as well as the Fundamental Research Funds for the Central Universities (FRF-TP-14-109A2).

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Authors and Affiliations

  1. State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing, 100083, P.R. China

    Lijun Wang (Associate Professor), Yaxian Wang (Master Student), Qi Wang (Master Student) & Kuochih Chou (Professor)

  2. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing, 100083, P.R. China

    Lijun Wang (Associate Professor), Yaxian Wang (Master Student), Qi Wang (Master Student) & Kuochih Chou (Professor)

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  1. Lijun Wang
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  2. Yaxian Wang
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Correspondence to Lijun Wang.

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Manuscript submitted on June 25, 2015.

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Wang, L., Wang, Y., Wang, Q. et al. Raman Structure Investigations of CaO-MgO-Al2O3-SiO2-CrO x and Its Correlation with Sulfide Capacity. Metall Mater Trans B 47, 10–15 (2016). https://doi.org/10.1007/s11663-015-0469-9

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