The oxidation behavior of synthetic pentlandite at 973 K (700 °C) under isothermal conditions was investigated. The pentlandite sample (Ni,Fe)9S8 was synthesized from pure components and oxidized at 973 K (700 °C) in air in a muffle furnace. The phase identification and components analysis of the oxidation products were performed by using the Rietveld quantitative analysis method based on the powder X-ray diffraction (XRD) profiles and scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM-EDX). The magnetic hysteresis loops were determined by a vibrating sample magnetometer. Fe2O3, Ni x Fe3-x O4, and NiO were dominant oxidation products, and their weight fractions changed in different ways along with the oxidation time. The nickel-rich phase and sulfur-rich phase were observed as intermediate phases in unreacted cores during oxidation, which led to the formation of gaps and holes. The oxidation reaction rate was rapid in the first 2 hours, and then it slowed down sharply.
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This work was supported financially by Grant 2007CB613601 from the National Key Program for Basic Research of 973 Program and grants 20731001, 50725415, 50704003, and 21031005 National Natural Science Foundation of China.
Manuscript submitted May 31, 2011.
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Zhu, H., Chen, J., Deng, J. et al. Oxidation Behavior and Mechanism of Pentlandite at 973 K (700 °C) in Air. Metall Mater Trans B 43, 494–502 (2012). https://doi.org/10.1007/s11663-011-9630-2
- Oxidation Mechanism
- Magnetic Hysteresis Loop